Results 131 to 140 of about 49,559 (307)

Method Based on Continuous Artificial Dry and Humid UV Treatments to Reduce the Luminescence Background in the Raman Spectra of Plastics

Journal of Raman Spectroscopy, EarlyView.
We propose an UV photobleaching pretreatment to reduce the strong luminescence in the Raman spectra of plastic samples. Our protocol proves its efficiency whatever the luminescence origin (from the pigments or from a surface biofilm) but requires a careful optimization of the illumination conditions (UV wavelength, time, humidity) to reach the ...
L. Dewyspelaere, L. Belec, I. Martin, V. Lenoble, A. Ruediger, A. Merlen   +5 more
wiley   +1 more source

Fast photolysis of carbonyl nitrates from isoprene

, 2016
Photolysis is shown to be a major sink for isoprene-derived carbonyl nitrates, which constitute an important component of the total organic nitrate pool over vegetated areas.
Peeters, J., Müller, J.-F., Stavrakou, T.   +2 more
core   +1 more source

Kinetic Study on the Reaction of Phenylperoxy Radicals With Nitric Oxide

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT Cavity ring‐down spectroscopy (CRDS) and quantum cascade laser absorption spectroscopy (QCLAS), in conjunction with pulsed laser photolysis, were employed to investigate the reaction between phenylperoxy radicals (C6H5O2) and nitric oxide (NO) at a temperature of 296 ± 4 K. The experiment was carried out under N2 as bath gas.
Maya Matsushita, Michiya Fujita, Kenichi Tonokura   +2 more
wiley   +1 more source

Reaction Rate Coefficients and Adduct Formation in the Cl Atom + (E)‐CF3CF2CH=CHCF2CF3 Reaction

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT In this work, rate coefficients for the Cl‐atom + (E)‐CF3CF2CH═CHCF2CF3 (HFO‐153‐10mczz, F22E) gas‐phase reaction were measured as a function of temperature and pressure, k(243–323 K, 50–300 Torr), using a pulsed laser photolysis‐resonance fluorescence (PLP‐RF) technique.
Maria‐Areti I. Spanoudaki, Daniel Van Hoomissen, Vassileios C. Papadimitriou, James B. Burkholder   +3 more
wiley   +1 more source

One-electron oxidation and reduction of glycosaminoglycan chloramides: a kinetic study.

, 2013
Hypochlorous acid and its acid-base counterpart, hypochlorite ions, produced under inflammatory conditions, may produce chloramides of glycosaminoglycans, these being significant components of the extracellular matrix (ECM).
Parsons, BJ, Houee-Levin, C., Sibanda, S., Heyes, D. J.; id_orcid, Marignier, JL, Sibanda, S, Parsons, B. J., Marignier, J. L., Paterson, A. W J, Houee-Levin, C, Paterson, AW, Heyes, DJ   +11 more
core   +1 more source

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Cavity ring-down spectroscopic study of gas-phase photolysis of unsaturated dicarbonyls and aromatic aldehydes, and surface photolysis of acetaldehyde

, 2009
Photochemical smog is a phenomenon associated with pollution in urban atmospheres arising from the photochemical oxidation of volatile organic compounds (VOCs) in the presence of nitrogen oxides.
Xiang, Bin
core  

Effect of Accelerated Aging on the Performances of 3D Printed Polylactic Acid‐Polyhydroxyalkanoate Specimens

Polymer Engineering &Science, EarlyView.
The accelerated aging behaviours on the FFF‐fabricated PLA‐PHA Specimens. ABSTRACT Despite the increasing use of biodegradable polymers in additive manufacturing, their long‐term durability remains insufficiently understood. The aim of this study to investigate the influence of accelerated aging on the performance of fused filament fabrication‐printed ...
Han Xu, Jiayu Chen, Yinshi Lu, Handai Liu, Farnoosh McDonagh, Evert Fuenmayor, Ian Major, Genfu Xiao, Ke Gong   +8 more
wiley   +1 more source

The continuing significance of chiral agrochemicals

Pest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Combining Laser‐Induced Edition to Collision‐Induced Sequencing of Digital Oligomers in a Single Gas‐Phase Experiment

Rapid Communications in Mass Spectrometry, EarlyView.
ABSTRACT Rationale To increase the confidentiality level of molecular tags, binary information can be hidden in sequence‐defined oligomers using isobaric monomers including a photo‐sensitive one, which mass can be modified upon light irradiation. Reading such secured data requires light edition prior to MS/MS sequencing, which was investigated here in ...
Clothilde Comby‐Zerbino, Jean‐François Lutz, Luke MacAleese, Laurence Charles   +3 more
wiley   +1 more source