Results 81 to 90 of about 149 (142)
Fairness in Federated Learning: Trends, Challenges, and Opportunities
Advanced Intelligent Systems, EarlyView.This survey delves into the intricate issues pertinent to fairness in federated learning , where various biasing factors can skew model performance. By systematically analyzing fairness‐aware strategies, evaluation metrics, and future directions, this work identifies pivotal research gaps in existing approaches and sheds light on both challenges and ...
Noorain Mukhtiar +2 more
wiley +1 more source
Production Of 11C‐Labeled Amides Via “In‐Loop” 11C‐Carbonylation
Asian Journal of Organic Chemistry, EarlyView.The current work utilizes carbon‐11 labelled aroyl dimethylaminopyridinium salts in a two‐step in‐loop carbonylative cross‐coupling reaction of aryl halides with [¹¹C]CO yielding a diverse range of carbon‐11 labelled primary benzamides with good to excellent yields.
Tanpreet Kaur +3 more
wiley +1 more source
Animal Models and Experimental Medicine, EarlyView.In an ethanol (EtOH)‐treated mouse model, increases in the NLRP3 inflammasome proteins, PC degeneration, and motor coordination disorders were observed. DIP suppressed the NLRP3‐ASC‐caspase‐1 signaling pathway, and alleviated the motor deficits and cerebellar pathological changes in chronic EtOH‐treated mice.
Jian Zhang +5 more
wiley +1 more source
Angewandte Chemie, EarlyView.Kinetic resolution by copper hydride catalyzed reduction of 2H‐azirines secured optically enriched N‐H aziridine‐2‐carboxylates with excellent diastereoselectivity (>20:1) and good enantioselectivity (up to 94% ee). DFT calculations and non‐covalent interaction analysis established the reaction pathway and revealed two key non‐covalent interactions ...
Yinuo Zheng +3 more
wiley +2 more sources
Animal Models and Experimental Medicine, EarlyView.The antioxidant efficacy of Colocasia esculenta flower’s methanolic extract was assessed using 2,2′‐azino‐bis‐(3‐ethylbenzothiazoline‐6‐sulfonic) (ABTS) and 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) scavenging assay. The hepatoprotective effect was investigated by assessing liver injury indicators (amino transferase [ALT], aspartate amino transferase [AST],
Mahathir Mohammad +9 more
wiley +1 more source
Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine
Angewandte Chemie, EarlyView.19E‐geissoschizine is a key precursor in the biosynthesis of monoterpene indole alkaloids such as strychnine, ibogaine, and vinblastine. Using enzymatic assays and gene silencing, three CYPs were identified from C. roseus that oxidize this compound to four alkaloid scaffolds: strychnos, sarpagan, akuammiline, and mavacurane. Mutational analysis reveals
Mohamed O. Kamileen +6 more
wiley +2 more sources
Advanced NanoBiomed Research, EarlyView.Lanthanide‐based luminescence nanothermometry holds multifaceted potential for nanomedical applications, yet despite significant research advances, clinical translation of the engineered nanomaterials is still controversial and widely disputed. This is related to crucial nanotoxicological aspects that must be addressed at the preclinical level ...
Simona Premcheska +2 more
wiley +1 more source
Angewandte Chemie, EarlyView.A CuOx@NiBiOx core‐shell‐like catalyst is synthesized. Thanks to the Bi presence, the electronic structure of Ni is tuned, leading to better catalytic performance for glycerol oxidation compared to both CuOx and CuOx@NiOx catalysts. Additionally, coupling glycerol oxidation with CO2 reduction significantly reduces the operational voltage and the ...
Thi‐Hong‐Hanh Le +13 more
wiley +2 more sources