Results 111 to 120 of about 44,750 (259)

Palladium Porphyrin-Modified Fibrin Hydrogel for Oxygen Sensing in Engineered Skin Tissue Applications. [PDF]

open access: yesACS Omega
Matesanz A   +7 more
europepmc   +1 more source

Covalent Insertion of a Mn(Salen) Type Complex in Cross‐Linked Protein Crystals: Design of an Enantioselective Artificial Epoxidase

open access: yesChemistry – A European Journal, EarlyView.
An Artificial metalloenzyme was designed by a Michael addition between a MnSalen complex and a cysteine residue within NikA crystals. The heterogeneous catalyst was found capable of an enantioselective and stereospecific epoxidation of cis‐β‐methylstyrene in cristallo.
Manel Boukhallat   +8 more
wiley   +1 more source

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

open access: yesChemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija   +3 more
wiley   +1 more source

Characterization of the Interaction of Known G‐quadruplex Ligands With a Minimal i‐Motif Structure

open access: yesChemistry – A European Journal, EarlyView.
The destabilization of a minimal i‐Motif (iM) structure by TMPyP4 is driven by ligand recognition of one terminal iM structural domain. ABSTRACT Peculiar genomic regions are prone to evolve transiently from double‐helix DNA to noncanonical secondary structures in response to physiological stress.
Davide Auricchio   +3 more
wiley   +1 more source

Ion‐Enriched Porous Organic Polymer for Gold Recovery From E‐Waste

open access: yesEcoEnergy, EarlyView.
A novel ion‐enriched porous organic polymer was designed and synthesized. It exhibits ultrahigh gold adsorption efficiency with capacity up to 1530.9 mg g−1, and also shows selective capture ability towards gold ions in the actual CPU leaching solution, demonstrating its promising potential for gold recovery from actual e‐waste.
Rui Zhang   +8 more
wiley   +1 more source

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