Results 11 to 20 of about 44,713 (249)

The Role of Norrish Type-I Chemistry in Photoactive Drugs: An ab initio Study of a Cyclopropenone-Enediyne Drug Precursor

open access: yesFrontiers in Chemistry, 2020
We present a contemporary mechanistic description of the light-driven conversion of cyclopropenone containing enediyne (CPE) precusors to ring-opened species amenable to further Bergman cyclization and formation of stable biradical species that have been
Spencer J. Léger   +4 more
doaj   +1 more source

Analysis of triacylglycerol and phospholipid sn‐positional isomers by liquid chromatographic and mass spectrometric methodologies

open access: yesMass Spectrometry Reviews, EarlyView., 2023
Abstract Analysis of triacylglycerol (TG) and phospholipid sn‐positional isomers can be divided into two main categories: (a) direct separation by chromatography or other means such as ion mobility mass spectrometry and (b) quantification of regioisomer ratios by structurally informative fragment ions with mass spectrometric methods.
Mikael Fabritius, Baoru Yang
wiley   +1 more source

Photoinduced bond oscillations in ironpentacarbonyl give delayed synchronous bursts of carbonmonoxide release

open access: yesNature Communications, 2022
The photodissociation of transition metal carbonyls is involved in catalysis and synthetic processes. Here the authors, using semi-classical excited state molecular dynamics, observe details of the early stage dynamics in the photodissociation of Fe(CO)5,
Ambar Banerjee   +6 more
doaj   +1 more source

A Theoretical Study of Temperature-dependent Photodissociation Cross Sections and Rates for O2

open access: yesThe Astrophysical Journal Supplement Series, 2023
The photodissociation of O _2 is thought to play a vital role in blocking UV radiation in the Earth’s atmosphere and likely has great importance in characterizing exoplanetary atmospheres.
Zhi Qin   +3 more
doaj   +1 more source

Real-Time Measurement of Photodissociation with a Static Modulated Fourier Transform Spectrometer

open access: yesApplied Sciences, 2022
A static modulated Fourier transform spectrometer composed of a modified Sagnac interferometer was implemented for real-time remote sensing of the spectral property changes in a solid dye.
Ju Yong Cho   +3 more
doaj   +1 more source

Iron monoxide photodissociation [PDF]

open access: yesThe Journal of Chemical Physics, 2005
The photodissociation of Fe56O was studied by means of the velocity map imaging technique. A molecular beam of iron atoms and iron monoxide molecules was created using an electrical discharge with an iron electrode in a supersonic expansion of molecular oxygen.
Chestakov, D.A.   +2 more
openaire   +4 more sources

Photochemical Micro-/Nano-Swelling of Silicone Rubber Induced by Long Pulse-Repetition Interval of an ArF Excimer Laser

open access: yesElectronic Materials, 2021
Long pulse-repetition intervals of 100 to 500 ms of a 193 nm ArF excimer laser successfully increased the height of the photochemical micro-/nano-swelling of silicone rubber, observed with a scanning electron microscope.
Masayuki Okoshi
doaj   +1 more source

The Catalyzed Photodissociation of Water [PDF]

open access: yesCatalysis Reviews, 1984
Abstract Chemical interactions between molecules in excited electronic, vibrational, or rotational states and surfaces is a new field of catalytic science. Until recently, catalysis of chemical reactions has only been considered for molecules in their thermodynamic ground states.
Somorjai, G.A.   +2 more
openaire   +2 more sources

Nanoscale Vacancy-Mediated Aggregation, Dissociation, and Splitting of Nitrogen Centers in Natural Diamond Excited by Visible-Range Femtosecond Laser Pulses

open access: yesNanomaterials, 2023
Natural IaA+B diamonds were exposed in their bulk by multiple 0.3 ps, 515 nm laser pulses focused by a 0.25 NA micro-objective, producing in the prefocal region (depth of 20–50 μm) a bulk array of photoluminescent nanostructured microtracks at variable ...
Sergey Kudryashov   +9 more
doaj   +1 more source

Breaking the Boring Billion

open access: yesGeophysical Monograph Series, Page 487-501., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
Charles W. Diamond   +3 more
wiley  

+1 more source

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