Results 121 to 130 of about 147,855 (291)

Impact of Polycyclic Aromatic Hydrocarbons on the Environment and Human Health: Evidence Retrieved from Biomonitoring Studies

Proceedings
The presence of polycyclic aromatic hydrocarbons (PAHs) in different environmental matrices has significant repercussions on ecosystems and human health [...]
Joana Teixeira, Cristina Delerue-Matos, Simone Morais, Marta Oliveira   +3 more
doaj   +1 more source

Pd‐Catalyzed Cyclotrimerization and Cycloaddition of 5,6‐Didehydrobenzo[8]annulenes (BenzoCOTynes): Formation of Nonplanar Tri[8]annulenes and Diels–Alder Cycloadducts

European Journal of Organic Chemistry, EarlyView.
A Pd(0)‐catalyzed cyclotrimerization of benzoCOTynes to form tri(benzo[8]annulenes) was developed. Three distinct isomers were isolated and structurally characterized by single‐crystal X‐ray diffraction. Ligand modulation proved crucial for enhancing regioselectivity: P(4‐OMePh), and (S)‐tBu‐Phox promoted the formation of the symmetric isomers.
Jesús Bello‐García, Jesús A. Varela, Carlos Saá   +2 more
wiley   +1 more source

Dibenzosuberene‐Winged Polycyclic Aromatic Hydrocarbons

European Journal of Organic Chemistry, EarlyView.
The twisted acene 8, which features two dibenzosuberene “wings”, was prepared by the addition of a crowded aryne to a similarly “winged” cyclopentadienone. Compound 8 is chiral, and it has a high barrier to thermal racemization (ΔG‡rac = 36 kcal/mol), but it undergoes fast photochemical racemization even in ambient light.
Mingshu Xie, Xiaodong Zhang, Michael W. Johnson, Robert A. Pascal Jr   +3 more
wiley   +1 more source

Investigation and Evaluation of Wax Deposition Treatment Methods in Large Natural Gas Plants

Energy Science &Engineering, EarlyView.
Problem: Wax blockage (Biphenyl, PAHs) in low‐temperature units crippled plant capacity. Solution: A novel Circulating Light Hydrocarbon Injection technology. Mechanism: Light hydrocarbons disrupt wax crystals via “like dissolves like” and are continuously recovered. Outcome: 1. Throughput dropped from 10 MMscmd to 3 MMscmd 2.
Jiahao Wu, Xing Chen, Fanzeng Yang, Kejia Zhang, Zhihan Cao, Xuyang Zhang, Dong Jiang   +6 more
wiley   +1 more source

Cytotoxicity of 19 Pesticides in Rainbow Trout Gill, Liver, and Intestinal Cell Lines

Environmental Toxicology and Chemistry, EarlyView.
Abstract The rainbow trout gill cell line (RTgill‐W1), via test guideline 249 of the Organisation for Economic Co‐operation and Development, has been established as a promising New Approach Methodology, although to advance confidence in the method more case studies are needed that: 1) expand our understanding of applicability domains (chemicals with ...
Sophie Emberley‐Korkmaz, Krittika Mittal, Na'im Temlock, Jessica Head, Niladri Basu   +4 more
wiley   +1 more source

A unifying picture of gas-phase formation and growth of PAH (Polycyclic Aromatic Hydrocarbons), soot, diamond and graphite [PDF]

A variety of seemingly different carbon formation processes -- polycyclic aromatic hydrocarbons and diamond in the interstellar medium, soot in hydrocarbon flames, graphite and diamond in plasma-assisted-chemical vapor deposition reactors -- may all have
Frenklach, Michael
core   +1 more source

Thermally activated delayed fluorescence exciplex sensitizers with fast reverse intersystem crossing for improving efficiency stability of organic light‐emitting diodes based on multi‐resonance emitters

FlexMat, EarlyView.
Two exciplex emitters are constructed based on a host‐guest doping strategy, and their exciton dynamics processes are investigated in depth. High‐performance OLEDs are fabricated by employing these exciplexes as emitters or sensitizers, providing excellent electroluminescence efficiencies and low efficiency roll‐offs.
Jingwen Xu, Min Wang, Jinshi Li, Ben Zhong Tang, Zujin Zhao   +4 more
wiley   +1 more source

Rational design of Ni‐based catalysts for methane dry reforming: Recent advances and future perspectives

FlexMat, EarlyView.
Addressing the challenges inherent in dry reforming of methane (DRM), this paper focuses on the structural design and performance optimization of Ni‐based catalysts. The modulation strategies for DRM are systematically reviewed across four dimensions: the micromorphology of active metals, metal‐support interactions, electronic modifications by ...
Bowei Cao, Junlei Zhang, Wanglei Wang
wiley   +1 more source

Heteroatom location‐ and orientation mode‐dependent reverse intersystem crossing rate in multiple resonance emitters

FlexMat, EarlyView.
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang, Yincai Xu, Yupei Qu, Xinliang Cai, Jinbei Wei, Yue Wang   +5 more
wiley   +1 more source

Fluorene‐based blue emitters: On the path to electrically pumped organic lasers

FlexMat, EarlyView.
Electrically pumped efficient operation remains unrealized, a major challenge in optoelectronics. Fluorene‐based blue‐emitting semiconductors are promising gain media, thanks to their structural tunability and favorable emission properties. This review summarizes recent advances, highlights their reliability and versatility in lasing, and outlines key ...
Yong Yan, Hao Li, Mengna Yu, Huiyin Wang, Jiangqiang He, Menghan Wu, Quanyou Feng, Linghai Xie   +7 more
wiley   +1 more source