Results 161 to 170 of about 1,361 (213)
A novel and generally applicable early screening method for 1,2‐diketones via cyclic voltammetry and DFT computations identifies phenanthrenequinone as a suitable candidate as cathode active material for use in RMB. Its successful incorporation into a polymer enabled promising lithium and magnesium battery performance.
Noushine Dorrani +3 more
wiley +1 more source
This review underscores the growing significance of vanadium nitride as a potential material for cutting‐edge energy storage and conversion technologies, attributed to its excellent conductivity, tunable electronic properties, and abundant active sites. It thoroughly examines synthesis methods, theoretical perspectives, and electrochemical applications
Warfa Fatima +5 more
wiley +1 more source
This work demonstrates a UiO‐66‐SH‐functionalized separator that boosts Li+ transport, thermal stability, polysulfide anchoring, and sulfur redox kinetics in Li–S batteries. As a result, the cell delivers an initial capacity of 821.3 mAh g−1 at 1 C and retains 521 mAh g−1 after 500 cycles.
Min Chen +11 more
wiley +1 more source
Polysulfide-Scission Reagents for the Suppression of the Shuttle Effect in Lithium–Sulfur Batteries [PDF]
Lithium-sulfur batteries have become an appealing candidate for next-generation energy-storage technologies because of their low cost and high energy density. However, one of their major practical problems is the high solubility of long-chain lithium polysulfides and their infamous shuttle effect, which causes low Coulombic efficiency and sulfur loss ...
Xi'An Chen, Zhi Yang, Zhi Yang
exaly +4 more sources
“Shuttle” in Polysulfide Shuttle: Friend or Foe? [PDF]
The polysulfide shuttle effect, where sulfur species reach the negative electrode surface and undergo chemical reduction, is believed to be a major bottleneck in lithium–sulfur chemistry. The importance of this phenomenon is often judged based on phenomenological arguments, which do not account for mesoscale complexations.
Aashutosh N. Mistry, Partha P. Mukherjee
openaire +2 more sources
Electrocatalytic Polysulfide Traps for Controlling Redox Shuttle Process of Li–S Batteries [PDF]
Stabilizing the polysulfide shuttle while ensuring high sulfur loading holds the key to realizing high theoretical energy of lithium-sulfur (Li-S) batteries. Herein, we present an electrocatalysis approach to demonstrate preferential adsorption of a soluble polysulfide species, formed during discharge process, toward the catalyst anchored sites of ...
Hesham, Al Salem +3 more
openaire +3 more sources
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Attenuating the Polysulfide Shuttle Mechanism by Separator Coating
ChemPhysChemAbstractLithium‐sulfur batteries have a high energy density but lack cycle stability to reach market maturity. This is mainly due to the polysulfide shuttle mechanism, i. e., the leaching of active material from the cathode into the electrolyte and subsequent side reactions.
Martin Opitz
exaly +4 more sources
Developing A “Polysulfide‐Phobic” Strategy to Restrain Shuttle Effect in Lithium–Sulfur Batteries
Angewandte Chemie - International Edition, 2019AbstractInspired by hydrophobic interface, a novel design of “polysulfide‐phobic” interface was proposed and developed to restrain shuttle effect in lithium–sulfur batteries. Two‐dimensional VOPO4 sheets with adequate active sites were employed to immobilize the polysulfides through the formation of a V−S bond.
Ping He, Haoshen Zhou
exaly +3 more sources
Minimizing Polysulfide Shuttle Effect in Lithium-Ion Sulfur Batteries by Anode Surface Passivation [PDF]
Lithium-ion sulfur batteries use nonlithium materials as the anode for extended cycle life. However, polysulfide shuttle reactions still occur on the nonmetal anodes (such as graphite and Si), and result in undesirable low Coulombic efficiency. In this work, we used Al2O3 layers coated by atomic layer deposition (ALD) technique to suppress the shuttle ...
Jian Liu +10 more
openaire +3 more sources

