Results 241 to 250 of about 167,383 (325)

Hydrogen Bond‐Assisted PCET and Formation of WIII─OH in Bis(Dithiolene) Complex

open access: yesAngewandte Chemie, EarlyView.
The single crystal structure of complex [2Et3NH‐1] reveals hydrogen bonding at both W‐oxo and dithiolene‐S sites within the bis(dithiolene) WIV‐oxo complex. This finding provides critical evidence for dithiolene's involvement in proton reactions in high‐valent W‐oxo complexes.
Wonjung Lee   +9 more
wiley   +2 more sources

Ein Monolithium‐Monohydrogen‐Porphyrin

open access: yesAngewandte Chemie, EarlyView.
Ein Monohydrogen‐Metalloporphyrin wurde durch Reaktion von Lithiumdampf mit einem dünnen Film von Tetraphenylporphyrin im Vakuum synthetisiert. Der resultierende LiHTPP‐Komplex ist thermisch stabil und durch Vakuumsublimation isolierbar. Spektroskopische und theoretische Analysen liefern Einblicke in seine nicht‐planare Struktur, die Reaktionsenergetik,
Maik Schöniger   +3 more
wiley   +1 more source

New Conjugatable Platinum(II) Chlorins: Synthesis, Reactivity and Singlet Oxygen Generation. [PDF]

open access: yesMolecules
Almeida J   +6 more
europepmc   +1 more source

Peptide‐Carbazolyl Cyanobenzene Conjugates: Enabling Biomolecule Functionalization via Photoredox and Energy Transfer Catalysis

open access: yesAngewandte Chemie, EarlyView.
We introduce two methods for incorporating carbazolyl cyanobenzenes onto peptides: a C‐terminus decarboxylative functionalization and a Cys‐selective SNAr reaction. Both conjugates exhibit excellent photoredox/energy‐transfer properties, enabling their use for C‐terminal alkynylation and Cys‐selective thiol‐ene reactions on peptides, as well as ...
Xing‐Yu Liu   +4 more
wiley   +2 more sources

Controlling Assembly of Hybrid DNA Nanostructures into Higher‐Order Structures via Hydrophobicity

open access: yesAngewandte Chemie, EarlyView.
We harness hydrophobic interactions, fundamental in biology yet underutilized in DNA nanotechnology, to build a design framework for hierarchical DNA assemblies. By conjugating small hydrophobic molecules to DNA motifs, we controlled the formation of higher‐order structures, moving beyond traditional Watson–Crick pairing.
Minu Saji   +4 more
wiley   +2 more sources

Inter- and Intramolecular On-Surface Synthesis of Porphyrin-Based Nanostructures on Au(111) and Cu(111). [PDF]

open access: yesACS Appl Nano Mater
Frampton ES   +8 more
europepmc   +1 more source

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