Synthesis and cell adhesion studies of linear and hyperbranched poly(butyl methacrylate) and poly(t-butyl acrylate) [PDF]
A library of polymers/oligomers with three different architectures was synthesised. Short chain, linear oligomers were produced by performing oxidative cleavage on a poly(butyl methacrylate-co-butadiene) polymer.
Cox-Nowak, Kayleigh
core +6 more sources
The Thermal Degradation of Poly-Tert.-Butyl Methacrylate [PDF]
Thermal degradation reactions of vinyl polymers can be classified into chain scission and non chain scisson reactions. Previous work on poly-tert-butyl methacrylate had indicated that the only reaction to occur with this substance was of the latter type;
Grant, Douglas H
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Fluorinated copolymer resists for high-resolution negative-tone lithography: Preparation and patterning performance. [PDF]
Electron‐beam induced C–F cleavage in –CF3 generates F−, which abstracts a proton to form the acid that catalyzes tBMA deprotection during post‐exposure baking. This self‐sensitization mechanism enables the precise formation of high‐resolution negative‐tone patterns with enhanced sensitivity and resolution.
Tang Y +9 more
europepmc +2 more sources
Recent advances in polymeric chemically amplified positive resists: Materials and design strategies. [PDF]
This review summarizes recent advances in the molecular design of positive chemically amplified resists, focusing on photoacid generators and polymer architectures. Key strategies for enhancing sensitivity—including self‐amplification effects, copolymerization of sensitive monomers, controlled polymerization, and photosensitized chemically amplified ...
Zhou L, Li H, Zhang J, Xin H.
europepmc +2 more sources
Hetrocyclic methacrylate systems as vehicles for the release of active species. [PDF]
PhDThe room temperature polymerising heterocyclic polymer system, poly(ethyl methacrylate)/tetrahydrofurfuryl methacrylate (PEM/THFM) has been shown previously to be biocompatible and supported tissue repair, specifically for bone and cartilage ...
Hoque, Shahma
core +4 more sources
Compared to traditional hydrogel materials, organohydrogels have wider applications due to their special properties such as abilities of self-adaptive, freeze-tolerant and mechanically stable over a wide range temperature. In this paper, we prepared Poly
Qingshan Wu +4 more
doaj +1 more source
Poly (α-methyl methacrylate-butyl acrylate-glycidyl methacrylate) (PMBG) and poly (α-methyl methacrylate-butyl acrylate) (PMB) were synthesized via solution polymerization and characterized via Fourier transform infrared spectroscopy (FTIR).
Kai Wan +5 more
doaj +1 more source
The Thermal and Photochemical Degradation of Poly-N-Butyl Methacrylate [PDF]
An investigation of the thermal and photochemical degradation behaviour of poly-n-butyl methacrylate is described in this thesis. The object of the work was to evaluate the velocity coefficients of the various steps in the depolymerisation process with a
MacCallum, James Richard
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Nanohybrid silica/polymer aerogels: The combined influence of polymer nanoparticle size and content
Nanohybrid silica/polymer aerogel monoliths were produced by the soft sol-gel process and dried at ambient pressure. The hybrid alcogels were prepared by a two-step acid/basic catalyzed co-hydrolysis/co-condensation of a silica precursor ...
Alexandra Fidalgo +3 more
doaj +1 more source
Monolayer Properties of Mixtures of Poly(octadecyl methacrylate) and Poly(butyl methacrylate) and Their Corresponding Copolymers [PDF]
Abstract The monolayer properties of mixtures of poly(octadecyl methacrylate) and poly(butyl methacrylate) have been compared with those of their corresponding copolymers of octadecyl methacrylate and butyl methacrylate, using the measurements of their surface pressure-area isotherms at the air/water interface at 20 °C.
Satoshi Yoshikawa +2 more
openaire +1 more source

