Results 41 to 50 of about 10,633,910 (143)

Stereoselective Single Step Cyclization to Give Belt-Functionalized Pillar[6]arenes

open access: yes
Two macrocycles were synthesized through cyclization reactions of secondary benzylic alcohols, giving pillar[6]­arenes with a methyl substituent at each belt position.
Zeke Coady (17780706)   +3 more
core   +6 more sources

Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 25, 15 June 2026.
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George   +13 more
wiley   +1 more source

Supramolecular chemistry of pillar[n]arenes functionalised by a copper(i)-catalysed alkyne–azide cycloaddition “click” reaction

open access: yes, 2017
We discuss the functionalization of pillar[n]arenes using copper(i)-catalysed alkyne–azide cycloaddition (CuAAC) “click” chemistry.
T. Ogoshi, T. Kakuta, T. Yamagishi
core   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 16, 4 June 2026.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa   +8 more
wiley   +1 more source

Structural and Chemical Engineering of Sub‐Nanochannel Membranes Toward Ion Selectivity

open access: yesAdvanced Functional Materials, Volume 36, Issue 46, 8 June 2026.
This review summarizes recent advances in structural and chemical engineering of sub‐nanochannels for ion selectivity. We first introduce fundamental ion transport mechanisms within sub‐nanochannels, followed by strategies to tune pore size, geometry, and surface functionalities, categorized into charge‐based, ion‐recognition, hydrophilic bonding, and ...
Yuyu Su   +5 more
wiley   +1 more source

Intelligent Molecular Recognition in Hydrogen‐Bond‐Mediated Supramolecular Polyhedra

open access: yesSmartMat, Volume 7, Issue 3, June 2026.
This perspective highlights the construction of sophisticated hydrogen‐bonded supramolecular polyhedra from macrocycles by emulating the hierarchical assembly of ferritin and viral capsids, and summarizes their selective recognition of individual guest molecules as well as the synergistic encapsulation of multiple species, demonstrating their potential
Ran‐Qi Chen   +3 more
wiley   +1 more source

Modular Strategy for Constructing para-Cage[n]arenes, meta-Cage[n]arenes, and meta-Bimacrocyclic-Arenes

open access: yes
Here, we present a versatile modular strategy for crafting novel covalent organic cages (para-cage[n]arenes and meta-cage[n]arenes, n = 3,4) and bimacrocycles (meta-bimacrocyclic-arenes) with stable backbones and modifiable rims.
Qihan Lin (17854824)   +5 more
core   +1 more source

Pillar-pipette assay.

open access: yes, 2021
(a) Cartoon showing two pairs of pre-existing (18 hrs) doublets adhering to each other through a junction established after 1 hr (red, shown by the square box). The doublets are attached to a pillar tip and are pulled by a micropipette to the left.
Yeh Shiu Chu (11868689)   +7 more
core   +1 more source

Towards Universal Stimuli-Responsive Drug Delivery Systems: Pillar[5]arenes Synthesis and Self-Assembly into Nanocontainers with Tetrazole Polymers

open access: yes, 2021
In this work, we have proposed a novel universal stimulus-sensitive nanosized polymer system based on decasubstituted macrocyclic structures—pillar[5]arenes and tetrazole-containing polymers.
Daut R. Islamov   +7 more
core   +1 more source

Clickable Di- and Tetrafunctionalized Pillar[n]arenes (n = 5, 6) by Oxidation–Reduction of Pillar[n]arene Units

open access: yes, 2016
We report a new route for the selective synthesis of di- and tetrafunctionalized pillararenes via oxidation and reduction of the pillararene units.
Takamichi Aoki (1269240)   +5 more
core   +2 more sources

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