Molecules with unpaired electrons, also known as open‐shell systems, are key intermediates in several light‐mediated or metal‐catalyzed transformations in organic chemistry. However, modeling this chemistry by density functional theory calculations is challenging.
Nil Sanosa +2 more
wiley +1 more source
All-visible-light-responsive porous aromatic frameworks manipulate CO<sub>2</sub> uptake by reversible bulk isomerization of azobenzene pendants. [PDF]
Sheng J +6 more
europepmc +1 more source
Single-engineered-residue solvation perturbations regulate global protein architecture and function. [PDF]
Liu Y +9 more
europepmc +1 more source
Recent Advances of Azobenzene-Based Photoresponsive Molecular Switches for Protein-Targeted Photopharmacology. [PDF]
Jiang J, Yuan X, Hu L.
europepmc +1 more source
MANGO‐“Fruitcage”: A Conditional Photocage Utilizing a Fluorescence Light‐Up Aptamer
Fruitcaging ‐ a proof of concept study of a conditional photocage (Thiazol‐Orange) activated upon binding to the fluorescence light up aptamer (Mango). The prolongation of the excited state lifetime explains the redirection of the reactive pathway toward photocleavage and provides a sensitive spectroscopic readout.
Konstantinos Stamatakis +6 more
wiley +1 more source
Light-Activated RPE65 Inhibitors Enable On-Demand Visual Cycle Control. [PDF]
Bassetto M +11 more
europepmc +1 more source
Therapeutic Applications of Stimuli‐Based Release and Engineering of Extracellular Vesicles
This review summarizes the effects of endogenous and exogenous stimuli, their effects on the natural release of extracellular vesicles, as well as their uptake and release. It also gives an overview of stimuli‐responsive EVs and their therapeutic applications. Extracellular vesicles (EVs), nano‐ to microsized lipid bilayer membrane‐bound particles, are
Gloria Kemunto, Kristen Dellinger
wiley +1 more source
Substituent Effects Govern the Efficiency of Isoxazole Photoisomerization to Carbonyl‑2<i>H</i>‑Azirines. [PDF]
Jackson KE +3 more
europepmc +1 more source
Recent Advances in Conjugation Chemistry Expanding the Applications of the DNA Tetrahedron
The tetrahedral DNA nanostructure (TDN) is a promising drug delivery and biosensing platform that can be chemically modified with absolute payload precision. This review highlights explicit conjugation chemistries driving functionalization of the TDN for a broad range of applications, advancing its role in support of next‐generation biomimetic ...
Tyler J. Rutherford +1 more
wiley +1 more source
Photoswitchable COX-2-Selective Inhibitors as Light-Regulated Anti-Inflammatory Agents. [PDF]
Morales A +17 more
europepmc +1 more source

