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Polyelectrolyte brushes and polyelectrolyte adsorption layers
Berichte der Bunsengesellschaft für physikalische Chemie, 1996AbstractThe structure of brushes and adsorption layers of polyelectrolytes containing strong and weak groups is analysed, using both a numerical self‐consistent‐field (SCF) model and approximate analytical expressions. The latter are based upon a local electroneutrality approximation (brushes) or upon a mutual compensation of the adsorbed polymer ...
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Polyelectrolyte Multilayers on Weak Polyelectrolyte Brushes
Macromolecular Rapid Communications, 2003AbstractThe interaction of surface‐attached weak polyelectrolyte brushes, grown directly from the surface of a solid substrate by surface‐initiated polymerization, with weak polyelectrolyte molecules in solution is studied. In addition, the formation of PEL multilayers onto such brush substrates is investigated. A strong template effect is observed and
Zhang, Haining, Rühe, Jürgen
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The Effect of Polyelectrolyte Architecture on Polyelectrolyte Complexation
2023Polyelectrolyte complexes (PECs) form spontaneously upon mixing aqueous solutions of oppositely charged polymers, forming a polymer rich complex phase and polymer poor supernatant phase. PECs are promising material platforms for various industrial applications due to their biocompatibility, low surface tension and stimuli-responsiveness.
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Polyelectrolyte Complex Coacervates: Recent Developments and New Frontiers
Annual Review of Condensed Matter Physics, 2021Artem M Rumyantsev +2 more
exaly