Results 181 to 190 of about 18,776 (234)

Organometallic Half-Sandwich Complexes of 8-Hydroxyquinoline-Derived Mannich Bases with Enhanced Solubility: Targeting Multidrug Resistant Cancer. [PDF]

open access: yesInorg Chem
Pivarcsik T   +11 more
europepmc   +1 more source

Cyclometalated complexes: promising metallodrugs in the battle against cancer. [PDF]

open access: yesRSC Med Chem
Amaya-Flórez A   +9 more
europepmc   +1 more source
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Reactivity of a Piano-Stool Iron Complex toward Boranes

Organometallics, 2023
Qiuming Liang   +2 more
semanticscholar   +2 more sources

Strong intermolecular interactions shaping a small piano-stool complex.

open access: yesAngewandte Chemie International Edition, 2013
The smallest piano stool [CpNa(NH3)3] is not a stand‐alone unit in the solid state but is largely shaped by strong intermolecular NH⋅⋅⋅π interactions. Small but important structural features, such as the bending of the CH bonds inwards to the sodium atom that was confirmed by experimental charge density investigations, could only be reproduced by ...
J. Hey   +4 more
semanticscholar   +4 more sources

Rotational Behavior in Piano Stool Ru(II) Complexes with Bulky-Substituted Cyclopentadienyl Ligands

open access: yesACS Organic & Inorganic Au
In this study, we designed and synthesized a series of novel piano stool ruthenium complexes featuring bulky substituents on the cyclopentadienyl (Cp) ligand to investigate how the substituent structure affects rotational behavior around the Cp–Ru bond ...
Naoki Ito   +5 more
semanticscholar   +2 more sources

Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex.

Angewandte Chemie International Edition, 1999
A transition metal Lewis acid with metal-centered chirality is obtained by η6 :η1 :η1 coordination of a 1,3-disubstituted arene with a phosphane and a pyrazole tether (PArN) to ruthenium. The three-legged piano-stool complex [{η6 :η1 :η1 -(PArN)}Ru(H2 O)]2+ (structure depicted) displays remarkable configurational stability.
B. Therrien, T. Ward
semanticscholar   +5 more sources

Positional and compositional disorder in a ruthenium(II) piano-stool complex.

Acta Crystallographica Section C Crystal Structure Communications, 2013
In (η6-p-cymene)(difluorophosphinato-κO){2-[(1H-pyrazol-1-yl)methyl-κN2]pyridine-κN}ruthenium(II) 0.85-hexafluorophosphate 0.15-tetrafluoroborate, [Ru(PO2F2)(C10H14)(C9H9N3)](PF6)0.85(BF4)0.15, (I), the [PO2F2]−ligand exhibits positional disorder due to one F atom and one O atom sharing the same two positions related by a mirror reflection across the O—
I. Guzei   +3 more
semanticscholar   +3 more sources

Synthesis, characterization and HSA interactions of a new piano-stool ruthenium(II) complex containing a thioamide-type ligand

Book of Proceedings, 2023
The synthesis and characterization of a newly synthesized piano-stool [Ru-(ɳ6-p-cymene)Cl2L] complex with a ligand 3-amino-2-cyano-N-phenyl-3-(4-phenyl-1-piperazinyl)-2-propenethioamide are presented.
D. Stojković   +6 more
semanticscholar   +1 more source

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