Results 131 to 140 of about 13,653 (246)

Advances in the Different Synthetic Routes of Fluorinated Hydrazines

The Chemical Record, EarlyView.
This review highlights the various routes to the preparation of fluorinated hydrazines, thereby promoting the exploration of innovative methods for the synthesis of new N‐fluorinated hydrazines. Their synthesis mainly involves synthetic routes such as organometallic, organocatalytic, and photocatalytic.
Dimitra Kyrko, Benoît Crousse
wiley   +1 more source

Facile Access to N‐Substituted Pyridyl Ligands

Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
A modular, robust, and versatile Buchwald–Hartwig amination protocol that enables the rapid synthesis of bipyridine, phenanthroline, terpyridine, and pybox ligands bearing dialkylamine, diarylamine, and heteroaromatic N‐substituents. Pyridyl motifs equipped with N‐substituents can be powerful ligands for catalysis, yet their broader adoption is limited
Adam Petrik, Aleksander R. Bena, Haralds Baunis, Riley M. Kelch, Tehshik P. Yoon, Bartholomäus Pieber   +5 more
wiley   +1 more source

Transition Metal‐Catalyzed Functionalization of Nonallylic Alkenyl Alcohols via Chain‐Walking Strategies

Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
This minireview outlines recent advances in chain‐walking reactions of nonallylic alkenyl alcohols catalyzed by various transition metals, including palladium, ruthenium, rhodium, iridium, and nickel. Furthermore, the corresponding reaction mechanisms are discussed.
Yong Huang, Chong Liu, Jasmine X. Yan, Md Sajib Joardar, Ke Yang, Haibo Ge   +5 more
wiley   +1 more source

Base Metal Meets Photoredox Chemistry – Advances in Fully Catalytic Metal-Catalyzed Hydrogen Atom Transfer Reactions

CHIMIA
Metal-catalyzed hydrogen atom transfer (MHAT) has become a valuable approach for the functionalization of alkenes and toward complex molecular structures.
Willi M. Amberg, Erick M. Carreira
doaj   +1 more source

A Cathodic Hydrogen Atom Transfer Strategy for Electrochemical Carboxylation of Dibenzylic C(sp3)H Bonds With CO2

ChemElectroChem, Volume 13, Issue 9, 5 May 2026.
A cathodically generated hydrogen atom transfer (HAT) strategy for the electrochemical carboxylation of dibenzylic C(sp3)H bonds with CO2 is developed. This strategy enables all key steps to occur at the same cathode, allowing efficient carboxylation under mild conditions.
Yuto Maeji, Toshimichi Kobayashi, Kento Kosugi, Yutaka Saga, Masanari Hirahara, Mio Kondo, Tetsuya Kambe, Shigeyuki Masaoka   +7 more
wiley   +1 more source

Photoinduced Selective Construction of Densely Functionalized Spirocyclic Ethers With Carbyne Equivalents

Angewandte Chemie, Volume 138, Issue 18, 27 April 2026.
A reactivity programmed cascade between carbyne equivalents and allylic benzoates was developed that sequentially orchestrates all three reactivity modes of carbyne equivalents, enabling the rapid installation of three σ‐bonds at a single carbon center and providing efficient, scalable access to structurally diverse spirocyclic ethers. ABSTRACT Carbyne
Jianke Su, Chu Wang, Zhongping Cai, Jiale Wu, Xu Yan Chen, Jie Wu   +5 more
wiley   +2 more sources

Alkene Diversification through a Molecular Recasting Strategy Enabled by N-Heterocyclic Carbene and Photoredox Dual Catalysis

Research
Alkenes are fundamental structural motifs in organic synthesis, valued for their prevalence in natural products and their broad reactivity profile. While traditional de novo synthesis offers access to diverse alkene frameworks, strategies enabling the ...
Qing-Zhu Li, Mei-Hao He, Peng-Tao Wang, Dong-Yang Xiang, Long-Hai Hong, Rong Zeng, Jun-Long Li   +6 more
doaj   +1 more source

Direct Mechanoorganocatalysis via Surface Functionalization of Milling Reactors With Amine Functions

ChemistryEurope, Volume 4, Issue 5, May 2026.
Surface functionalization of milling jars in epoxy resin furnished reactive milling jars, able to perform direct mechanoorganocatalysis with high efficiency, recyclability, and simplified purification. This proof of concept was applied successfully to base‐catalyzed Knoevenagel condensation and multicomponent reactions.
Joao Tanepau, Maxime Provost, Marie Gressier, Marie‐Joëlle Menu, Sandrine Duluard, Frédéric Lamaty, Julien Pinaud, Xavier Bantreil   +7 more
wiley   +1 more source

Regioselective Tele‐Substitution of Aroyl Chlorides via Activation by an Al/P Frustrated Lewis Pair

ChemistryEurope, Volume 4, Issue 5, May 2026.
A tele‐substitution of aroyl chlorides with silyl ketene acetals is enabled by an ortho‐phenylene‐linked Al/P frustrated Lewis pair. Intramolecular aluminum activation polarizes the aroylphosphonium intermediate, promoting regioselective dearomative nucleophilic addition to the aromatic ring.
Hirotaka Okamoto, Yoshihiro Nishimoto, Makoto Yasuda   +2 more
wiley   +1 more source

Photochemistry of (‐)‐Levoglucosenone: Norrish Type I Reaction and Photoinduced Electron Transfer Processes

ChemPhotoChem, Volume 10, Issue 5, May 2026.
Photochemically excited levoglucosenone (LGO) efficiently undergoes Norrish type I reactions yielding particularly functionalized alkenes. In the presence of tertiary amines, this reaction is quenched by an intermolecular electron transfer. This process leads to addition products with high stereoselectivity.
Mario Andrés Gomez Fernandez, Mohammed Latrache, Gilles Lemercier, Clémence Allain, Florent Allais, Manabu Abe, Norbert Hoffmann   +6 more
wiley   +1 more source