Polarized neutron study of the intermetallic conpound GdAl2
Journal of Magnetism and Magnetic Materials, 1983Abstract We report the Gd magnetic form factor in GdAl2. In order to avoid the strong absorption of neutrons by natural gadolium very short wavelenghts were used. The 4f part of the form factor agrees with the relativistic radial integral 〈j0〉 calculated for a free ion, with a moment of only 6.6μB instead of the 7.0μB expected.
J.S. Abell +4 more
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Polar‐Covalent Bonding Beyond the Zintl Picture in Intermetallic Rare‐Earth Germanides
Chemistry – A European Journal, 2019AbstractA comparative chemical bonding analysis for the germanides La2MGe6 (M=Li, Mg, Al, Zn, Cu, Ag, Pd) and Y2PdGe6 is presented, together with the crystal structure determination for M=Li, Mg, Cu, Ag. The studied compounds adopt the two closely related structure types oS72‐Ce2(Ga0.1Ge0.9)7 and mS36‐La2AlGe6, containing zigzag chains and corrugated ...
Freccero R. +5 more
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Experimental and theoretical investigations of the polar intermetallics SrPt3Al2 and Sr2Pd2Al
Journal of Solid State Chemistry, 2016Abstract SrPt3Al2, a CaCu5 relative (P6/mmm; a = 566.29(3), c = 389.39(3) pm; wR2 = 0.0202, 121 F2 values, 9 parameters), and Sr2Pd2Al, isostructural to Ca2Pt2Ge (Fdd2; a = 1041.45(5), b = 1558.24(7), c = 604.37(3) pm; wR2 = 0.0291, 844 F2 values, 25 parameters) have been prepared from the elements.
Frank Stegemann +4 more
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Effect of the Polarity of the III-V Intermetallic Compounds on Etching
Journal of Applied Physics, 1960For the III-V intermetallic compounds, the <111> directions are polar axes. The shape of etch pits bounded by crystallographic planes and the presence or absence of pits at dislocations are influenced by the effect of the polar axes on the etch rates.
J. W. Faust, A. Sagar
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Interpenetrating Polar and Nonpolar Sublattices in Intermetallics: The NaCd2 Structure
ChemInform, 2007AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Daniel C, Fredrickson +2 more
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Electrocrystallization: A Synthetic Method for Intermetallic Phases with Polar Metal–Metal Bonding
Inorganic Chemistry, 2016Isothermal electrolysis is a convenient preparation technique for a large number of intermetallic phases. A solution of the salt of a less-noble metal is electrolyzed on a cathode consisting of a liquid metal or intermetallic system. This yields crystalline products at mild reaction conditions in a few hours.
Frank, Tambornino +6 more
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Novel Polar Intermetallic π-Systems along the Zintl Border
MRS Proceedings, 1998AbstractStudies have shown that complex Zintl phases exhibit a rich diversity of crystal structures. These have also revealed a remarkable success of the Zintl concept in rationalizing stoichiometry, crystal structure and chemical bonding of many main group intermetallics.
Arnold M. Guloy, Zhihong Xu
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Chemically driven surface effects in polar intermetallic topological insulators A 3 Bi
Physical Chemistry Chemical Physics, 2018Surface electronic spectra, surface and bulk properties as well as the underlying chemical bonding characteristics in topological insulators with complex bonding patterns are considered for the example of cubic, polar intermetallics KNa 2 Bi, K 3 Bi and
I. P. Rusinov +6 more
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Conduction electron spin polarization in some intermetallic europium compounds
Physica B+C, 1977Abstract For the CaCu 5 -type compounds EuX 5 (X = Cu, Zn, Ag, Au) the magnetic properties, the lattice constants, the 151 Eu hyperfine fields and the isomer shifts were determined. The transferred hyperfine fields were estimated by means of data obtained on some pseudobinaries Eu 1− x R x X 5 (R = Ca, La, Gd).
F.J. van Steenwijk +4 more
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β-Li2Zn5: A Low Symmetric Polar Intermetallic Compound
Inorganic Chemistry, 2019The crystal structure of the high-temperature modification of the compound Li2Zn5 was determined using single-crystal X-ray diffraction data. It is the first representative of a new binary structure type with triclinic space group P1̅, where the parameters of the unit cell are a = 8.0073(3)Å, b = 11.5956(6)Å, c = 15.2956(5)Å, α = 96.39°, β = 101.92 ...
Igor Oshchapovsky +2 more
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