Results 21 to 30 of about 40,404 (274)

Photodissociation of long-range Rydberg molecules [PDF]

open access: yesPhys. Rev. A 102, 062819 (2020), 2020
We present photodissociation of ultracold long-range Rydberg molecules as a tool to characterize their electronic properties. We photoassociate K2 37P molecules with highly entangled electronic and nuclear spins of the two bound atoms and quantify the entanglement by projection of the molecular state onto non-interacting atoms using radiofrequency ...
arxiv   +1 more source

ExoMol photodissociation cross sections I: HCl and HF [PDF]

open access: yes, 2022
Photon initiated chemistry, \textit{i.e.} the interaction of light with chemical species, is a key factor in the evolution of the atmosphere of exoplanets. For planets orbiting stars in UV-rich environments, photodissociation induced by high energy photons dominates the atmosphere composition and dynamics.
arxiv   +1 more source

Analysis of triacylglycerol and phospholipid sn‐positional isomers by liquid chromatographic and mass spectrometric methodologies

open access: yesMass Spectrometry Reviews, EarlyView., 2023
Abstract Analysis of triacylglycerol (TG) and phospholipid sn‐positional isomers can be divided into two main categories: (a) direct separation by chromatography or other means such as ion mobility mass spectrometry and (b) quantification of regioisomer ratios by structurally informative fragment ions with mass spectrometric methods.
Mikael Fabritius, Baoru Yang
wiley   +1 more source

Photochemical Micro-/Nano-Swelling of Silicone Rubber Induced by Long Pulse-Repetition Interval of an ArF Excimer Laser

open access: yesElectronic Materials, 2021
Long pulse-repetition intervals of 100 to 500 ms of a 193 nm ArF excimer laser successfully increased the height of the photochemical micro-/nano-swelling of silicone rubber, observed with a scanning electron microscope.
Masayuki Okoshi
doaj   +1 more source

C60IN PHOTODISSOCIATION REGIONS [PDF]

open access: yesThe Astrophysical Journal, 2014
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar
Pablo Castellanos   +5 more
openaire   +5 more sources

Three-isotope plot of fractionation in photolysis: A perturbation theoretical expression [PDF]

open access: yes, 2005
The slope of the three-isotope plot for the isotopomer fractionation by direct or nearly direct photodissociation is obtained using a perturbation theoretical analysis.
Marcus, R. A., Prakash, M. K.
core   +1 more source

Host‐guest tuning of the CO2 reduction activity of an iron porphyrin cage

open access: yesNatural Sciences, Volume 3, Issue 1, January 2023., 2023
An iron porphyrin cage can catalyze CO2 electroreduction to CO with a large selectivity. The catalytic properties can be further improved by tuning the internal electrostatic potential of the cage by hosting the potassium ions in the crown‐ether‐like side walls.
Adarsh Koovakattil Surendran   +7 more
wiley   +1 more source

Nanoscale Vacancy-Mediated Aggregation, Dissociation, and Splitting of Nitrogen Centers in Natural Diamond Excited by Visible-Range Femtosecond Laser Pulses

open access: yesNanomaterials, 2023
Natural IaA+B diamonds were exposed in their bulk by multiple 0.3 ps, 515 nm laser pulses focused by a 0.25 NA micro-objective, producing in the prefocal region (depth of 20–50 μm) a bulk array of photoluminescent nanostructured microtracks at variable ...
Sergey Kudryashov   +9 more
doaj   +1 more source

The impact of optical excitation on the binding in complexes of the cationic gold dimer: Au2+N2${\rm{Au}_{2}^{+}} {\rm{N}_{2}} $ and Au2+N2O${\rm{Au}_{2}^{+}} {\rm{N}_{2}{\rm{O}}} $

open access: yesNatural Sciences, Volume 3, Issue 1, January 2023., 2023
Vibrationally‐resolved optical spectra of Au2+N2${\rm{Au}_{2}^{+}} {\rm{N}_{2}} $ and Au2+N2O${\rm{Au}_{2}^{+}} {\rm{N}_{2}{\rm{O}}} $ allow for a detailed look at the binding motifs in the ground and excited states of these important metal complexes, opening the door for a systematic approach in the study of their reactivity.
Marko Förstel   +7 more
wiley   +1 more source

Vibrationally mediated photodissociation dynamics of pyrrole

open access: yesAIP Advances, 2019
We investigate photodissociation of vibrationally excited pyrrole molecules in a velocity map imaging experiment with IR excitation of N–H bond stretching vibration v1 = 1, νIR= 3532 cm−1, and UV photodissociation at λUV= 243 nm. In the IR+UV experiment,
Kateryna Grygoryeva   +5 more
doaj   +1 more source

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