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Peculiarities of β‐Pinene Autoxidation
ChemSusChem, 2011AbstractThe thermal oxidation of the renewable olefin β‐pinene with molecular oxygen was experimentally and computationally investigated. Peroxyl radicals abstract weakly bonded allylic hydrogen atoms from the substrate, yielding allylic hydroperoxides (i.e., myrtenyl and pinocarvyl hydroperoxide).
Ulrich, Neuenschwander +2 more
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Gamma-radiolysis of chiral terpenes: α-(−)pinene and α-(+)pinene
Journal of Radioanalytical and Nuclear Chemistry, 2007The terpenes α-(+)-pinene, and α-(−)pinene have been radiolyzed at radiation doses of 150, 300 and 600 kGy. The radiolyzed samples have been analyzed by FT-IR spectroscopy and polarimetry. Both α-(+)-, α-(−)-pinenes show a linear trend to radioracemization as a function of the radiation dose administered ≈2.5·10−3 [α]D/kGy.
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Berichte der deutschen chemischen Gesellschaft, 1895
Ferd. Tiemann, F. W. Semmler
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Ferd. Tiemann, F. W. Semmler
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Molecular mechanism for rapid autoxidation in α-pinene ozonolysis
Nature Communications, 2021Siddharth Iyer +2 more
exaly
Ozonolysis of alpha-pinene and beta-pinene: kinetics and mechanism.
The Journal of chemical physics, 2006A combined quantum-chemical and RRKM/ME (ME--master equation) approach is employed to investigate the structures, energetics, and kinetics of intermediate and stable species, and the yields of stabilized carbonyl oxides and OH radicals from the alpha-pinene and beta-pinene ozonolysis reactions.
Dan, Zhang, Renyi, Zhang
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