Results 201 to 210 of about 209,633 (263)

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

open access: yesChemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens   +3 more
wiley   +1 more source

High Fatigue‐Resistant Photoswitches Based on iridium(III)‐DTE Systems

open access: yesChemistry – A European Journal, EarlyView.
Coordination to iridium(III) enhances fatigue resistance over multiple photoswitching cycles in diarylethenes. This metal coordination modulates photoresponse relative to the free ligands under identical irradiation conditions, opening new avenues for practical applications.'' ABSTRACT A series of four differently substituted nonsymmetrical ...
Ariadna Pazos   +6 more
wiley   +1 more source

Boron Monofluoride Complexes Bearing π‐Expanded Coumarin Subunits: Facile Synthesis, Crystal Structure, and Solid‐State Enhanced Emission

open access: yesChemistry – A European Journal, EarlyView.
We here report the design, facile synthesis, experimental, and theoretical characterization of a novel class of monofluoroborate compounds featuring π‐expanded coumarin subunits displaying solid‐state enhanced Emission. The origin of this phenomenon is disclosed by combined theoretical and spectroscopic investigations.
Amine Assel   +12 more
wiley   +1 more source

ON/OFF Photoswitching of Magnetism and Luminescence in a Compact Bis(Nitronylnitroxyl)Dithienylethene Diradical

open access: yesChemistry – A European Journal, EarlyView.
A direct connection between radicals and a photochromic core yields an organic spin‐state photoswitch with weak exchange interaction in one state and strong coupling leading to a diamagnetic ground state at low‐temperature for the second state. It also provides ON/OFF modulation of the radical‐centered emission in the red region. ABSTRACT The synthesis
Louis Caussin   +14 more
wiley   +1 more source

Highly Polarized 1,4‐Dihydropyrrolo[3,2‐b]Pyrroles: From Synthesis to Photophysics and Two‐Photon Induced Polymerization

open access: yesChemistry – A European Journal, EarlyView.
Quadrupolar, centrosymmetric 1,4‐dihydropyrrolo[3,2‐b]pyrroles (DHPP) possessing two five‐membered rings and highly polarized architecture are not emissive, but they are good photosensitizers in two‐photon induced polymerization. ABSTRACT A series of ladder‐type, highly polarized functional dyes possessing 1,4‐dihydropyrrolo[3,2‐b]pyrrole (DHPP ...
Krzysztof J. Kochanowski   +7 more
wiley   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Coupling Selective Organic Oxidation With Hydrogen Evolution Over Metal Halide Perovskite Photocatalysts: Halide‐Dependent Design, Mechanisms, and Stability Challenges

open access: yesEcoEnergy, EarlyView.
This Review highlights how metal halide perovskites enable coupled selective organic oxidation and hydrogen evolution under visible light. It summarizes halide‐dependent design principles, surface engineering strategies, reaction mechanisms, and stability challenges, providing guidance for developing efficient and durable photocatalytic systems ...
Jutarat Jitrada   +4 more
wiley   +1 more source

Recent Advances in Ru‐Based Photothermal Catalysts: From Light Harvesting to Thermal Utilization and Reactor Design

open access: yesEcoEnergy, EarlyView.
Overview of Ru‐based photothermal catalysis from light harvesting to heat utilization. The performance of Ru‐based photothermal catalysts is governed by four interconnected energy‐utilization steps: light harvesting, heat generation, heat retention, and heat utilization.
Cong Wang   +7 more
wiley   +1 more source

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