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Visible Photoluminescence in Polysilanes
Monatshefte fuer Chemie/Chemical Monthly, 2001The photoluminescence spectrum of poly-(methyl-(phenyl)-silanediyl) shows a strong narrow peak in the UV region which is of excitonic nature and related to σ*-σ transitions. The broad emission peak in the visible region is related to polymer branching, charge transfer transitions, and defect electronic states (backbone scission).
Stanislav Nešpůrek +2 more
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Physical Review B, 1982
A study of the vibrational properties of polysilanelike conformations in amorphous hydrogenated silicon ($a$-Si: H) is presented. With the use of the valence force-field representation of the near-neighbor interactions, the generalized cluster-Bethe-lattice method, and a chemical bonding model for obtaining realistic force constants, the one-phonon ...
W. B. Pollard, G. Lucovsky
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A study of the vibrational properties of polysilanelike conformations in amorphous hydrogenated silicon ($a$-Si: H) is presented. With the use of the valence force-field representation of the near-neighbor interactions, the generalized cluster-Bethe-lattice method, and a chemical bonding model for obtaining realistic force constants, the one-phonon ...
W. B. Pollard, G. Lucovsky
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Photochemistry of Oligosilanes and Polysilanes
ChemInform, 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
Mitsuo Kira, Ramachandram Badugu
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Electronic spectra of polysilanes
Macromolecules, 1987Spectres en solution et a l'etat solide de hauts polymeres avec des substituants alkyl et ...
L. A. Harrah, J. M. Zeigler
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A Review of Electrosynthesis of Polysilane
Journal of Macromolecular Science, Part C: Polymer Reviews, 19981. INTRODUCTION In recent years, increasing research interest has been focused on the chemistry of inorganic polymers such as polysilanes, polygermanes, and the like based on the saturated linear skeletons of group 4 atoms. Among these, polymeric organosilicon compounds, namely, polysilanes having the catenation in its backbone, are studied [1–8 ...
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