Results 101 to 110 of about 39,422 (338)

Passivation‐Induced Species Dynamics and Microstructural Evolution in Solid‐State Lithium–Sulfur Cathodes

open access: yesAdvanced Science, EarlyView.
The formation of insulating Li2S during discharge in solid‐state lithium–sulfur batteries passivate reaction sites and limits sulfur utilization. In this work, a microstructure‐resolved modeling framework coupling transport and reaction kinetics is developed to predict charge–discharge behavior and reveal particle‐scale species evolution and incomplete
Arpan K. Sharma   +4 more
wiley   +1 more source

Thiosulfonate‐Derived BODIPY “Stick and Glue” Strategy for Fluorescent Thiol Labeling

open access: yesAngewandte Chemie, EarlyView.
We present a powerful photochemical strategy for converting disulfide bonds into stable thioether linkages via a [1,2]‐sigmatropic rearrangement. By integrating this reaction into traditional methanethiosulfonate‐based thiol labeling, we enable light‐triggered stabilization of peptide and protein conjugates with enhanced robustness and versatility ...
Lucie Šálková   +4 more
wiley   +2 more sources

Ether-compatible sulfurized polyacrylonitrile cathode with excellent performance enabled by fast kinetics via selenium doping

open access: yesNature Communications, 2019
Lithium sulfur batteries are promising for advanced energy storage, but polysulfide shuttling limits performance lifetime. Here the authors report selenium-doping in a sulfur-based cathode to prevent dissolution of polysulfide intermediates, leading to ...
Xin Chen   +10 more
doaj   +1 more source

Atomic Defects in Layered Transition Metal Dichalcogenides for Sustainable Energy Storage and the Intelligent Trends in Data Analytics

open access: yesAdvanced Science, EarlyView.
This review comprehensively summarizes the atomic defects in TMDs for their applications in sustainable energy storage devices, along with the latest progress in ML methodologies for high‐throughput TEM data analysis, offering insights on how ML‐empowered microscopy facilitates bridging structure–property correlation and inspires knowledge for precise ...
Zheng Luo   +6 more
wiley   +1 more source

Modulating Li+ and Polysulfide Solvation with Low‐Density Moderately Solvating Electrolytes for Lithium–Sulfur Batteries

open access: yesAngewandte Chemie, EarlyView.
A low‐density, nonfluorinated moderately solvating electrolyte (MSE) composed of methyl tert–butyl ether concurrently tunes Li+ and polysulfide solvation, lowering desolvation barrier and mitigating polysulfide shuttling. It effectively stabilizes both electrodes and enables stable cycling of Li–S batteries under practical parameters at room ...
Tianxing Lai   +2 more
wiley   +2 more sources

In Situ Liquid‐Cell Transmission Electron Microscopy Insights Into Lithium‐Ion Battery Materials Degradation: Challenges and Emerging Solutions

open access: yesAdvanced Science, EarlyView.
Lithium‐ion battery degradation arises from complex, localized processes during operation, limiting long‐term performance. In situ electrochemical liquid cell TEM provides unique access to these mechanisms. This review summarizes degradation phenomena revealed by liquid cell TEM, traces the evolution of the three main cell designs, compares their ...
Walid Dachraoui, Rolf Erni
wiley   +1 more source

TRPA1 Ion Channel Determines Beneficial and Detrimental Effects of GYY4137 in Murine Serum-Transfer Arthritis

open access: yesFrontiers in Pharmacology, 2019
Modulation of nociception and inflammation by sulfide in rheumatoid arthritis and activation of transient receptor potential ankyrin 1 (TRPA1) ion channels by sulfide compounds are well documented.
István Z. Bátai   +14 more
doaj   +1 more source

Innentitelbild: Strain Engineering of a MXene/CNT Hierarchical Porous Hollow Microsphere Electrocatalyst for a High‐Efficiency Lithium Polysulfide Conversion Process (Angew. Chem. 5/2021) [PDF]

open access: bronze, 2021
Xin Wang   +13 more
openalex   +1 more source

Unveiling Copper‐Induced Phase Transitions and Degradation Mechanisms of Transition Metal Sulfide Anodes for Sodium‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
Sodium polysulfides, which are generated from TMS anodes, react with the Cu current collector, thereby triggering Na‐Cu–S interfacial phase formation. Simultaneously, transition metals undergo ionization and redeposition on the counter electrode. The coupled processes drive the phase evolution of TMS toward the stable Cu1.8S phase.
Jacob Choe   +7 more
wiley   +1 more source

Hypoxia increases persulfide and polysulfide formation by AMP kinase dependent cystathionine gamma lyase phosphorylation

open access: gold, 2023
Shafiul Alam   +13 more
openalex   +1 more source

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