Results 231 to 240 of about 5,891,064 (303)

ALDH Inhibition‐Primed Photocatalysis Disrupts Cancer Stemness Plasticity

open access: yesAngewandte Chemie, EarlyView.
DE‐Et converts ALDH‐mediated redox buffering into a photoredox vulnerability by coupling ALDH inhibition with red‐light‐driven catalytic NADH oxidation. This enzyme‐coupled photoredox strategy sustains mitochondrial NADH/NAD+ imbalance, induces pyroptotic tumor cell death, suppresses tumor growth in vivo, and promotes systemic antitumor immunity ...
Yujin Kim   +10 more
wiley   +1 more source

Anion Engineering of Surface Frustrated Lewis Pairs for Light‐Assisted CO2 Hydrogenation to Methanol

open access: yesAngewandte Chemie, EarlyView.
Anion engineering through nitrogen incorporation regulates the local coordination environment and promotes the formation of defect‐associated Ga–O/N frustrated Lewis pairs in non‐stoichiometric zinc gallium oxide. The engineered surface sites facilitate heterolytic H2 splitting, while the modified electronic structure enhances light utilization ...
Rui Song   +27 more
wiley   +1 more source

Conformationally Switchable Copper(I) Complexes Amplify BODIPY Triplet Photosensitization

open access: yesAngewandte Chemie, EarlyView.
Coupling a structurally switchable Cu(I) complex to an organic light‐harvesting chromophore boosts photoinduced intersystem crossing via the transient formation of a Cu(II) intermediate. Spectroscopic, physical, computational, and photocatalytic studies support this unique new approach to solar energy upconversion.
Nisha Kamboj   +4 more
wiley   +1 more source

Site‐Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C2+ Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Site‐specific self‐assembly of alkyl thiols on Au/TiO2 enables precise modulation of interfacial electron distribution and the local microenvironment through covalent Au‐thiolate interactions. This site‐specific molecular engineering synergistically promotes surface kinetics and charge separation, suppressing ·O2−‐driven overoxidation and thereby ...
Yaru Shao   +11 more
wiley   +1 more source

Boosting the Mechanical Strength and Photocatalytic Activity of 3D-Printed Titania Aerogels by Atomic Layer Deposition and Heat Treatment. [PDF]

open access: yesACS Mater Au
Schmidt MM   +7 more
europepmc   +1 more source

Photocatalytically active titanium dioxide

open access: yesFocus on Powder Coatings, 2008
openaire   +1 more source

Modulating Covalent Organic Framework Nanochannel Microenvironments for Sustainable Hydrogen Peroxide Photosynthesis

open access: yesAngewandte Chemie, EarlyView.
Alkoxy side chains regulate hydrazone‐linked COF nanochannel microenvironments by tuning pore polarity, reactant adsorption, and charge‐separation behavior. The optimized framework facilitates oxygen activation and hydrogen peroxide photosynthesis in real water and a 1 L natural‐sunlight reactor. LCA further shows that natural sunlight and larger‐scale
Ruixue Sun   +11 more
wiley   +1 more source

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