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Preparation and Characterization of Photo-Cross-Linked Thermosensitive PNIPAAm Nanogels
Macromolecules, 2006Thermosensitive nanogels were prepared from photo-cross-linkable copolymers of N-isopropyl-acrylamide (NIPAAm) and 2-dimethylmaleinimido ethylacrylamide (DMIAAm). The colloidal nanogels were formed by UV-irradiated solutions of thermosensitive polymers in water at 45 °C.
Ruckling, D. +4 more
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Temperature-Sensitive Nanogels PNIPAAm/DMA Prepared and Research
Advanced Materials Research, 2012There have much study about thermo-responsive nanogels,which exhibit temperature-controlled volume phase transitions.There have been few reports,however,of electrostatically neutral,thermosensitive nanogels with a high composition of hydrophilic monomer.Here,we describe the synthesis and characterization of a new class of nonionic copolymer nanogels ...
Hai Yan Wang +4 more
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Thermally reversible shape transformation of nano-patterned PNIPAAm hydrogel
Polymer Bulletin, 2020In the field of stimuli-responsive polymer research, poly-N-isopropylacrylamide (PNIPAAm) has been widely studied, because this material has unique properties which respond to temperatures near to that of the human body, approximately 36 °C. In this study, a nano-patterned PNIPAAm hydrogel was prepared using UV-irradiation and soft lithography ...
Byulhana Kim, Jung-Soo Lee
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Tannic Acid Mediated Suppression of PNIPAAm Microgels Thermoresponsive Behavior
Macromolecules, 2011Tannic acid (TA) complexation with poly(N-isopropylacrylamide) (PNIPAAm) microgels changed their morphology and temperature responsiveness, depending on TA concentration and pH (below the TA pKa).
Eunice Costa +4 more
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Thermo-Responsive PNiPAAm-g-PEG Films for Controlled Cell Detachment
Biomacromolecules, 2003A series of graft copolymers consisting of either poly(N-isopropylacrylamide) (PNiPAAm) or poly(N,N-diethylacrylamide) (PDEAAm) as a thermo-responsive component in the polymer backbone and poly(ethyleneglycol) (PEG) were immobilized as thin films and cross-linked on a fluoropolymer substrate using low-pressure argon plasma treatment.
Dirk, Schmaljohann +5 more
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AIP Conference Proceedings, 2012
Block copolymers have been used extensively in the synthesis of different types of nanoparticles. A novel ABA type tri-block nanopolymer PNIPAAm-b-PU-b-PNIPAAm has been synthesized via atom transfer radical polymerization (ATRP) technique, using a tertiary bromo-terminated as a macroinitiator.
Prashant Singh +6 more
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Block copolymers have been used extensively in the synthesis of different types of nanoparticles. A novel ABA type tri-block nanopolymer PNIPAAm-b-PU-b-PNIPAAm has been synthesized via atom transfer radical polymerization (ATRP) technique, using a tertiary bromo-terminated as a macroinitiator.
Prashant Singh +6 more
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Synthesis, characterization and controlled drug release of thermosensitive IPN–PNIPAAm hydrogels
Biomaterials, 2004A method was developed to prepare thermosensitive poly(N-isopropylacrylamide) (PNIPAAm) hydrogels with an interpenetrating polymer network (IPN) structure for the purpose of improving its mechanical properties, response rate to temperature and sustained release of drugs.
Xian-Zheng, Zhang +2 more
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Macromolecular Chemistry and Physics, 2012
AbstractWhen γ‐CDs are added to an aqueous solution of PNIPAAm‐b‐PEG‐b‐PNIPAAm block copolymer, they are threaded onto the polymer chains to give loose‐fit polypseudorotaxanes (PPRs). The inclusion complexation shows a marked dependence on the length of the PNIPAAm blocks although the threaded γ‐CDs are preferably located on the central PEG block.
Peng Gao +5 more
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AbstractWhen γ‐CDs are added to an aqueous solution of PNIPAAm‐b‐PEG‐b‐PNIPAAm block copolymer, they are threaded onto the polymer chains to give loose‐fit polypseudorotaxanes (PPRs). The inclusion complexation shows a marked dependence on the length of the PNIPAAm blocks although the threaded γ‐CDs are preferably located on the central PEG block.
Peng Gao +5 more
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Fabrication and characterization of microgel-impregnated, thermosensitive PNIPAAm hydrogels
Polymer, 2005Abstract Poly(N-isopropylacrylamide)/poly(ethylene glycol) diacrylate (PNIPAAm/PEG-DA) microgels were used as an additive during the polymerization and/or crosslinking of PNIPAAm hydrogels to improve their thermosensitive properties. The influence of this additive on the property of resulting PNIPAAm hydrogels was investigated and characterized.
Xian-Zheng Zhang, Chih-Chang Chu
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Hybrid collagen/pNIPAAM hydrogel nanocomposites for tissue engineering application
Colloid and Polymer Science, 2018The present work explores new hybrid bioactive, enzymatically degradable hydrogel nanocomposites. They are composed by stimuli-sensitive semi-interpenetrating collagen/poly(N-isopropyl acrylamide) polymeric matrix, Dellite® 67G and Cloisite® 93A nanoclays, and hydroxyapatite particles.
Nistor Manuela Tatiana +3 more
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