Results 111 to 120 of about 44,845 (259)
An Artificial metalloenzyme was designed by a Michael addition between a MnSalen complex and a cysteine residue within NikA crystals. The heterogeneous catalyst was found capable of an enantioselective and stereospecific epoxidation of cis‐β‐methylstyrene in cristallo.
Manel Boukhallat +8 more
wiley +1 more source
Porphyrin-Based Fluorescent Probe for Nanomolar Detection of Cu<sup>2+</sup> and Ni<sup>2+</sup> Ions. [PDF]
Shin SH +4 more
europepmc +1 more source
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija +3 more
wiley +1 more source
Inducing a chiral twist in achiral porphyrins: tailoring molecular interactions for circularly polarized luminescence from chiral microflowers. [PDF]
Cheran A +4 more
europepmc +1 more source
Characterization of the Interaction of Known G‐quadruplex Ligands With a Minimal i‐Motif Structure
The destabilization of a minimal i‐Motif (iM) structure by TMPyP4 is driven by ligand recognition of one terminal iM structural domain. ABSTRACT Peculiar genomic regions are prone to evolve transiently from double‐helix DNA to noncanonical secondary structures in response to physiological stress.
Davide Auricchio +3 more
wiley +1 more source
N-Confused Metalloporphyrin-Based Electrocatalysts for Oxygen Reduction. [PDF]
Luo Y, Li Z, Xie J.
europepmc +1 more source
Stepwise Synthesis of Tetrabenzotriazaporphyrins (TBTAPs) and Their Open 2‐ and 3‐Ring Fragments
Unexpected reaction pathways to porphyrin‐phthalocyanine hybrids are uncovered by the synthesis of “half‐macrocycle” fragments and subsequent macrocyclization. Rather than the expected 2:2 “ABBA” product, the 3:1 “ABBB” hybrid is isolated as the only macrocyclic product.
Jacob Gretton +10 more
wiley +1 more source
Theoretical study on the geometry, aromaticity and electronic properties of porphyrin analogues. [PDF]
Chen X, Li D, Zhang C, She Y, Yang YF.
europepmc +1 more source
Control of Gemcitabine Activity With Blue and Red Light
Treating cancer with chemotherapy is generally associated with many side effects, which can be addressed by selectively releasing the desired drugs with visible light. Sixteen new blue light‐activatable cytostatics were introduced, with the gemcitabine derivative exhibiting ideal properties.
Nils F. Kersten +6 more
wiley +1 more source

