Results 31 to 40 of about 10,633,910 (143)

Prism[5]MaxQ: A Sulfated Prism[5]Arene and Its Molecular Recognition Properties Toward a Panel of Quaternary Ammonium Guests

Chemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino, Lyle Isaacs   +1 more
wiley   +1 more source

Carbon monoxide adsorption on NaY zeolite and impregnated with 5% niobium: Characteristics and fixed‐bed study

The Canadian Journal of Chemical Engineering, EarlyView.
Schematic of the CO adsorption process in a fixed‐bed column containing pure NaY zeolite and Nb‐modified NaY (NaY–5%Nb). On the left, breakthrough curves and temperature profiles highlight the dynamic performance and thermal effects during CO adsorption.
Elson Oliveira, Karina Querne de Carvalho, Erika Pereira Felix, Roberta C. P. Rizzo‐Domingues   +3 more
wiley   +1 more source

]arenes

, 2014
ConspectusMacrocyclic chemistry has relied on the dominance of some key cavitands, including cyclodextrins, calixarenes, cyclophanes, and cucurbiturils, to advance the field of host-guest science.
J. Fraser Stoddart, Stoddart, J. Fraser, Severin T. Schneebeli, Zhang, Huacheng, Nathan L. Strutt, Huacheng Zhang, Strutt, Nathan L., Schneebeli, Severin T.   +7 more
core   +1 more source

A Biocompatible Liquid Pillar[n]arene-Based Drug Reservoir for Topical Drug Delivery

Pharmaceutics, 2022
Advanced external preparations that possess a sustained-release effect and integrate few irritant elements are urgently needed to satisfy the special requirements of topical administration in the clinic. Here, a series of liquid pillar[n]arene-bearing varying-length oligoethylene oxide chains (OEPns) were designed and synthesized. Following rheological
Yahan Zhang, Mengke Ma, Longming Chen, Xinbei Du, Zhao Meng, Han Zhang, Zhibing Zheng, Junyi Chen, Qingbin Meng   +8 more
openaire   +3 more sources

AI‐Driven Synthesis in Medicinal Chemistry: Integrating Large Language Models, Robotic Automation, and Sustainability Metrics to Accelerate Drug Discovery

Medicinal Research Reviews, EarlyView.
ABSTRACT Artificial intelligence (AI) is transforming synthetic chemistry from task‐specific predictors into integrated platforms that unify retrosynthesis, reaction optimization, and closed‐loop robotic automation. This review highlights how AI‐assisted planning and robotic execution shorten cycle times, reduce step counts, and improve route ...
Amit Gangwal, Antonio Lavecchia
wiley   +1 more source

White light emitting molecular logic gates

Smart Molecules, EarlyView.
White light emitting smart molecules with Boolean logic computing ability are surveyed. Abstract White light emitting (WLE) materials are of considerable interest with commercial and societal applications in video displays and lighting devices. A characteristic property of WLE materials is the luminescence profile spanning from 380 to 700 nm.
Davide Benedetto Tiz, Massimo Catania, David C. Magri   +2 more
wiley   +1 more source

Catalytic Enantioselective Synthesis of Planar Chiral Pillar[5]arenes via Asymmetric Sonogashira Coupling

As a novel type of macrocycles with attractive planar chirality, pillar[5]arenes have gained increasing research interest over the past decades, enabling their widespread applications in diverse fields such as porous materials, molecular machines, and ...
Lin-Tao, Bao, Wei, Wang, Hai-Bo, Yang, Xin, Zhang, Xue , Li, Xu-Qing, Wang, Xiao-Hua, Zhou, Yi-Ru, Song, Wei-Tao, Xu   +8 more
core   +1 more source

The Non‐Understandable World of Autism Spectrum Disorder: A Therapist's Implicit Understanding and Subsequent Deepened Understanding

Journal of Analytical Psychology, EarlyView.
Abstract This paper examines the concept of non‐understandable in psychotherapy, based on the author's own play therapy with a boy with mild ASD (autism spectrum disorder). ASD is considered to belong to an area beyond comprehension, as psychotherapy is often deemed ineffective for it.
Toshio Kawai
wiley   +1 more source

Synthesis and Conformational Characteristics of Alkyl-Substituted Pillar[5]arenes

, 2016
A series of pillar[5]arene derivatives with alkyl groups of different length were synthesized. The new alkyl-substituted pillar[5]arene derivatives 1,4-bis(ethoxy)pillar[5]arene (C2), 1,4-bis(propoxy)pillar[5]arene (C3), 1,4-bis(butoxy)pillar[5]arene (C4)
Takamichi Aoki (1269240), Shuhei Fujinami (1748545), Tomoki Ogoshi (1269234), Keisuke Kitajima (1269243), Yoshiaki Nakamoto (1269231), Tada-aki Yamagishi (1269237)   +5 more
core   +2 more sources

Pillar[5]arenes: fascinating cyclophanes with a bright future

, 2012
Pillar[5]arenes are [15]paracyclophane derivatives consisting of 1,4-disubstituted hydroquinones linked by methylene bridges in the 2,5-positions. The first report of these novel macrocycles was in 2008, when 1,4-dimethoxypillar[5]arene was prepared in ...
Sharma, Kushal, Kushal Sharma, Peter J. Cragg, Cragg, Peter; id_orcid   +3 more
core   +1 more source