Atmospheric Chemistry of CF3C(Cl)═CH2 (HCFO‐1233xf)
ABSTRACT 2‐chloro‐3,3,3‐trifluoropropene, CF3C(Cl)═CH2 (HCFO‐1233xf), is a volatile hydrochlorofluoroolefin, commonly used in industrial synthesis of other halogenated olefins. Kinetics and reaction mechanisms for the reactions of OH radicals, Cl atoms, and O3 with CF3C(Cl)═CH2 were investigated using FTIR/smog chamber studies in 700 Torr of air/N2 ...
Bethanie Curiel +6 more
wiley +1 more source
From Carbon-Monoxide Inhibition to Light Activation: Probing [NiFe] Hydrogenase Dynamics by Multiscale Time-Resolved Infrared Spectroscopy. [PDF]
Khalil M +11 more
europepmc +1 more source
Seasonal Shifts in Nitrogen Isotope Fractionation Regimes in the Leighton Cycle
Abstract Nitrogen isotopes are used to trace nitrogen oxides (NOx = nitric oxide (NO) + nitrogen dioxide (NO2)) emissions and nitrate formation, but their interpretation depends on isotope redistribution during NO−NO2 cycling. A key uncertainty is whether this partitioning is controlled by equilibrium exchange or Leighton cycle.
Zeqian Liu +11 more
wiley +1 more source
Degradation of Perfluoroalkyl Acids under 222 nm Irradiation in the Presence and Absence of Sulfite. [PDF]
Jung B, McKay G.
europepmc +1 more source
Abstract Plumes from sulfur dioxide (SO2) point sources have been shown to be significant contributors to new particle formation (NPF), but SO2 emissions in the United States (US) have decreased drastically by ∼10× since the early 2000s. We present observations of plume‐scale NPF from SO2 point sources over the industrial hub in Gary, Indiana and ...
En Li +27 more
wiley +1 more source
Synthesis, characterization, and imidogen photochemistry of a hydrazoic acid adduct of Rh<sub>2</sub>. [PDF]
Paikar A +7 more
europepmc +1 more source
Encapsulation of Porphyrins in Polymer Microgels and Microbeads for Heterogeneous Photooxidation
Amino‐ or ammonium‐functionalized tetraphenylporphyrins were synthesized and encapsulated within polymers to form microgels and microbeads that act as heterogeneous photocatalysts. Photooxidation in aqueous media quantitatively converts sulfides and aldehydes into sulfoxides and carboxylic acids via the singlet‐oxygen pathway, demonstrating an ...
Imogen Smith +3 more
wiley +1 more source
UVA and UVB Photolysis of Natural and Synthetic Cannabinoids Studied by Online Mass Spectrometry. [PDF]
Shaikh ASA +3 more
europepmc +1 more source
The Study on Photolysis of Benzyl Compounds. Photolysis of Phenylacetonitrille.
OTA, Kazuo, HABU, Teiji
openaire +1 more source
Photosensitizing Au(I) Catalysis With Coumarins
A Au(I) complex with a tethered coumarin fragment was synthesized and characterized by UV‐vis and emission spectroscopy. Its ability to facilitate photo‐driven cross‐coupling reactions through single‐electron and energy transfer events was evaluated. ABSTRACT Gold catalysis shows versatility in a wide range of challenging transformations, wherein light‐
Liliana Capulín Flores +2 more
wiley +1 more source

