The radiative association of PO/PH+ and the photodissociation of PH+
The potential energy curves (PECs) and transition dipole moments (TDMs) of PH+ and PO are computed with the multireference configuration interaction method, and the cross-sections for the radiative association (RA) of PH+ and PO, which is the most ...
Yang Chen+7 more
doaj +1 more source
Indistinguishability and Interference in the Coherent Control of Atomic and Molecular Processes
The subtle and fundamental issue of indistinguishability and interference between independent pathways to the same target state is examined in the context of coherent control of atomic and molecular processes, with emphasis placed on possible "which-way"
Feynman R. P.+8 more
core +1 more source
Control of the Jovian Magnetopause by Iogenic Plasma: Initial Results From Global MHD Simulations
Abstract The size and variability of Jupiter's magnetosphere are not only determined by upstream conditions but also substantially influenced by internal processes within Jupiter's magnetosphere, specifically the dynamics of the rotation magnetodisc.
Enhao Feng+6 more
wiley +1 more source
Grain Dynamics in Photodissociation Regions [PDF]
We discuss the forces on grains exposed to anisotropic radiation fields, including the usual ``radiation pressure'' force and also recoil forces due to photoemitted electrons, photodesorbed hydrogen atoms, and hydrogen molecules which form on the grain surface.
arxiv
Theoretical Models of Photodissociation Fronts [PDF]
Observations of H2 line emission have revealed higher-than-expected gas temperatures in a number of photodissociation fronts. We discuss the heating and cooling processes in photodissociation regions. Observations of NGC 2023 are compared to a theoretical model in which there is substantial gas at temperatures T = 500-1000K heated by photoelectric ...
arxiv
Mechanistic Investigation of an Organocatalytic Bromocyclization of O‐Allyl Carbamates
The enantioselective bromoaminocyclization of O‐cinnamyl tosylcarbamates catalyzed by thiourea‐functionalized Cinchona alkaloids achieved 80:20 er and 69% isolated yield. Experimental and theoretical studies reveal key bromonium intermediates and non‐covalent interactions stabilizing the catalytic structure. This model reaction elucidates the mechanism
Francisco Wanderson Moreira Ribeiro+5 more
wiley +1 more source
Hydroxyl super rotors from vacuum ultraviolet photodissociation of water
Free electron lasers provide a state-of-the-art tool to investigate the photochemistry of water. Here, the authors show that highly rotationally excited hydroxyl radicals, so-called “super rotors” existing above the bond dissociation energy, are observed
Yao Chang+16 more
doaj +1 more source
Dissociation Dynamics of CIONO_2 and Relative Cl and ClO Product Yields following Photoexcitation at 308 nm [PDF]
Chlorine nitrate photolysis at 308 nm has been investigated with a molecular beam technique. Two primary decomposition pathways, leading to Cl + NO_3 and ClO + NO_2, were observed.
Minton, Timothy K.+3 more
core +1 more source
Translational Spectroscopy: Cl2 Photodissociation [PDF]
G. E. Busch+3 more
openalex +1 more source
Integrating Flow Chemistry With Electrospray Ionization Mass Spectrometry
The direct integration of flow chemistry with electrospray ionization‐mass spectrometry is emerging as a method for real‐time monitoring of reaction mixtures under well‐defined conditions. As shown in selected examples, this interface facilitates the characterization of reaction intermediates, enables the tracking of reaction dynamics under changing ...
Quentin Duez
wiley +1 more source