Fluorescence detection system based on silicon quantum dots–polysilane nanocomposites
A dual channel fluorescence system that combines the optical properties of silicon quantum dots–polysilane nanocomposites with those of 2-(4-chlorophenyl)-6-(thiophen-2-yl)pyridine, a fluorescent cytotoxic agent, is presented.
L. Sacarescu +3 more
doaj +2 more sources
Photovoltaic Properties and Microstructures of Polysilane-Added Perovskite Solar Cells
CH3NH3PbI3 perovskite photovoltaic devices inserted with a polysilane layer were fabricated and characterized. A Decaphenylcyclopentasilane (DPPS) in chlorobenzene solution was spin-coated between the perovskite layer and the hole transport layer of ...
Shinichiro Mizuno +6 more
doaj +2 more sources
Polysilane films were prepared by the drop casting method and their optical and morphological properties have been analyzed in order to investigate their suitability as alignment layers for nematic molecules.
M. Soroceanu +4 more
doaj +2 more sources
Polysilane–Barium Titanate Polymeric Composite Obtained through Ultrasonication
This work describes the synthesis of a polysilane (PSH)–barium titanate (BT) ferroelectric polymer composite that keeps stable in the presence of ultraviolet light (UV).
Răzvan Rotaru +3 more
doaj +2 more sources
SmI<sub>2</sub>/Sm-Induced Reductive Silacyclization of Alkene/Diene Derivatives Using Dichlorosilanes or 1,2-Dichlorodisilanes via Reductive Radical-Polar Crossover. [PDF]
A SmI2/Sm‐mediated silacyclization unlocks a concise route to 4–7‐membered silacycles from simple unsaturated substrates and dichlorosilanes/disilanes. The complementary functions of samarium reductants trigger a reductive radical–polar crossover, offering a versatile strategy for constructing multiple Si─C bonds efficiently.
Chen Z +7 more
europepmc +2 more sources
Reticular Frameworks for Advanced Polymer Materials. [PDF]
Reticular frameworks (RFs) such as metal–organic frameworks, covalent organic frameworks, and hydrogen‐bonded organic frameworks offer versatile platforms for polymer materials innovation, enabling regulated polymerization, efficient macromolecular purification, and polymer functionalization.
Cheng B, Hosono N, Uemura T.
europepmc +2 more sources
Vacuum-Nitrogen Assisted (VANS) Topotactical Deintercalation for Extremely Fast Production of Functionalized Silicene Nanosheets. [PDF]
Silicene, an analog of graphene with silicon atoms arranged in a honeycomb lattice, shows promise for electronic devices and photocatalysis. A new rapid VANS (vacuum‐nitrogen assisted) protocol accelerates its production by efficiently removing hydrogen and maintaining inert conditions.
Kozma E +9 more
europepmc +2 more sources
Fabrication and Characterization of SnCl2- and CuBr-Added Perovskite Photovoltaic Devices
Perovskite photovoltaic devices added with tin (Sn) dichloride and copper (Cu) bromide were fabricated and characterized. The thin film devices were prepared by an ordinary spin-coating technique using an air blowing method in ambient air.
Yugo Asakawa +8 more
doaj +1 more source
Perfluorinated Organosilicons Enabling Low-Loss Ferroelectric Polymer Composites for Efficient Energy Storage and Electroluminescence. [PDF]
Ferroelectric polymers for energy storage and conversion are suffering from severe energy losses despite their highly electroactive functions. Here an organic–inorganic hybrid—perfluorinated polyhedral oligomeric silsesquioxane (F‐POSS) is synthesized to markedly suppress losses in ferroelectric polymers for achieving efficient energy storage and ...
Li L +9 more
europepmc +2 more sources
1,5-Dichloro-1,1,2,2,3,3,4,4,5,5-decaphenylpentasilane
The title compound, C60H50Cl2Si5, was obtained by a ring-opening reaction of decaphenylcyclopentasilane. The chain of silicon atoms adopts an all trans conformation [Si—Si—Si—Si torsion angles = −156.31 (5) and −161.02 (5)°]. One of the Cl atoms is in an
Felix Neumeyer +3 more
doaj +1 more source

