Results 31 to 40 of about 31,710 (279)

E/Z Molecular Photoswitches Activated by Two-Photon Absorption: Comparison between Different Families

open access: yesMolecules, 2021
Nonlinear optical techniques as two-photon absorption (TPA) have raised relevant interest within the last years due to the capability to excite chromophores with photons of wavelength equal to only half of the corresponding one-photon absorption energy ...
Marco Marazzi   +5 more
doaj   +1 more source

Tyrosine 263 in Cyanobacterial Phytochrome Cph1 Optimizes Photochemistry at the prelumi-R→lumi-R Step [PDF]

open access: yes, 2014
We report a low-temperature fluorescence spectroscopy study of the PAS-GAF-PHY sensory module of Cph1 phytochrome, its Y263F mutant (both with known 3D structures) as well as Y263H and Y263S to connect their photochemical parameters with intramolecular ...
Essen, Lars-Oliver   +7 more
core   +1 more source

Flipping the Switch: Fast Photoisomerization in a Confined Environment.

open access: yesJournal of the American Chemical Society, 2018
Stimuli-responsive materials are vital for addressing emerging demands in the advanced technology sector as well as current industrial challenges.
D.E Williams   +8 more
semanticscholar   +1 more source

Structural Evidence of Photoisomerization Pathways in Fluorescent Proteins.

open access: yesJournal of the American Chemical Society, 2019
Double-bond photoisomerization in molecules such as the green fluorescent protein (GFP) chromophore can occur either via a volume-demanding one-bond-flip pathway or via a volume-conserving hula-twist pathway.
Jeffrey Chang, M. Romei, S. Boxer
semanticscholar   +1 more source

Intraannular photoreactions in pseudo-geminally substituted [2.2]paracyclophanes

open access: yesBeilstein Journal of Organic Chemistry, 2011
The photoisomerization of the pseudo-geminal tetraene 11 furnishes the cyclooctadiene derivatives 13 and 15 with a completely new type of molecular bridge for a [2.2]paracyclophane which promise many interesting novel applications; the same is true for ...
Henning Hopf   +2 more
doaj   +1 more source

Regulation of the Switchable Luminescence of Tridentate Platinum(II) Complexes by Photoisomerization

open access: yesFrontiers in Chemistry, 2021
Organoplatinum (II) complexes are promising candidates for the construction of smart supramolecular materials due to their unique flat structures. This accompanied by intriguing luminescent properties, prompts the molecules to aggregate after external ...
Yongguang Li   +4 more
doaj   +1 more source

Stacking-induced fluorescence increase reveals allosteric interactions through DNA [PDF]

open access: yes, 2018
From gene expression to nanotechnology, understanding and controlling DNA requires a detailed knowledge of its higher order structure and dynamics. Here we take advantage of the environment-sensitive photoisomerization of cyanine dyes to probe local and ...
Lopez, Sergio G.   +4 more
core   +1 more source

Determining the Photoisomerization Quantum Yield of Photoswitchable Molecules in Solution and in the Solid State

open access: yesScientific Reports, 2017
Photoswitchable molecules are able to isomerize between two metastable forms through light stimuli. Originally being studied by photochemists, this type of molecule has now found a wide range of applications within physics, chemistry and biology.
Kati Stranius, Karl Börjesson
semanticscholar   +1 more source

Chloro- and Dichloro-methylsulfonyl Nitrenes: Spectroscopic Characterization, Photoisomerization, and Thermal Decomposition

open access: yesMolecules, 2018
Chloro- and dichloro-methylsulfonyl nitrenes, CH2ClS(O)2N and CHCl2S(O)2N, have been generated from UV laser photolysis (193 and 266 nm) of the corresponding sulfonyl azides CH2ClS(O)2N3 and CHCl2S(O)2N3, respectively.
Yang Yang   +4 more
doaj   +1 more source

Monitoring the photochemistry of a formazan over 15 orders of magnitude in time

open access: yesFrontiers in Chemistry, 2022
2,3,5-triphenyltetrazolium chloride (TTC) may convert into phenyl-benzo[c]tetrazolocinnolium chloride (PTC) and 1,3,5-triphenylformazan (TPF) under irradiation with light.
Svenja Wortmann   +2 more
doaj   +1 more source

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