Results 171 to 180 of about 155,987 (342)

Conformational switching of ethano-bridged Cu,H2-bis-porphyrin induced by aromatic amines

open access: yesBeilstein Journal of Nanotechnology, 2015
Cu,H2-bis-porphyrin (Cu,H2-Por2), in which copper porphyrin and free-base porphyrin are linked together by an ethano-bridge, was dissolved in chloroform and spread at the air/liquid subphase interface of a Langmuir trough.
Simona Bettini   +6 more
doaj   +1 more source

Surfactant‐Assisted Construction of Covalent Organic Frameworks

open access: yesAdvanced Science, EarlyView.
This paper presents a comprehensive overview of the latest advancements and future trends in the surfactant‐assisted synthesis of covalent organic frameworks. It emphasizes the crucial role of surfactants as key additives in optimizing the crystallinity, morphology, and structure of COFs, facilitating diverse regulation, and enhancing their practical ...
Youqi Li   +8 more
wiley   +1 more source

Biomedical Applications of Gadolinium‐Containing Biomaterials: Not Only MRI Contrast Agent

open access: yesAdvanced Science, EarlyView.
This paper summarizes the latest applications and potential mechanisms of the rare earth element gadolinium in biomedical fields, in addition to its traditional application as an MRI contrast agent, including osteogenesis, antimicrobial, antitumor, bioimaging, bioprobes, and so on.
Xingtong Pan   +9 more
wiley   +1 more source

Ligand Engineering of Co‐N4 Single‐Atom Catalysts for Highly‐Active and Stable Acidic Oxygen Evolution

open access: yesAdvanced Science, EarlyView.
This study highlights the effects of metal – ligand distance on d electron structure and orbital configuration of single atom catalysts (SACs) and their corresponding oxygen evolution reaction (OER) catalytic activity and stability based on the ligand engineering.
Taeyoung Jeong   +6 more
wiley   +1 more source

Symmetry breaking fluctuations split the porphyrin Q bands [PDF]

open access: yesarXiv
Porphyrins offer a malleable and cost-efficient platform to sculpt bioinspired technologies with tunable charge transfer, energy conversion, and photocatalytic properties. Yet, despite decades of research, the physical mechanisms that determine their electronic spectra remain elusive. Even for metal-free porphyrins, no consensus exists on the origin of
arxiv  

Squaraine Dyes for Organic Photomultiplication Photodetectors with 220% External Quantum Efficiency at 1240 nm

open access: yesAdvanced Science, EarlyView.
The synthesis of a range of squaraine dyes is reported with maximum absorption in solution above 1100 nm. Near‐infrared sensitive organic photomultiplication photodetectors are developed. Photomultiplication occurs via squaraine hole trap‐induced injection of electrons from the external circuit.
Joshua Csucker   +9 more
wiley   +1 more source

Electrochemistry and spectroelectrochemistry of iron porphyrins in the presence of nitrite [PDF]

open access: yes, 2001
The reaction of nitrite with ferric and ferrous porphyrins was examined using visible, infrared and NMR spectroscopy. Solutions of either ferric or ferrous porphyrin were stable in the presence of nitrite, with only complexation reactions being observed.
Ryan, Michael D., Wei, Zhongcheng
core   +1 more source

A Universal Approach to Anchoring Chromophores onto Magnetic Scaffold for Achieving Easily Recyclable Heterogeneous Photocatalytic Systems

open access: yesAdvanced Science, EarlyView.
The practical application of chromophores such as porphyrins, coumarins, anthraquinones, and pyrene derivatives in photocatalysis is severely limited by catalyst stability and reusability. In this work, a simple and universal strategy is presented for preparing highly efficient and recyclable heterogeneous photocatalysts for the oxidative coupling of ...
Xuan Zhan   +9 more
wiley   +1 more source

Unlocking the Potential of Photoelectrochemical Water Splitting via Heterointerface Charge Polarization

open access: yesAdvanced Science, EarlyView.
This research presents a charge polarization approach aimed at enhancing both long‐range charge transfer and surface catalytic activities by incorporating a CoOx/MnOx heterointerface within the semiconductor/transition metal oxyhydroxide system. As anticipated, the BiVO4/CoOx/MnOx/FeNiOOH exhibits an impressive photocurrent of 6.75 mA cm−2 at 1.23 VRHE,
Li Xu   +8 more
wiley   +1 more source

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