Results 201 to 210 of about 155,987 (342)

meso‐Free Porphyrinoids

open access: yesAsian Journal of Organic Chemistry, EarlyView.
meso‐Free porphyrinoids are recognized as a versatile platform for further functionalization and oligomerization. The synthesis and characteristic features of such meso‐free porphyrinoids are reviewed. Abstract meso‐Unsubstituted (meso‐free) porphyrins have been an effective platform for creating versatile peripherally functionalized porphyrins and ...
Takayuki Tanaka   +2 more
wiley   +1 more source

Hydrogen Binding Energy Is Insufficient for Describing Hydrogen Evolution on Single‐Atom Catalysts

open access: yesAngewandte Chemie, EarlyView.
The research introduces a refined volcano model that incorporates both ΔGH* and ΔGHO*, addressing the limitations of traditional H models by factoring in HO* adsorption effects. Furthermore; the subquestion was discussed: Whether the metal site in SACs is the only active site?
Songbo Ye   +8 more
wiley   +2 more sources

Longitudinal Metabolomics in Amyotrophic Lateral Sclerosis Implicates Impaired Lipid Metabolism

open access: yesAnnals of Neurology, EarlyView.
Objective Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disease characterized by altered metabolome and energy homeostasis, manifesting with body mass index changes and hypermetabolism—both prognostic of disease progression and survival.
Kai Guo   +7 more
wiley   +1 more source

Synthesis, Photophysical Properties and Biological Evaluation of New Conjugates BODIPY: Dinuclear Trithiolato‐Bridged Ruthenium(II)‐Arene Complexes

open access: yesChemBioChem, Volume 23, Issue 23, December 5, 2022., 2022
Fifteen new dinuclear arene‐ruthenium (II)‐BODIPY conjugates were synthesized. Despite a fluorescence quenching effect, these conjugates can be used as fluorescent tracers. Their antiparasitic activity but also their toxicity against healthy human foreskin fibroblasts (HFFs) was reduced compared to the parent ruthenium compounds.
Oksana Desiatkina   +6 more
wiley   +1 more source

Advances and Challenges in Low‐Temperature Upcycling of Waste Polyolefins via Tandem Catalysis

open access: yesAngewandte Chemie, EarlyView.
This review presents an overview of recent advances in mild catalytic transformations of polyolefins, emphasizing the kinetic and thermodynamic interplay between endothermic C─C bond cleavages and the exothermic formation of new C─H, C─C, and C─O bonds.
Wei Zhang   +5 more
wiley   +2 more sources

Induction of Cell Death by Combined Treatment with Photosensitizer‐Chitosan Nanoparticles and the Ferroptosis Inducer RSL3 in Breast Cancer Cell Lines

open access: yesAdvanced NanoBiomed Research, EarlyView.
This study demonstrates that combination of phosphosensitizer‐conjugated chitosan nanoparticles and ferroptosis inducer RSL3 increases cell death in mesenchymal breast cancer cells. Data suggests that this is attributed to variations in ferroptosis‐related protein expression, lipid peroxydation and mitochondrial function.
Marek Feith   +10 more
wiley   +1 more source

Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine

open access: yesAngewandte Chemie, EarlyView.
19E‐geissoschizine is a key precursor in the biosynthesis of monoterpene indole alkaloids such as strychnine, ibogaine, and vinblastine. Using enzymatic assays and gene silencing, three CYPs were identified from C. roseus that oxidize this compound to four alkaloid scaffolds: strychnos, sarpagan, akuammiline, and mavacurane. Mutational analysis reveals
Mohamed O. Kamileen   +6 more
wiley   +2 more sources

Engineering cofacial porphyrin dimers using lacunary polyoxotungstates. [PDF]

open access: yesChem Sci
Yamaguchi M   +7 more
europepmc   +1 more source

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