Narrowband Macrocycles: A New Paradigm for High‐Color‐Purity Organic Light‐Emitting Diodes
This graphical abstract illustrates two key strategies for constructing macrocyclic multi‐resonance (MR) emitters for high‐performance OLEDs: (1) the covalent assembly of MR moieties onto macrocyclic scaffolds, and (2) the local multi‐resonance strategy within the macrocyclic backbone.
Zhongbo Xiang +3 more
wiley +1 more source
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing +7 more
wiley +1 more source
Eccentric sombor index of graphs and its role in the structure-property relationship analysis of polycyclic aromatic compounds. [PDF]
Khaji B, Hanif S, Arathi Bhat K.
europepmc +1 more source
Addressing the challenges inherent in dry reforming of methane (DRM), this paper focuses on the structural design and performance optimization of Ni‐based catalysts. The modulation strategies for DRM are systematically reviewed across four dimensions: the micromorphology of active metals, metal‐support interactions, electronic modifications by ...
Bowei Cao, Junlei Zhang, Wanglei Wang
wiley +1 more source
Synthesis of <i>N</i>‑Substituted Acenaphtho[1,2‑<i>b</i>]pyrroles and Dibenzo[<i>e,g</i>]indoles with Promising Antileukemic Activity from Morita-Baylis-Hillman Adducts. [PDF]
Arantes J +7 more
europepmc +1 more source
By constructing two pairs of isomers with different heteroatom anchoring positions, the relationship between heteroatom location and orientation mode and reverse intersystem crossing rate constant (kRISC) in multiple resonance (MR) emitters is systematically investigated.
Tingting Huang +5 more
wiley +1 more source
Electrochemically driven strain-release dearomative (3 + 2) cyclization for the synthesis of bicyclo[2.1.1]hexane-fused polycyclic spiroindolines. [PDF]
Zhu Y +8 more
europepmc +1 more source
Fluorene‐based blue emitters: On the path to electrically pumped organic lasers
Electrically pumped efficient operation remains unrealized, a major challenge in optoelectronics. Fluorene‐based blue‐emitting semiconductors are promising gain media, thanks to their structural tunability and favorable emission properties. This review summarizes recent advances, highlights their reliability and versatility in lasing, and outlines key ...
Yong Yan +7 more
wiley +1 more source
Vosamidines A-C, Polycyclic 2-Aminoimidazole Alkaloids from a Marine Calcareous Sponge <i>Vosmaeropsis wilsoni</i>. [PDF]
Senadeera SPD +8 more
europepmc +1 more source
By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang +8 more
wiley +1 more source

