Results 151 to 160 of about 50,780 (252)

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun   +4 more
wiley   +2 more sources

Acetylene Semi‐Hydrogenation by Photocatalysis

open access: yesAngewandte Chemie, EarlyView.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato   +6 more
wiley   +2 more sources

The shadow of mercury behind gold extraction in the Amazon: hidden threats to human health and the environment. [PDF]

open access: yesLancet Reg Health Am
Valbuena Ruiz FJ   +5 more
europepmc   +1 more source

Dual d–p hybridization in Ternary PtGaGe Enables Concurrent Activity and Stability Enhancement for Alkaline Oxygen Reduction

open access: yesAngewandte Chemie, EarlyView.
A unique dual d–p orbital hybridization strategy was established in a ternary PtGaGe alloy catalyst to overcome the longstanding activity–stability trade‐off in oxygen reduction reaction (ORR). Synergistic hybridization between Ga/Ge p orbitals and Pt d orbitals modulates the Pt electronic structure, optimizes oxygen intermediates adsorption, and ...
Qian Zhang   +8 more
wiley   +2 more sources

Site‐Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C2+ Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Site‐specific self‐assembly of alkyl thiols on Au/TiO2 enables precise modulation of interfacial electron distribution and the local microenvironment through covalent Au‐thiolate interactions. This site‐specific molecular engineering synergistically promotes surface kinetics and charge separation, suppressing ·O2−‐driven overoxidation and thereby ...
Yaru Shao   +11 more
wiley   +2 more sources

Epitaxial Oxide Interfaces Create Poison‐Resistant CuO Sites for Environmental Catalysis

open access: yesAngewandte Chemie, EarlyView.
An epitaxially stabilized CuO overlayer on Ti1−xInxO2 creates electron‐poor, high‐symmetry Cu–O sites that activate interfacial lattice‐oxygen redox. This interface promotes NOx reduction through an Eley–Rideal pathway, diverts sulfate formation, and sustains CH3SH deep oxidation via a Mars–van Krevelen cycle, offering a route to poison‐resistant ...
Lupeng Han   +14 more
wiley   +2 more sources

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