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Journal of the American Chemical Society
Although photoredox catalysis is complex from a mechanistic point of view, it is also often surprisingly efficient. In fact, the quantum efficiency of a puzzlingly large portion of photoredox reactions exceeds 100% (i.e., the measured quantum yields (QYs)
Igor V. Alabugin +3 more
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Although photoredox catalysis is complex from a mechanistic point of view, it is also often surprisingly efficient. In fact, the quantum efficiency of a puzzlingly large portion of photoredox reactions exceeds 100% (i.e., the measured quantum yields (QYs)
Igor V. Alabugin +3 more
semanticscholar +1 more source
Conditionally Activatable Photoredox Catalysis in Living Systems.
Journal of the American Chemical Society, 2021The transformational effect of photoredox catalytic chemistries has inspired new opportunities, enabling us to interrogate nature in ways that are not possible otherwise and to unveil new biotechnologies in therapy and diagnosis.
Ming-Le Li +7 more
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Photoredox Catalysis Is On A Roll
Chemical & Engineering News Archive, 2015The practice of using light to drive catalytic reactions is hotter than ever. The field of photoredox catalysis may trace its origins back to the late 1970s, but its popularity has grown considerably over the past five years. Most recently, David W. C.
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Generating carbyne equivalents with photoredox catalysis
Nature, 2018Carbon has the unique ability to bind four atoms and form stable tetravalent structures that are prevalent in nature. The lack of one or two valences leads to a set of species-carbocations, carbanions, radicals and carbenes-that is fundamental to our understanding of chemical reactivity.
Zhaofeng, Wang +3 more
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Metal‐Free Carbonylations by Photoredox Catalysis
Angewandte Chemie International Edition, 2014AbstractThe synthesis of benzoates from aryl electrophiles and carbon monoxide is a prime example of a transition‐metal‐catalyzed carbonylation reaction which is widely applied in research and industrial processes. Such reactions proceed in the presence of Pd or Ni catalysts, suitable ligands, and stoichiometric bases.
Michal, Majek, Axel, Jacobi von Wangelin
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Journal of the American Chemical Society
The catalytic and enantioselective construction of quaternary (all-carbon substituents) stereocenters poses a formidable challenge in organic synthesis due to the hindrance caused by steric factors.
Lian-Jie Li +7 more
semanticscholar +1 more source
The catalytic and enantioselective construction of quaternary (all-carbon substituents) stereocenters poses a formidable challenge in organic synthesis due to the hindrance caused by steric factors.
Lian-Jie Li +7 more
semanticscholar +1 more source
Journal of the American Chemical Society
Herein, we designed a reaction for the desymmetrization-addition of cyclopropenes to imines by leveraging the synergy between photoredox and asymmetric cobalt catalysis.
Xiang-Kui He +5 more
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Herein, we designed a reaction for the desymmetrization-addition of cyclopropenes to imines by leveraging the synergy between photoredox and asymmetric cobalt catalysis.
Xiang-Kui He +5 more
semanticscholar +1 more source
Photoredox Catalysis for Organic Syntheses
Advanced Synthesis & Catalysis, 2013AbstractCurrent examples of photoredox catalytic processes for CO, CN, CHal and CC bond formation are described with emphasis on the basic mechanistic scenarios. The focus is on the special aspects of photochemical redox catalysis especially on the electron transfer energetics, the use of electron transfer (ET) sensitizers and mediators as well as ...
Melissa Reckenthäler, Axel G. Griesbeck
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Allylsilane as a versatile handle in photoredox catalysis
Chemical CommunicationsThis review briefly summarizes the utilization of allylsilane in photoredox catalysis. It highlights the underlying mechanisms for the formation of the C–C/C–heteroatom bond with various functionalities in mild conditions with high selectivity.
Nand Lal +4 more
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Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chemical Reviews, 2022David W. C. MacMillan +2 more
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