Results 111 to 120 of about 482,822 (233)
Polymer brush-supported photoredox catalysis [PDF]
openVisible light organo-photoredox catalysis has demonstrated its enormous potential for enabling challenging chemical reactions while being a cheaper and greener alternative to transition metal-based catalysts.
AVANZINI, ELENA
core
Multiphoton photoredox catalysis enables selective hydrodefluorinations
Late-stage modification of complex molecules via site-selective hydrodefluorination is a challenging endeavor. The selective activation of carbon-fluorine (C–F) bonds in the presence of multiple C–F bonds is of importance in organic synthesis and drug ...
Murugesan, Kathiravan +5 more
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Allylation of aldehydes by dual photoredox and nickel catalysis
, 2019 Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a
Cozzi P. G. +9 more
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Nature CatalysisThe scope of nature’s catalytic abilities has been expanded by recent advancements in biocatalysis to include synthetic transformations with no biological equivalent.
Jin-Yan Rui +6 more
semanticscholar +1 more source
Catalytic Wacker-type Oxidations Using Visible Light Photoredox Catalysis
, 2019 A combined palladium/photoredox catalytic system for the efficient oxidation of terminal olefins to the corresponding methyl ketones is presented. The interplay of air, water, and light leads to a protocol in which the stoichiometric oxidants required ...
Rüping, Magnus +12 more
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Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H Functionalization
, 2016 Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H ...
Allison G. Condie (787886) +2 more
core +1 more source
An Eosin Y-catalyzed visible light-promoted 1,4-peroxidation–sulfonylation of enynones was achieved to give tetrasubstituted allenes. The photoredox catalysis of Eosin Y allowed the concomitant formation of peroxy and sulfonyl radicals, where the ...
Kosei Miyake (18296587) +4 more
core +2 more sources
A general deoxygenation approach for synthesis of ketones from aromatic carboxylic acids and alkenes
Nature Communications, 2018 Synthesis of aryl ketones can be generally achieved via C–C coupling strategies. Here, the authors show a deoxygenative coupling of carboxylic acids and alkenes enabled by photoredox catalysis and report a wide scope of products, including bioactive and ...
Muliang Zhang, Jin Xie, Chengjian Zhu
doaj +1 more source
Nature Communications, 2019 Alkenylpyridines are versatile building blocks for the synthesis of drugs and other complex molecular structures. Here, the authors show a branch-selective pyridylation of alkenes via sulfinate-assisted photoredox catalysis and showcase its utility in an
Shengqing Zhu +4 more
doaj +1 more source
Photoredox-Catalyzed Multicomponent Petasis Reaction with Alkyltrifluoroborates
, 2019 A redox-neutral alkyl Petasis reaction has been developed that proceeds via photoredox catalysis. A diverse set of primary, secondary, and tertiary alkyltrifluoroborates participate effectively in this reaction through a single-electron transfer ...
Rauful Alam (1286283) +7 more
core +1 more source