The Role of Metallodrugs in Enhancing Neuroendocrine Neoplasm Therapies: The Promising Anticancer Potential of Ruthenium-Based Complexes. [PDF]
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Organometallic Half-Sandwich Complexes of 8-Hydroxyquinoline-Derived Mannich Bases with Enhanced Solubility: Targeting Multidrug Resistant Cancer. [PDF]
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Cyclometalated complexes: promising metallodrugs in the battle against cancer. [PDF]
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Reactivity of a Piano-Stool Iron Complex toward Boranes
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Strong intermolecular interactions shaping a small piano-stool complex.
The smallest piano stool [CpNa(NH3)3] is not a stand‐alone unit in the solid state but is largely shaped by strong intermolecular NH⋅⋅⋅π interactions. Small but important structural features, such as the bending of the CH bonds inwards to the sodium atom that was confirmed by experimental charge density investigations, could only be reproduced by ...
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Rotational Behavior in Piano Stool Ru(II) Complexes with Bulky-Substituted Cyclopentadienyl Ligands
In this study, we designed and synthesized a series of novel piano stool ruthenium complexes featuring bulky substituents on the cyclopentadienyl (Cp) ligand to investigate how the substituent structure affects rotational behavior around the Cp–Ru bond ...
Naoki Ito +5 more
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Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex.
Angewandte Chemie International Edition, 1999A transition metal Lewis acid with metal-centered chirality is obtained by η6 :η1 :η1 coordination of a 1,3-disubstituted arene with a phosphane and a pyrazole tether (PArN) to ruthenium. The three-legged piano-stool complex [{η6 :η1 :η1 -(PArN)}Ru(H2 O)]2+ (structure depicted) displays remarkable configurational stability.
B. Therrien, T. Ward
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Positional and compositional disorder in a ruthenium(II) piano-stool complex.
Acta Crystallographica Section C Crystal Structure Communications, 2013In (η6-p-cymene)(difluorophosphinato-κO){2-[(1H-pyrazol-1-yl)methyl-κN2]pyridine-κN}ruthenium(II) 0.85-hexafluorophosphate 0.15-tetrafluoroborate, [Ru(PO2F2)(C10H14)(C9H9N3)](PF6)0.85(BF4)0.15, (I), the [PO2F2]−ligand exhibits positional disorder due to one F atom and one O atom sharing the same two positions related by a mirror reflection across the O—
I. Guzei +3 more
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The synthesis and characterization of a newly synthesized piano-stool [Ru-(ɳ6-p-cymene)Cl2L] complex with a ligand 3-amino-2-cyano-N-phenyl-3-(4-phenyl-1-piperazinyl)-2-propenethioamide are presented.
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