Results 61 to 70 of about 13,653 (246)

Laser‐Assisted Phase Engineering of 2D MoS2 for Efficient Solution‐Processed Electronics

Advanced Materials, EarlyView.
Here, local laser‐assisted phase transition from solution‐processed phase‐pure 1T′ to 2H MoS2 is shown to critically depend on the irradiation atmosphere. While processing in air leads to damaged insulating regions, inert conditions yield semiconducting 2H domains, enabling direct field‐effect transistor patterning with optimized lateral 1T′‐2H MoS2 ...
Anna Zhuravlova, Minjuan Li, Osamah Alharbi, Yeonsu Jeong, Bin Han, Lei Gao, Mischa Bonn, Mario Lanza, Sheng Yang, Antonio Gaetano Ricciardulli, Paolo Samorì   +10 more
wiley   +1 more source

Photoredox Catalysis in Organic Chemistry

The Journal of Organic Chemistry, 2016
In recent years, photoredox catalysis has come to the forefront in organic chemistry as a powerful strategy for the activation of small molecules. In a general sense, these approaches rely on the ability of metal complexes and organic dyes to convert visible light into chemical energy by engaging in single-electron transfer with organic substrates ...
Shaw, Megan H., Twilton, Jack, MacMillan, David W. C.   +2 more
openaire   +2 more sources

Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor

Nature Communications, 2022
Sulfonyl fluorides are compounds with potential application in chemical biology and drug discovery, but their preparation can be challenging. Here, the authors present a type of bench-stable fluorosulfonyl radical reagents that enable radical ...
Peng Wang, Honghai Zhang, Xingliang Nie, Tianxiao Xu, Saihu Liao   +4 more
doaj   +1 more source

Synthetic strategies for 5- and 6-membered ring azaheterocycles facilitated by iminyl radicals [PDF]

, 2016
The author thanks EaStCHEM for financial support.The totality of chemical space is so immense that only a small fraction can ever be explored. Computational searching has indicated that bioactivity is associated with a comparatively small number of ring ...
Walton, John Christopher
core   +2 more sources

Shaping Carbon Nitrides for Advanced Macrostructures

Advanced Materials Technologies, EarlyView.
This review examines how carbon nitride can be shaped through a range of printing and interfacial assembly methods. By bringing together additive manufacturing and liquid–liquid structuring concepts, carbon nitride is moving beyond its traditional powder‐based photocatalyst form toward digitally designed robust macroscale architectures with high design
Simona Baluchová, Baris Kumru
wiley   +1 more source

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis [PDF]

Angewandte Chemie International Edition, 2016
Abstract A method for the decarboxylative macrocyclization of peptides bearing N‐terminal Michael acceptors has been developed. This synthetic method enables the efficient synthesis of cyclic peptides containing γ‐amino acids and is tolerant of functionalities present in both natural and non‐proteinogenic amino acids.
Stefan J, McCarver, Jennifer X, Qiao, Joseph, Carpenter, Robert M, Borzilleri, Michael A, Poss, Martin D, Eastgate, Michael M, Miller, David W C, MacMillan   +7 more
openaire   +2 more sources

Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis

Nature Communications, 2021
Hydrogen atom transfer (HAT) hydrogenation of alkenes usually requires stoichiometric silanes and peroxides. Here, the authors report a silane- and peroxide-free HAT hydrogenation method using a combined cobalt/photoredox catalysis and vitamin C as a ...
Yuji Kamei, Yusuke Seino, Yuto Yamaguchi, Tatsuhiko Yoshino, Satoshi Maeda, Masahiro Kojima, Shigeki Matsunaga   +6 more
doaj   +1 more source

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. [PDF]

, 2015
Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient ...
Jamison, Christopher R, MacMillan, David WC, Nawrat, Christopher C, Overman, Larry E, Slutskyy, Yuriy   +4 more
core  

The Development of Visible‐Light Photoredox Catalysis in Flow [PDF]

, 2014
Visible‐light photoredox catalysis has recently emerged as a viable alternative for radical reactions otherwise carried out with tin and boron reagents. It has been recognized that by merging photoredox catalysis with flow chemistry, slow reaction times,
Andrews, Bou-Hamdan, Bou-Hamdan, Chen, Condie, Dai, Freeman, Furst, Garegg, Goodell, Hernandez-Perez, Hook, Jas, Knowles, Larraufie, Lévesque, Lévesque, Narayanam, Narayanam, Neumann, Neumann, Nguyen, Nguyen, Nguyen, Nicewicz, Prier, Rueping, Trommsdorff, Tucker, Tucker, Tucker, Wang, Webb, Yoon   +33 more
core   +1 more source

Cyclodextrin‐Functionalized Light‐Driven Cu2O Micromotors for Simultaneous Capture and Degradation of Bisphenol A

Advanced Robotics Research, EarlyView.
Fuel‐free Cu2O‐based micromotors functionalized with β‐cyclodextrin actively remove bisphenol A from water under visible light. The cyclodextrin shell captures BPA and enhances micromotor motility, leading to faster degradation and higher overall removal than nonfunctionalized Cu2O and Cu2O@Au.
Luisa Natalia Cordoba Urresti, Rebeca Ferrer Campos, Yufen Chen, Katherine Villa   +3 more
wiley   +1 more source