Results 221 to 230 of about 21,000 (274)

In Situ Phase Transition and Cu Doping Synergistically Regulate Perovskite Z‐Scheme Heterojunction for Photocatalytic CO2 Reduction

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A novel in situ synthesis strategy is proposed for fabricating Cu‐CsPbBr3/Cu‐CsPb2Br5 heterojunction materials, with dual optimization of structure and composition expanding the CO2 adsorption/activation area and enhancing intrinsic catalytic activity.
Qiliang Zhu   +5 more
wiley   +1 more source

Tuning Colloidal Stability and Photothermal Conversion Efficiency of Graphite Nanofluids via Anionic‐Nonionic Surfactant Engineering

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Graphite nanofluids were stabilized using a mixed SDS/Tween 80 surfactant system. The optimized formulation exhibited enhanced colloidal stability, red‐shifted UV–Vis absorption, and improved photothermal conversion under solar irradiation. Achieving stable dispersion of graphite flakes (GFs) in aqueous media remains a critical challenge in developing ...
Ahmad Chehade   +3 more
wiley   +1 more source

Synthesis and Characterization of Novel Silylated Sm3+ and Eu3+ Complexes Incorporated Into Mesoporous Silica Nanoparticles

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The strategy of incorporating the Eu(tta‐Si)3(phen) and Sm(tta‐Si)3(phen)2 complexes prevented leaching of the complexes and preserved their intrinsic optical properties. Preliminary studies of silylated Ln3+ complexes and nanoparticles loaded with these complexes demonstrated cytotoxicity against cancer cells, with minimal cytotoxic effect on nontumor
Juliana Jorge   +11 more
wiley   +1 more source

On the Planarity of Heterocyclic Bay‐Substituted Perylenediimides: Insight into the Fluorescent Photoinduced Electron Transfer Sensing Framework

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Near‐infrared fluorescent pH indicators based on perylenediimide were constructed in a modular receptor–spacer–fluorophore–spacer–receptor format with heterocyclic amino moieties at the bay positions. Counterintuitively, the dibrominated intermediate with two heavy atoms is more emissive than the heterocyclic compounds.
Luke Camenzuli   +4 more
wiley   +1 more source

Design, Synthesis, and Photophysical Studies of Functionalized Polyaromatic Isonitriles as Visible Light Photoredox Catalysts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini   +9 more
wiley   +1 more source

Lithium Diisopropylamide‐Mediated Ring‐Opening of Tetrahydrofuran in the Synthesis of Polyhydroxylated Indolizidines

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Chiral tri‐ and pentahydroxy spirocyclopentane‐indolizidines were synthesized using lithium diisopropylamide “LDA” promoted diallylation and tetrahydrofuran “THF” ring‐opening in a one‐pot procedure as a key step. The sequence leading to the targeted hydroxy‐spiroindolizidines was achieved by cis‐dihydroxylation followed by reduction of the enamine and
Paula Fraňová   +6 more
wiley   +1 more source

Fast Reduction of Nitroalkenes Into Nitroalkanes Under Continuous‐Flow Chemical Conditions

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Flow chemical synthesis was employed for the reduction of nitroalkenes to the corresponding nitroalkanes using sodium borohydride as the reducing agent. The reaction proceeds in only 150 s, affording products from good‐to‐excellent yields (61–96%). Herein, we describe an efficient and rapid continuous‐flow reduction of nitroalkenes to nitroalkanes. The
Iqra Munir   +3 more
wiley   +1 more source

Activation of Aryl Halides by Triplet–Triplet Annihilation Upconversion Enabling Coupling Processes Under an Open‐to‐Air Environment

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez   +4 more
wiley   +1 more source

Home - About - Disclaimer - Privacy