Results 61 to 70 of about 454,598 (214)

On‐Surface Friedel–Crafts Alkylation Through a Stabilized Intermediate Complex

Angewandte Chemie International Edition, EarlyView.
On‐surface Friedel–Crafts alkylation is demonstrated on Ag(111) at the single‐molecule level. STM, XPS, and DFT calculations uncover the reaction mechanism and explain the stabilization of the key intermediate, providing insight into noble‐metal‐surface‐mediated Csp3${\rm C}_{sp^{3}}$─Csp2${\rm C}_{sp^{2}}$ coupling. ABSTRACT The incorporation of sp3${\
Paul Schweer, Christoph J. Vonnemann, Nishanth Arumugam, Stefan M. Huber, Daniel P. Miller, Karina Morgenstern   +5 more
wiley   +1 more source

Fluorine-Containing Dibenzoanthracene and Benzoperylene-Type Polycyclic Aromatic Hydrocarbons: Synthesis, Structure, and Basic Chemical Properties

Molecules, 2018
Intramolecular photocyclization of stilbene derivatives (Mallory reaction) is one of the efficient methods for building polycyclic aromatic hydrocarbon (PAH) frameworks, and is also expected to be applicable to synthesis of fluorine-containing PAHs (F ...
Otohiro Gotsu, Tomomi Shiota, Hiroki Fukumoto, Tomoko Kawasaki-Takasuka, Takashi Yamazaki, Tomoko Yajima, Tomohiro Agou, Toshio Kubota   +7 more
doaj   +1 more source

Granular Bed Filtration of Coal Pyrolysis Gas: Effects of Media Reactivity on Dust Removal and Products

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT Granular bed filtration is a promising technology for removing dust from high‐temperature coal pyrolysis gas. In this work, the reactivity of coal pyrolysis products over ceramsite, char, ultrastable Y‐type (USY) zeolite, and quartz particles was compared.
Shuaiqiang Yang, Guangchao Ding, Lin Du, Wenli Song, Songgeng Li   +4 more
wiley   +1 more source

Avaliação da biodegradação de pireno pela microbiota nativa em sedimento do manguezal do Itacorubi, Florianópolis,SC [PDF]

, 2006
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-graduação em QuímicaA localização dos manguezais é estrategicamente propícia à contaminação podendo, portanto, receber poluentes ...
Oliveira, Cristiane Rossi de
core  

Interface‐Engineered Li–Ni–O/Ni Heterostructures With Tunable Vacancies on Biochar Enable Biomass‐to‐Hydrogen Conversion

Carbon Energy, EarlyView.
This study shows that lithium induces Li–Ni–O/Ni heterostructures on biochar, creating oxygen vacancies and optimal acid–base environments that enhance steam activation and suppress carbon deposition. These interfacial effects and synergistic modulation lead to high hydrogen yields at moderate temperatures, providing a scalable catalyst design strategy
Jiali Guo, Jit Loong Cyrus Foo, Guicai Liu, Liya Ge, Andrei Veksha, Wei Ping Chan, Dean Song, Grzegorz Lisak   +7 more
wiley   +1 more source

Avaliação da concentração de compostos mono e policíclicos aromáticos dos processos de conversão térmica de lodo sanitário para uso como fonte alternativa de energia [PDF]

, 2015
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro Tecnológico, Programa de Pós-Graduação em Engenharia Química, Florianópolis, 2015.Atualmente, o tratamento de águas residuárias, através das estações de tratamento de efluentes, gera lodos
Susin, Renato Cesar
core  

Exploring the Boundaries of Aromaticity in Complex Structures and Excited States Through Computational Analysis

Chemistry – A European Journal, EarlyView.
Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola, Miquel Solà, Albert Poater   +2 more
wiley   +1 more source

Respostas transcricionais no manto de ostras do mangue, Crassostrea brasiliana exposta a fenantreno [PDF]

, 2014
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Biológicas, Programa de Pós-Graduação em Bioquímica, Florianópolis, 2014.Os hidrocarbonetos policíclicos aromáticos (HPAs) estão entre os principais contaminantes nos ...
Miguelão, Talita
core  

Proximal Steric Shielding Unlocks High Solid‐State Luminescence in Quinoxaline‐Fused Pyrene Heteroacenes

Chemistry – A European Journal, EarlyView.
Proximal steric tuning of quinoxaline‐fused pyrene heteroacenes enables soluble derivatives that exhibit solid‐state photoluminescence quantum yields (PLQYs) up to 82%, surpassing previous benchmarks. This work reveals key structure–property relationships for next‐generation, processable organic emitters in advanced optoelectronic applications ...
Rafiq Ahamed, Sonal Patil, Madhusudan Dutta, Godi Kiran Venkata Sai, Sergey Fisher, Anil Bhadke, Rama Krishna Gamidi, Susnata Pramanik, Tomáš Šolomek, Sudhakar Gaikwad   +9 more
wiley   +1 more source

Exploring the possibility of polycyclic aromatic hydrocarbons and fulleranes as the carrier of the 21 micron emission feature

Frontiers in Astronomy and Space Sciences
IntroductionThe 21 μm emission feature discovered in a small sample of carbon-rich protoplanetary nebulae has remained unidentified for over 30 years. A dozen of different molecular species (both organics and inorganics) have been proposed as the carrier
Xuan-Xiang Liao, Yong Zhang, Yong Zhang, SeyedAbdolreza Sadjadi   +3 more
doaj   +1 more source