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A Polysulfide‐Immobilizing Polymer Retards the Shuttling of Polysulfide Intermediates in Lithium–Sulfur Batteries

Advanced Materials, 2018
AbstractLithium–sulfur batteries are regarded as one of the most promising candidates for next‐generation rechargeable batteries. However, the practical application of lithium–sulfur (Li–S) batteries is seriously impeded by the notorious shuttling of soluble polysulfide intermediates, inducing a low utilization of active materials, severe self ...
Shuibin Tu   +7 more
openaire   +2 more sources

Polysulfide-Scission Reagents for the Suppression of the Shuttle Effect in Lithium-Sulfur Batteries.

ACS Nano, 2017
Lithium-sulfur batteries have become an appealing candidate for next-generation energy-storage technologies because of their low cost and high energy density. However, one of their major practical problems is the high solubility of long-chain lithium polysulfides and their infamous shuttle effect, which causes low Coulombic efficiency and sulfur loss ...
Wuxing Hua   +8 more
semanticscholar   +3 more sources

Ion-Selective Covalent Organic Framework Membranes as a Catalytic Polysulfide Trap to Arrest the Redox Shuttle Effect in Lithium-Sulfur Batteries.

ACS Applied Materials and Interfaces, 2022
In the wake of shaping the energy future through materials innovation, lithium-sulfur batteries (LSBs) are top-of-the-line energy storage system attributed to their high theoretical energy density and specific capacity inclusive of low material costs ...
Kai Sun   +9 more
semanticscholar   +1 more source

Suppressing Polysulfide Shuttling in Lithium–Sulfur Batteries via a Multifunctional Conductive Binder

Small Methods, 2021
AbstractExhibiting high specific energy and low cost, lithium–sulfur batteries are considered promising candidates for the next‐generation battery. However, its wide applications are limited by the insulating nature of the sulfur, dissolution of polysulfide species, and large volume change of the sulfur cathode.
Shiming Chen   +10 more
openaire   +2 more sources

Controlling Polysulfide Shuttling in Lithium-Sulfur Batteries

ECS Meeting Abstracts, 2015
Most electric cars run on rechargeable lithium-ion batteries, a pricey technology that accounts for more than half of the vehicle's total cost [1]. The development of renewable, low cost, high performance energy technologies is a key scientific challenge.
Manan Pathak   +2 more
openaire   +1 more source

Confined Polysulfide Shuttle by Nickel Disulfide Nanoparticles Encapsulated in Graphene Nanoshells Synthesized by Cooking Oil

, 2020
Polysulfide shuttle effect has remained one of the main obstacles restraining the commercialization of lithium-sulfur battery technology.
M. Asif   +4 more
semanticscholar   +1 more source

Tailoring the Pore Size of a Polypropylene Separator with a Polymer Having Intrinsic Nanoporosity for Suppressing the Polysulfide Shuttle in Lithium–Sulfur Batteries

Advanced Energy Materials, 2019
Lithium–sulfur (Li–S) batteries are being considered as one of the most promising candidates for the development of next‐generation energy storage technologies.
Xingwen Yu, Hao Wu, J. Koo, A. Manthiram
semanticscholar   +1 more source

Electrocatalytic Polysulfide Traps for Controlling Redox Shuttle Process of Li-S Batteries.

Journal of the American Chemical Society, 2015
Stabilizing the polysulfide shuttle while ensuring high sulfur loading holds the key to realizing high theoretical energy of lithium-sulfur (Li-S) batteries. Herein, we present an electrocatalysis approach to demonstrate preferential adsorption of a soluble polysulfide species, formed during discharge process, toward the catalyst anchored sites of ...
Hesham Al Salem   +3 more
semanticscholar   +3 more sources

Graphdiyne-Modified Polyimide Separator: A Polysulfide-Immobilizing Net Hinders the Shuttling of Polysulfides in Lithium–Sulfur Battery

ACS Applied Materials & Interfaces, 2019
Graphdiyne (GDY), a new type of carbon material with an electron-rich conjugated structure, has been investigated as a separator coating layer to enhance the electrochemical performance of lithium-sulfur (Li-S) battery. Acetylenic bond (-C≡C-C≡C-) and benzene ring in the GDY coating layer are experimentally verified to reversibly attract the soluble ...
Yanqing Wang   +5 more
openaire   +2 more sources

Analysis of Polysulfide Shuttle Currents in Lithium-Sulfur Cells

ECS Meeting Abstracts, 2013
Abstract not Available.
Derek Moy   +2 more
openaire   +1 more source

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