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Effects of polydimethylsiloxane concentration on properties of polyurethane/polydimethylsiloxane hybrid dispersions

Journal of Applied Polymer Science, 2006
AbstractA series of waterborne polyurethane (WPU) derived from isophorone isocyanate and poly(tetramethylene glycol) were modified by hydroxyl‐terminated polydimethylsiloxane (HPMS). The solutions were then cast into films named as PUHS. Rheological behavior of the emulsions were studied using Rheometer and morphology was studied with transmission ...
Guiqiang Fei   +3 more
openaire   +1 more source

The effects of polydimethylsiloxane on transparent and hydrophobic waterborne polyurethane coatings containing polydimethylsiloxane

Physical Chemistry Chemical Physics, 2014
The effects of polydimethylsiloxane (PDMS) on phase separation, optical transmittance and surface properties including surface composition, morphology and wettability of waterborne polyurethane (WPU) containing PDMS were investigated. After the introduction of PDMS into the WPU backbone by polymerization, the large difference in the solubility ...
Zhaofeng, Wu   +5 more
openaire   +2 more sources

Polydimethylsiloxane (PDMS)-based antifoams

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1997
The most widely used industrial antifoams are based on polydimethylsiloxane (PDMS) oils, yet very little fundamental information exists for these products. In most formulations hydrophobically modified particles are dispersed in the oil to increase antifoam efficiency but the primary mechanism responsible for this effect has remained unclear.
V. Bergeron   +5 more
openaire   +1 more source

Polysulfone–polydimethylsiloxane block copolymers

Journal of Polymer Science Part A-1: Polymer Chemistry, 1971
AbstractAlternating block copolymers have been synthesized from dihydroxyl‐terminated polysulfone and bis(dimethylamine)‐terminated polydimethylsiloxane oligomers. The products are soluble, amorphous, and transparent, and display excellent thermal and hydrolytic stability. Elastomeric and rigid compositions can be prepared by varying oligomer molecular
A. Noshay, M. Matzner, C. N. Merriam
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Thermodynamics of polydimethylsiloxane solutions

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1973
Solvent chemical potentials and heats of dilution have been obtained for systems containing polydimethylsiloxane and solvents comprising normal and branched alkanes, aromatic hydrocarbons and dimethylsiloxane oligomers. Using the Flory–Huggins approximation to eliminate the combinatorial contribution to ΔSM, the results are expressed as concentration ...
Ramlal S. Chahal   +2 more
openaire   +1 more source

Polyurethane/polydimethylsiloxane segmented copolymers

European Polymer Journal, 1999
Abstract New polydimethylsiloxane-containing segmented block copolyurethanes were obtained from aromatic or aliphatic diisocyanates, 1,4-butanediol and poly(ethylene glycol)adipate using a multistep polyaddition process. The polydimethylsiloxane–polyurethane elastomers were characterized by IR and NMR spectroscopy, DSC, WAXD and TEM measurements ...
A Stanciu   +5 more
openaire   +1 more source

Environmental Occurrence of Polydimethylsiloxane

Environmental Science & Technology, 1997
An extensive monitoring program was conducted to determine the occurrence of polydimethylsiloxane (PDMS) in environmental compartments impacted by consumer waste disposal practices. Eight wastewater treatment plants, representative of those found in North America, were monitored to determine PDMS removal during wastewater treatment.
N. J. Fendinger   +3 more
openaire   +1 more source

Injectable polydimethylsiloxane-hydroxyapatite composite cement.

Bio-medical materials and engineering, 2003
An injectable polydimethylsiloxane/hydroxyapatite (PDMS/HAp) composite cement was synthesised using linear PDMS and HAp (particles of about 100 nm in size) of different mass fractions. The effect of HAp mass fraction (5-60 mass%) on the hardness of PDMS/HAp composite cement was investigated. The hardness achieved is 25-49 degrees ShA.
Ignjatović, Nenad   +3 more
openaire   +3 more sources

Elasticity of Polydimethylsiloxane Melts

Nature, 1968
THE observation of Mieras and Van Rijn1 that the steady shear flow compliance of polymer melts is dependent only on the width of the molecular weight distribution, characterized by Mz/Mw, is in accord with our similar measurements on polydimethylsiloxane melts.
openaire   +1 more source

Polydimethylsiloxane (PDMS)

2013
G. Steiner, C. Zimmerer
openaire   +2 more sources

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