Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh +2 more
wiley +1 more source
Epoxidation of Cashmeran and Unprecedented Rearrangement to an α‐Carbonyl δ‐Spirolactone
A new strategy enables diastereoselective conversion of Cashmeran into a previously unknown α‐carbonyl δ‐spirolactone via epoxidation, Baeyer–Villiger oxidation, and acid‐catalyzed rearrangement. Structure and mechanism were confirmed by NMR, single crystal X‐ray diffraction, and computational studies. We report the epoxidation of Cashmeran followed by
Lukas Kell +7 more
wiley +1 more source
Non—photochemical quenching in photosynthetic antenna
Borodinas, Dominykas, Chmeliov, Jevgenij
openaire +1 more source
We report the synthesis, structural characterization, and photophysical investigation of a series of Excited‐State Intramolecular Proton Transfer‐active HBO and HDMI derivatives. By varying heterocyclic cores, substituents, and ethynyl planarization, we establish structure–property relationships governing fluorescence behavior.
Mathieu Gervais +7 more
wiley +1 more source
Organic Photodetectors and Sensors for Low‐Light and Infrared Applications
This mini review highlights recent advances in organic photodetectors and sensors for low‐light and infrared applications, emphasizing molecular design, device architectures, and interface engineering that improve charge transport, detectivity, speed, and spectral selectivity.
Swarup Biswas, Hyeok Kim
wiley +1 more source
Enhancing Optogenetics‐Based Cancer Therapy Via Nanotechnology
Nanotechnology enhances optogenetics‐based cancer therapy through improved delivery systems and non‐invasive optical regulation. It further enables precise and programmable control of optogenetic living therapeutics for localized antitumor responses.
Honggang Shen +8 more
wiley +1 more source
Understanding mechanistic responses underlying diurnal photoprotection and photosynthetic plasticity among cacao genotypes under natural amazonian field conditions. [PDF]
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Humic Acid Modulates Photosynthetic Responses to PEG-Induced Drought in <i>Ocimum basilicum</i> L. [PDF]
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Contrasting PSII Photochemistry and Energy Partitioning Between Spikes and Leaves During Grain Anthocyanin Accumulation in Hulless Barley on the Tibetan Plateau. [PDF]
Qin Z +8 more
europepmc +1 more source
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Non-photochemical quenching of fluorescence in cyanobacteria
Biochemistry (Moscow), 2007The pathways of energy dissipation of excessive absorbed energy in cyanobacteria in comparison with that in higher plants are discussed. Two mechanisms of non-photochemical quenching in cyanobacteria are described. In one case this quenching occurs as light-induced decrease of the fluorescence yield of long-wavelength chlorophylls of the photosystem I ...
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