Hydrogen Bond‐Assisted PCET and Formation of WIII─OH in Bis(Dithiolene) Complex
The single crystal structure of complex [2Et3NH‐1] reveals hydrogen bonding at both W‐oxo and dithiolene‐S sites within the bis(dithiolene) WIV‐oxo complex. This finding provides critical evidence for dithiolene's involvement in proton reactions in high‐valent W‐oxo complexes.
Wonjung Lee+9 more
wiley +2 more sources
Synergistic experimental and computational investigation of azo-linked porphyrin-based porous organic polymers for CO<sub>2</sub> capture. [PDF]
Panić B+5 more
europepmc +1 more source
Ein Monolithium‐Monohydrogen‐Porphyrin
Ein Monohydrogen‐Metalloporphyrin wurde durch Reaktion von Lithiumdampf mit einem dünnen Film von Tetraphenylporphyrin im Vakuum synthetisiert. Der resultierende LiHTPP‐Komplex ist thermisch stabil und durch Vakuumsublimation isolierbar. Spektroskopische und theoretische Analysen liefern Einblicke in seine nicht‐planare Struktur, die Reaktionsenergetik,
Maik Schöniger+3 more
wiley +1 more source
New Conjugatable Platinum(II) Chlorins: Synthesis, Reactivity and Singlet Oxygen Generation. [PDF]
Almeida J+6 more
europepmc +1 more source
Porphyrin Metabolism in Xeroderma Pigmentosum*
H El-Hefnawi, Derek J. Cripps
openalex +1 more source
We introduce two methods for incorporating carbazolyl cyanobenzenes onto peptides: a C‐terminus decarboxylative functionalization and a Cys‐selective SNAr reaction. Both conjugates exhibit excellent photoredox/energy‐transfer properties, enabling their use for C‐terminal alkynylation and Cys‐selective thiol‐ene reactions on peptides, as well as ...
Xing‐Yu Liu+4 more
wiley +2 more sources
Cu-mediated bipolar-type extended π-conjugated microporous polymers for lithium-ion battery cathodes with high energy density and fast-charging capability. [PDF]
Li Y+11 more
europepmc +1 more source
Controlling Assembly of Hybrid DNA Nanostructures into Higher‐Order Structures via Hydrophobicity
We harness hydrophobic interactions, fundamental in biology yet underutilized in DNA nanotechnology, to build a design framework for hierarchical DNA assemblies. By conjugating small hydrophobic molecules to DNA motifs, we controlled the formation of higher‐order structures, moving beyond traditional Watson–Crick pairing.
Minu Saji+4 more
wiley +2 more sources
Inter- and Intramolecular On-Surface Synthesis of Porphyrin-Based Nanostructures on Au(111) and Cu(111). [PDF]
Frampton ES+8 more
europepmc +1 more source