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MoS2 coated separator as an efficient barrier for inhibiting shuttle effect of polysulfide

Ceramics International, 2019
Abstract Functional separators have become one of the hot topics for improving the electrochemical performance of the Li-S batteries. This is mainly due to the positive effect of the functional separators for efficiently inhibiting the shuttle effect of soluble polysulfide.
Shoufa Liu, Zhaofeng Zhou, Dancheng Liu
openaire   +1 more source

Thiuram vulcanization accelerators as polysulfide scavengers to suppress shuttle effects for high-performance lithium-sulfur batteries.

ACS Applied Materials and Interfaces, 2019
Lithium-sulfur (Li-S) batteries are considered one of the most promising alternatives for next-generation high-energy-density storage systems. Nevertheless, the notorious "shuttle effect" and sluggish kinetic conversion in actual operation seriously ...
Q. Xiang   +6 more
semanticscholar   +1 more source

Discretized Analysis of Polysulfide Shuttle Dynamics in Lithium-Sulfur Batteries

Journal of The Electrochemical Society
The polysulfide shuttle effect remains a fundamental challenge in lithium-sulfur batteries, particularly for high-energy-density applications where conventional mitigation strategies prove insufficient. Here, we introduce a state-resolved methodology for quantifying shuttle current by analyzing Coulombic efficiency across discretized charging blocks ...
Saeme Motevalian   +5 more
openaire   +1 more source

Electrolyte-Mediated Transport and Polysulfide Shuttle in Lithium–Sulfur Batteries

ECS Meeting Abstracts
Electrolyte composition critically governs the electrochemical performance of lithium–sulfur (Li–S) batteries. In this work, we investigate the coupled effects of electrolyte concentration and electrolyte-to-sulfur (E/S) ratio on electrochemical performance, with a specific focus on the polysulfide shuttle effect and its impact on active material ...
Md Shahriar Nahian   +3 more
openaire   +1 more source

Locally Confined Polysulfide-Reactive Electrolytes for Shuttle-Free Sodium–Sulfur Batteries

Journal of the American Chemical Society
Sodium-sulfur batteries promise high-energy-density and sustainable electrochemical energy storage but suffer from uncontrolled polysulfide dissolution and high sodium reactivity. These challenges fundamentally originate from poor electrolyte-electrode compatibility.
Biyu Jin   +2 more
openaire   +2 more sources

CoO/MoO3@Nitrogen-Doped carbon hollow heterostructures for efficient polysulfide immobilization and enhanced ion transport in Lithium-Sulfur batteries.

Journal of Colloid and Interface Science
Lithium-sulfur batteries (LSBs) have emerged as a promising energy storage system, but their practical application is hindered by the polysulfide shuttle effect and sluggish redox kinetics. To address these challenges, we have developed CoO/MoO3@nitrogen-
Yuxuan Jiang   +5 more
semanticscholar   +1 more source

Safe, Facile, and Straightforward Fabrication of Poly(N‐vinyl imidazole)/Polyacrylonitrile Nanofiber Modified Separator as Efficient Polysulfide Barrier Toward Durable Lithium–Sulfur Batteries

Advanced Functional Materials
Lithium–sulfur (Li–S) batteries are gaining tremendous attention as promising energy storage solutions due to their impressive energy density and the affordability of sulfur.
Chenxiao Lin   +8 more
semanticscholar   +1 more source

Accelerated Polysulfide Conversion by Rationally Designed NiS2‐CoS2 Heterostructure in Lithium–Sulfur Batteries

Advanced Functional Materials
Lithium–sulfur (Li–S) batteries are considered as potential candidates for future‐oriented energy storage systems. However, their practical deployment is hampered by the shuttle effect and the sluggish reaction kinetics of lithium polysulfides (LiPSs). A
Xing Ye   +13 more
semanticscholar   +1 more source

Suppressing the Polysulfide Shuttle Effect by Heteroatom-Doping for High-Performance Lithium–Sulfur Batteries

, 2018
Manfang Chen   +7 more
semanticscholar   +1 more source

Modified Separator Performing Dual Physical/Chemical Roles to Inhibit Polysulfide Shuttle Resulting in Ultrastable Li-S Batteries.

ACS Nano, 2017
Syed Ali Abbas   +9 more
semanticscholar   +1 more source

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