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The forgotten reagent of photoredox catalysis

Dalton Transactions, 2022
Light is a critical reagent in photochemical synthesis but rarely considered beyond on or off controls. This Frontier article highlights recent examples where photon delivery is controlled, affording unique reactivity.
openaire   +2 more sources

A Borocarbonitride Ceramic Aerogel for Photoredox Catalysis

Angewandte Chemie - International Edition, 2019
AbstractBorocarbonitride (BCN) is a new type of photocatalyst, but bulk BCN shows a large band gap, and low surface area, and moderate activity for photocatalysis. Here, a three‐dimensional (3D) porous ceramic BCN aerogel was developed as an effective photocatalyst for relevant reactions.
Yuanxing Fang, Xinchen Wang, Min Zhou
exaly   +3 more sources

Visible‐Light Photoredox Catalysis

Angewandte Chemie International Edition, 2012
AbstractIn the last few years, visible‐light initiated organic transformations have attracted increasing attention. The development of visible‐light‐promoted photocatalytic reactions, which enable rapid and efficient synthesis of fine chemicals, is highly desirable from the viewpoint of cost, safety, availability, and environmental friendliness.
Jun, Xuan, Wen-Jing, Xiao
openaire   +2 more sources

Organic Photoredox Catalysis

2022
Organic photoredox catalysis is a powerful light-driven synthetic technology enabling the development of a diverse number of organic free radical reactions. It has had a substantial impact on organic synthesis, materials science and pharmaceutical chemistry and will be an essential method for looking at future research developments.
Hans-Achim Wagenknecht, Todd Hyster
openaire   +1 more source

Applications of red light photoredox catalysis in organic synthesis.

Organic and biomolecular chemistry, 2023
Photoredox catalysis has emerged as an efficient and versatile approach for developing novel synthetic methodologies. Particularly, red light photocatalysis has attracted more attention due to its intrinsic advantages of low energy, few health risks, few
Alexander Schade, Liangyong Mei
semanticscholar   +1 more source

Efficient super-reducing organic photoredox catalysis with proton-coupled electron transfer mitigated back electron transfer.

Science
Photoredox catalysis driven by visible light has improved chemical synthesis by enabling milder reaction conditions and unlocking distinct reaction mechanisms.
Amreen K. Bains   +9 more
semanticscholar   +1 more source

Shining a Light on the Advances, Challenges and Realisation of Utilising Photoredox Catalysis in Pharmaceutical Development

ChemCatChem, 2023
Photoredox catalysis has advanced significantly over the last fifteen years, with improvements in technology facilitating implementation in both academic and industrial settings.
Emily E. Callard‐Langdon   +2 more
semanticscholar   +1 more source

Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis.

Chemical Reviews, 2021
Recent progress in the development of photocatalytic reactions promoted by visible light is leading to a renaissance in the use of photochemistry in the construction of structurally elaborate organic molecules.
S. P. Pitre, L. Overman
semanticscholar   +1 more source

Enantioselective [2π + 2σ] Cycloadditions of Bicyclo[1.1.0]butanes with Vinylazaarenes through Asymmetric Photoredox Catalysis.

Journal of the American Chemical Society
Here we present a highly enantioselective [2π + 2σ] photocycloaddition of bicyclo[1.1.0]butanes (BCBs). The reaction uses a variety of vinylazaarenes as partners and is catalyzed by a polycyclic aromatic hydrocarbon (PAH)-containing chiral phosphoric ...
Qianqian Fu   +6 more
semanticscholar   +1 more source

Photoredox catalysis over semiconductors for light-driven hydrogen peroxide production

, 2021
Hydrogen peroxide (H2O2) is a commodity chemical applied in diverse products and industries. Nevertheless, its current industrial production process is not sustainable.
Xiangkang Zeng   +3 more
semanticscholar   +1 more source

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