Results 231 to 240 of about 21,000 (274)

Enantiospecific Acid‐Catalysed Hydroperoxidation of Scalemic Tertiary Benzylic Alcohols Facilitating a Concise Asymmetric Synthesis of Yingzhaosu C

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh   +2 more
wiley   +1 more source

Epoxidation of Cashmeran and Unprecedented Rearrangement to an α‐Carbonyl δ‐Spirolactone

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new strategy enables diastereoselective conversion of Cashmeran into a previously unknown α‐carbonyl δ‐spirolactone via epoxidation, Baeyer–Villiger oxidation, and acid‐catalyzed rearrangement. Structure and mechanism were confirmed by NMR, single crystal X‐ray diffraction, and computational studies. We report the epoxidation of Cashmeran followed by
Lukas Kell   +7 more
wiley   +1 more source

Impact of Electronic Substitution and Planarization on the Photophysical Properties of 2‐(2′‐Hydroxyphenyl)benzoxazole or 2‐(2′‐Hydroxyphenyl)‐Dimethylindole

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
We report the synthesis, structural characterization, and photophysical investigation of a series of Excited‐State Intramolecular Proton Transfer‐active HBO and HDMI derivatives. By varying heterocyclic cores, substituents, and ethynyl planarization, we establish structure–property relationships governing fluorescence behavior.
Mathieu Gervais   +7 more
wiley   +1 more source

Organic Photodetectors and Sensors for Low‐Light and Infrared Applications

open access: yesElectron, EarlyView.
This mini review highlights recent advances in organic photodetectors and sensors for low‐light and infrared applications, emphasizing molecular design, device architectures, and interface engineering that improve charge transport, detectivity, speed, and spectral selectivity.
Swarup Biswas, Hyeok Kim
wiley   +1 more source

Enhancing Optogenetics‐Based Cancer Therapy Via Nanotechnology

open access: yesExploration, EarlyView.
Nanotechnology enhances optogenetics‐based cancer therapy through improved delivery systems and non‐invasive optical regulation. It further enables precise and programmable control of optogenetic living therapeutics for localized antitumor responses.
Honggang Shen   +8 more
wiley   +1 more source

Humic Acid Modulates Photosynthetic Responses to PEG-Induced Drought in <i>Ocimum basilicum</i> L. [PDF]

open access: yesPlants (Basel)
Stefanov MA   +4 more
europepmc   +1 more source

Non-photochemical quenching of fluorescence in cyanobacteria

Biochemistry (Moscow), 2007
The pathways of energy dissipation of excessive absorbed energy in cyanobacteria in comparison with that in higher plants are discussed. Two mechanisms of non-photochemical quenching in cyanobacteria are described. In one case this quenching occurs as light-induced decrease of the fluorescence yield of long-wavelength chlorophylls of the photosystem I ...
N V Karapetyan, Karapetyan N V
exaly   +3 more sources

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