Results 81 to 90 of about 23,107 (206)

Rational Design Strategies for Stimuli‐Responsive DNAzymes Using Modified and Artificial Nucleotides

Chemistry – A European Journal, EarlyView.
Activity control of RNA‐cleaving DNAzymes in response to external stimuli has attracted growing interest for applications in DNA‐based diagnostics, therapeutics, and dynamic DNA nanotechnology. This review summarizes rational design strategies for stimuli‐responsive DNAzymes using modified or artificial nucleotides, including split and caged DNAzymes ...
Yusuke Takezawa, Mitsuhiko Shionoya
wiley   +1 more source

Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance

Chemistry – A European Journal, EarlyView.
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini, Daniele Lavelli, Alberto Dal Corso, Luca Pignataro   +3 more
wiley   +1 more source

flash photolysis

, 2014
Citation: 'flash photolysis' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.F02418 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +2 more sources

On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media

Chemistry – A European Journal, EarlyView.
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso, Alessia Zollo, Leonardo Palmisano, Stefano Livraghi, Francesco Parrino   +4 more
wiley   +1 more source

High‐throughput Photocatalytic Reactor With in Operando Characterisation for Fast Screening of Materials for the Photodegradation of Water‐Borne Pollutants

Advanced Materials Interfaces
A novel fast‐screening photocatalytic reactor system (FaS‐PhoReS) using simulated terrestrial sunlight is conceived and demonstrated. The instrument is capable of screening, automated data measurement and recording 32 samples at once with no external ...
Elisante Maloda Maloda, Likius Shipwiisho Daniel, Dmitry Busko, Andrey Turshatov, Justine Sageka Nyarige, Bryce Sydney Richards   +5 more
doaj   +1 more source

Single GAF Domain Phytochrome Exhibits a pH‐Dependent Shunt on the Millisecond Timescale

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
During their light‐induced photocycle, phytochromes can engage in a thermal reversion back to the initially excited state, denoted as a shunt. This study investigates a pH‐dependent shunt transition in the Pfr state of the All2699g1 phytochrome from Nostoc punctiforme using UV/Vis laser flash photolysis and kinetic modeling. The findings suggest a keto‐
Florian Trunk, Lisa Köhler, Tobias Fischer, Wolfgang Gärtner, Chen Song, Chavdar Slavov, Josef Wachtveitl   +6 more
wiley   +1 more source

Additives Promote Divergent Reactivity in Photolytic Deoxygenation and Lactonization Reactions of Cobalt Alkoxycarbonyls

European Journal of Organic Chemistry, EarlyView.
We report a carbonylation‐homolysis process to access acyl radicals that can undergo decarboxylation or cyclization onto tethered alkenes. In both cases, ligands and additives are shown to influence the outcome to give saturated or unsaturated products, in some cases with isomerization of the initial products.
Jacob N. Hackbarth, Dana R. Chambers, Cory T. Ludwig, Tyler K. Brown, David B. C. Martin   +4 more
wiley   +1 more source

Method Based on Continuous Artificial Dry and Humid UV Treatments to Reduce the Luminescence Background in the Raman Spectra of Plastics

Journal of Raman Spectroscopy, EarlyView.
We propose an UV photobleaching pretreatment to reduce the strong luminescence in the Raman spectra of plastic samples. Our protocol proves its efficiency whatever the luminescence origin (from the pigments or from a surface biofilm) but requires a careful optimization of the illumination conditions (UV wavelength, time, humidity) to reach the ...
L. Dewyspelaere, L. Belec, I. Martin, V. Lenoble, A. Ruediger, A. Merlen   +5 more
wiley   +1 more source

Evaluating Numerical Methods to Investigate Spectral Solar Radiative Transfer in Plant Canopies

Journal of Advances in Modeling Earth Systems
The disposition of spectral solar irradiance in plant canopies is crucially important to understand processes such as photolysis of molecules amenable to absorbing actinic light.
Zachary Moon, Jose D. Fuentes
doaj   +1 more source

Atmospheric Chemistry of CFH2CH2CH2CFH2: Kinetics and Mechanism of Reactions With Cl Atoms and OH Radicals

International Journal of Chemical Kinetics, EarlyView.
ABSTRACT The atmospheric chemistry of 1,4‐difluorobutane (CFH2CH2CH2CFH2) was investigated through a kinetic and mechanistic study of the reaction with chlorine (Cl) atoms and hydroxyl (OH) radicals. Using Fourier transform infrared (FTIR) spectroscopy and relative rate methods, the rate constants (k) for the reactions were determined at 298 ± 2 K as k(
Ellen R. Kjaergaard, Elena Jiménez, Connor Blair, Ole J. Nielsen, Mads P. Sulbaek Andersen   +4 more
wiley   +1 more source