Results 31 to 40 of about 778 (181)

Environmentally friendly polysilane photoresists [PDF]

open access: yes, 1995
Several novel polysilanes synthesized by the free-radical hydrosilation of oligomeric polyphenylsilane or poly(p-tert- butylphenylsilane) were examined for lithographic behavior.
Waymouth, R.M.   +3 more
core  

Thermal dehydrogenation of polysilane

open access: yes, 1984
The isochronal thermal decomposition of polysilane, -(SiH2)n− has been investigated at temperatures up to 335°C by in situ infrared spectroscopy. The studies were performed, in vacuo, on compressed discs of polysilane in a KBr matrix. Dehydrogenation was
Odeh, I. M., John, P., Cowie, B. C.
core   +1 more source

COATING OF POLYMERIC SUBSTRATE CATALYSTS ON METALLIC SURFACES [PDF]

open access: yesChemical Industry and Chemical Engineering Quarterly, 2010
This article presents results of a study on coating of a polymeric substrate ca-talyst on metallic surface. Stability of coating on metallic surfaces is a proper specification.
H. HOSSEINI, A. MEHRABANI-ZEINABAD
doaj  

Isolation and Reactivity of a Square‐Planar Trisamido Silane

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 21, 18 May 2026.
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel   +5 more
wiley   +1 more source

Confinement of Single Polysilane Chains in Coordination Nanospaces

open access: yes, 2015
Understanding the intrinsic properties of single conducting polymer chains is of interest, largely for their applications in molecular devices. In this study, we report the accommodation of single polysilane chains with hole-transporting ability in ...
Masanobu Naito (1281168)   +7 more
core   +1 more source

Exploring the Reactivity of Perphenylheptasilanes: Synthesis of Terminally Functionalized Derivatives

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 7, 6 May 2026.
Different methods to prepare 1,7‐disubstituted tetradecaphenylheptasilanes are explored. The triflated heptasilane TfO‐(SiPh2)7‐OTf reacts with alkali metal halides to produce the 1,7‐dihalogenides X‐(SiPh2)7‐X (X = F, Cl, Br, I). The 1,7‐dihydrogen derivative H‐(SiPh2)7‐H is obtained with LiAlH4 or (i‐Bu)2AlH as reducing agents.
Mike Friebel, Böhme Uwe, Edwin Kroke
wiley   +1 more source

Static vibrational polarizability of all-trans polyethylene and polysilane

open access: yes, 1995
The evolution with chain length of the vibrational contribution to the static linear polarizability of all-trans polyethylene and polysilane chains has been computed at the ab initio Hartree-Fock and MP2 levels within the double harmonic oscillator ...
André, Jean-Marie   +3 more
core   +1 more source

Functional polymer materials containing heavy group‐14 elements focusing on germanium and tin

open access: yesSmart Molecules, Volume 4, Issue 1, March 2026.
The synthesis, functions, and applications of the polymers containing heavy group 14 elements focusing on germanium and tin are outlined. Owing to their large atomic radii and weak binding energies, the polymers show unique properties: chromism, luminescence, carrier mobility, and reactivity to produce radials and higher coordinated states.
Masayuki Gon, Kazuo Tanaka
wiley   +1 more source

Helical-Sense Programming through Polysilane-Poly(triphenylmethyl methacrylate) Block Copolymers

open access: yes, 2016
Helical-Sense Programming through Polysilane-Poly(triphenylmethyl methacrylate) Block ...
Takanobu Sanji (2037262)   +2 more
core   +1 more source

Ringspannungs‐vermittelte Aktivierung von Pyridinen durch einen gesättigten BSi2‐Ring

open access: yesAngewandte Chemie, Volume 138, Issue 1, 2 January 2026.
Wir berichten über ein stark gespanntes Boratadisiliran mit dem bisher nicht zugänglichen anionischen BSi2‐Ringmotiv. Die Spaltung der S–Si‐Bindung während der Reaktionen mit Pyridinderivate aktiviert diese auf drei verschiedene Arten: (1) Bei Pyridin selbst erfolgt eine selektive ortho‐CH‐Aktivierung und ein gleichzeitiger Wasserstofftransfer zu einem
Nasrina Parvin   +5 more
wiley   +1 more source

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