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Recent advances in inhibiting shuttle effect of polysulfide in lithium-sulfur batteries
Journal of Energy Storage, 2023Tianyi Ma, Songyan Jia, Qiang Zheng
exaly +2 more sources
Fluorinated Multi-Walled Carbon Nanotubes Coated Separator Mitigates Polysulfide Shuttle in Lithium-Sulfur Batteries [PDF]
Li-S batteries still suffer from two of the major challenges: polysulfide shuttle and low inherent conductivity of sulfur. Here, we report a facile way to develop a bifunctional separator coated with fluorinated multiwalled carbon nanotubes.
Pulickel Ajayan +2 more
exaly +2 more sources
Size Effect for Inhibiting Polysulfides Shuttle in Lithium‐Sulfur Batteries
Small, 2023AbstractIt is undeniable that the dissolution of polysulfides is beneficial in speeding up the conversion rate of sulfur in electrochemical reactions. But it also brings the bothersome “shuttle effect”. Therefore, if polysulfides can be retained on the cathode side, the efficient utilization of the polysulfides can be guaranteed to achieve the ...
Xiaoya Kang +6 more
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Small Methods, 2021
AbstractExhibiting high specific energy and low cost, lithium–sulfur batteries are considered promising candidates for the next‐generation battery. However, its wide applications are limited by the insulating nature of the sulfur, dissolution of polysulfide species, and large volume change of the sulfur cathode.
Shiming Chen +10 more
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AbstractExhibiting high specific energy and low cost, lithium–sulfur batteries are considered promising candidates for the next‐generation battery. However, its wide applications are limited by the insulating nature of the sulfur, dissolution of polysulfide species, and large volume change of the sulfur cathode.
Shiming Chen +10 more
openaire +3 more sources
Advanced Materials, 2018
AbstractLithium–sulfur batteries are regarded as one of the most promising candidates for next‐generation rechargeable batteries. However, the practical application of lithium–sulfur (Li–S) batteries is seriously impeded by the notorious shuttling of soluble polysulfide intermediates, inducing a low utilization of active materials, severe self ...
Shuibin Tu +7 more
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AbstractLithium–sulfur batteries are regarded as one of the most promising candidates for next‐generation rechargeable batteries. However, the practical application of lithium–sulfur (Li–S) batteries is seriously impeded by the notorious shuttling of soluble polysulfide intermediates, inducing a low utilization of active materials, severe self ...
Shuibin Tu +7 more
openaire +2 more sources
Controlling Polysulfide Shuttling in Lithium-Sulfur Batteries
ECS Meeting Abstracts, 2015Most electric cars run on rechargeable lithium-ion batteries, a pricey technology that accounts for more than half of the vehicle's total cost [1]. The development of renewable, low cost, high performance energy technologies is a key scientific challenge.
Manan Pathak +2 more
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Analysis of Polysulfide Shuttle Currents in Lithium-Sulfur Cells
ECS Meeting Abstracts, 2013Abstract not Available.
Derek Moy +2 more
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ACS Applied Materials & Interfaces, 2019
Graphdiyne (GDY), a new type of carbon material with an electron-rich conjugated structure, has been investigated as a separator coating layer to enhance the electrochemical performance of lithium-sulfur (Li-S) battery. Acetylenic bond (-C≡C-C≡C-) and benzene ring in the GDY coating layer are experimentally verified to reversibly attract the soluble ...
Yanqing Wang +5 more
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Graphdiyne (GDY), a new type of carbon material with an electron-rich conjugated structure, has been investigated as a separator coating layer to enhance the electrochemical performance of lithium-sulfur (Li-S) battery. Acetylenic bond (-C≡C-C≡C-) and benzene ring in the GDY coating layer are experimentally verified to reversibly attract the soluble ...
Yanqing Wang +5 more
openaire +2 more sources
Polysulfide Shuttle Study in the Li/S Battery System
Journal of The Electrochemical Society, 2004This work reports a quantitative analysis of the shuttle phenomenon in Li/S rechargeable batteries. The work encompasses theoretical models of the charge process, charge and discharge capacity, overcharge protection, thermal effects, self-discharge, and a comparison of simulated and experimental data.
Yuriy V. Mikhaylik, James R. Akridge
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Probing Polysulfide Shuttle Effect in the Li-S Battery
ECS Meeting Abstracts, 2016The lithium-sulfur battery is a strong contender among the beyond Li-ion chemistries due to its superior capacity and energy density as compared to the conventional Li-ion cells. However, experimental evidences suggest that even the first discharge capacity is appreciably lower than the theoretical limit.
Aashutosh Mistry +3 more
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