Results 91 to 100 of about 438,427 (238)

Anaerobic degradation of polycyclic aromatic hydrocarbons

open access: yesApplied and Environmental Microbiology
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous and toxic pollutants in the environment that are mostly introduced through anthropogenic activities.
Isabelle Heker   +3 more
doaj   +1 more source

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

open access: yesChemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad   +3 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Charge Resonance Interaction in Aromatic Trimer Radical Cations Revealed by IR Spectroscopy: The Case of Pyrrole Homo‐ and Heterotrimers

open access: yesChemistry – A European Journal, EarlyView.
We demonstrate the power of high‐resolution infrared spectroscopy and complementary quantum chemical calculations to unravel the evolution of the aromatic charge resonance interaction (CR) in cold trimer radical cations for the prototypical pyrrole clusters.
Dashjargal Arildii, Otto Dopfer
wiley   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

open access: yesChemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik   +11 more
wiley   +1 more source

Avaliação da concentração de compostos mono e policíclicos aromáticos dos processos de conversão térmica de lodo sanitário para uso como fonte alternativa de energia [PDF]

open access: yes, 2015
Tese (doutorado) - Universidade Federal de Santa Catarina, Centro Tecnológico, Programa de Pós-Graduação em Engenharia Química, Florianópolis, 2015.Atualmente, o tratamento de águas residuárias, através das estações de tratamento de efluentes, gera lodos
Susin, Renato Cesar
core  

Cyclization of a 1,8‐Diphenylanthracene by Scholl Reactions to Form Five‐ and Seven‐Membered Ring Embedded Polycyclic Aromatic Hydrocarbons

open access: yesChemistry – A European Journal, EarlyView.
Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki   +2 more
wiley   +1 more source

Aliphatic and polycyclic aromatic hydrocarbons profiles of photomodified natural bitumen of Agbabu, Southwestern Nigeria

open access: yesBulletin of the Chemical Society of Ethiopia, 2010
The impact of sunlight on aliphatic and polycyclic aromatic hydrocarbons profiles of Agbabu natural bitumen in Nigeria was investigated. The raw flow type of the bitumen was purified and exposed to sunlight for six consecutive months.
O.M. Olabemiwo   +3 more
doaj  

Bacterioneuston da Ria de Aveiro: abundância, actividade e degradação de hidrocarbonetos aromáticos policíclicos [PDF]

open access: yes, 2008
Mestrado em MicrobiologiaA microcamada superficial marinha (sea surface microlayer - SML) situa-se na interface entre a hidrosfera e a atmosfera. Esta camada é geralmente definida como o milímetro superior da coluna de água e representa um ambiente ...
Coelho, Francisco José Riso da Costa
core  

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

open access: yesChemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa   +3 more
wiley   +1 more source

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