Results 41 to 50 of about 10,633,910 (143)
Stereoselective Single Step Cyclization to Give Belt-Functionalized Pillar[6]arenes
Two macrocycles were synthesized through cyclization reactions of secondary benzylic alcohols, giving pillar[6]arenes with a methyl substituent at each belt position.
Zeke Coady (17780706) +3 more
core +6 more sources
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George +13 more
wiley +1 more source
We discuss the functionalization of pillar[n]arenes using copper(i)-catalysed alkyne–azide cycloaddition (CuAAC) “click” chemistry.
T. Ogoshi, T. Kakuta, T. Yamagishi
core +1 more source
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa +8 more
wiley +1 more source
Structural and Chemical Engineering of Sub‐Nanochannel Membranes Toward Ion Selectivity
This review summarizes recent advances in structural and chemical engineering of sub‐nanochannels for ion selectivity. We first introduce fundamental ion transport mechanisms within sub‐nanochannels, followed by strategies to tune pore size, geometry, and surface functionalities, categorized into charge‐based, ion‐recognition, hydrophilic bonding, and ...
Yuyu Su +5 more
wiley +1 more source
Intelligent Molecular Recognition in Hydrogen‐Bond‐Mediated Supramolecular Polyhedra
This perspective highlights the construction of sophisticated hydrogen‐bonded supramolecular polyhedra from macrocycles by emulating the hierarchical assembly of ferritin and viral capsids, and summarizes their selective recognition of individual guest molecules as well as the synergistic encapsulation of multiple species, demonstrating their potential
Ran‐Qi Chen +3 more
wiley +1 more source
Here, we present a versatile modular strategy for crafting novel covalent organic cages (para-cage[n]arenes and meta-cage[n]arenes, n = 3,4) and bimacrocycles (meta-bimacrocyclic-arenes) with stable backbones and modifiable rims.
Qihan Lin (17854824) +5 more
core +1 more source
(a) Cartoon showing two pairs of pre-existing (18 hrs) doublets adhering to each other through a junction established after 1 hr (red, shown by the square box). The doublets are attached to a pillar tip and are pulled by a micropipette to the left.
Yeh Shiu Chu (11868689) +7 more
core +1 more source
In this work, we have proposed a novel universal stimulus-sensitive nanosized polymer system based on decasubstituted macrocyclic structures—pillar[5]arenes and tetrazole-containing polymers.
Daut R. Islamov +7 more
core +1 more source
We report a new route for the selective synthesis of di- and tetrafunctionalized pillararenes via oxidation and reduction of the pillararene units.
Takamichi Aoki (1269240) +5 more
core +2 more sources

