Results 111 to 120 of about 310,793 (174)

A hepatoprotective experiment on taro vegetable (Colocasia esculenta (L.) Schott) flower employing animal models by mitigating oxidative stress

open access: yesAnimal Models and Experimental Medicine, EarlyView.
The antioxidant efficacy of Colocasia esculenta flower’s methanolic extract was assessed using 2,2′‐azino‐bis‐(3‐ethylbenzothiazoline‐6‐sulfonic) (ABTS) and 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) scavenging assay. The hepatoprotective effect was investigated by assessing liver injury indicators (amino transferase [ALT], aspartate amino transferase [AST],
Mahathir Mohammad   +9 more
wiley   +1 more source

Coupling of CuO@NiBiOx Catalyzed Glycerol Oxidation to Carbon Dioxide Reduction Reaction for Enhanced Energy Efficiency

open access: yesAngewandte Chemie, EarlyView.
A CuOx@NiBiOx core‐shell‐like catalyst is synthesized. Thanks to the Bi presence, the electronic structure of Ni is tuned, leading to better catalytic performance for glycerol oxidation compared to both CuOx and CuOx@NiOx catalysts. Additionally, coupling glycerol oxidation with CO2 reduction significantly reduces the operational voltage and the ...
Thi‐Hong‐Hanh Le   +13 more
wiley   +2 more sources

Roadmap to Nanomedical Applications: Nanotoxicology and In Vitro Guidelines for Lanthanide‐Doped Luminescence Nanothermometers

open access: yesAdvanced NanoBiomed Research, EarlyView.
Lanthanide‐based luminescence nanothermometry holds multifaceted potential for nanomedical applications, yet despite significant research advances, clinical translation of the engineered nanomaterials is still controversial and widely disputed. This is related to crucial nanotoxicological aspects that must be addressed at the preclinical level ...
Simona Premcheska   +2 more
wiley   +1 more source

Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines

open access: yesAngewandte Chemie, EarlyView.
We present a one‐step deaminative Suzuki–Miyaura‐type coupling of anilines via fleeting diazonium intermediate with nitrate and bisulfite as the reagents. This represents the first application of the nitrate reduction strategy in transition metal catalysis of diazonium chemistry.
Chen‐Chen Li   +6 more
wiley   +2 more sources

Stochastic Hydrodynamic Velocity Field and the Representation of Langevin Equations

open access: yesAnnalen der Physik, EarlyView.
A lumped method is proposed to account for both mean‐field hydrodynamics and stochastic fluctuations within the kinematic equations of motion, providing a regularized formulation of the overdamped approximation. The concept of stochastic realizability in broad sense is introduced based on the spectral properties of the Fredholm operator associated with
Massimiliano Giona   +2 more
wiley   +1 more source

Site‐Selective Carbonylation of Azetidines via Copper‐Catalyzed Difluorocarbene Insertion

open access: yesAngewandte Chemie, EarlyView.
We disclose a site‐selective Cu‐catalyzed carbonylation of azetidines promoted by difluorocarbene insertion at low temperature, enabling access to a variety of functionalized γ‐lactams and a therapeutic agent for diabetes (40 examples). This skeletal expansion strategy provides a distinct disconnection approach to synthesize medicinally relevant five ...
Fang Zhou, Tong‐De Tan, Ming Joo Koh
wiley   +2 more sources

A Bench‐Stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application

open access: yesAngewandte Chemie, EarlyView.
We herein present the synthesis of a bench‐stable Ni(0) complex, [Ni(PFPh2)4], stabilized by vastly underexplored fluorophosphine ligands. The application of [Ni(PFPh2)4] in Suzuki–Miyaura and Kumada‐Tamao‐Corriu cross‐coupling reactions as well as in Buchwald–Hartwig C─N bond formation reactions, indicates its promising potential as alternative to ...
Franziska Flecken   +3 more
wiley   +2 more sources

Asymmetric Coordination in Cobalt Single‐Atom Catalysts Enables Fast Charge Dynamics and Hierarchical Active Sites for Two‐Stage Kinetics in Photodegradation of Organic Pollutants

open access: yesAngewandte Chemie, EarlyView.
This investigation demonstrates an efficient synthetic methodology for the fabrication of atomically dispersed cobalt species anchored on carbon nitride substrate, featuring distinctive asymmetric Co─C2N3 coordination environments and hierarchical active sites.
Xiaoming Liu   +7 more
wiley   +2 more sources

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