Interfacial Photoelectrochemistry in Organic Synthesis
Photoelectrodes have traditionally enjoyed widespread attention as heterogeneous catalysts for the activation of water and CO2 in energy research, while photoelectrochemistry with homogeneous molecular catalysts dominates the activations of more complex molecules in organic synthesis.
Gabriel Chan+4 more
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Formulation and Characterization of Carbopol-Based Porphyrin Gels for Targeted Dermato-Oncological Therapy: Physicochemical and Pharmacotechnical Insights. [PDF]
Ozon EA+11 more
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METABOLISM OF PORPHYRIN AND HEME ON EXPERIMENTAL CHLOROMA
Tadashi Mitsuoka
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Chiral iron porphyrin (+)-D<sub>4</sub>-(por)FeCl catalyzes highly enantioselective cyclopropanation of alkenes using <i>in situ</i> generated diazoacetonitrile with up to 35 000 product turnover. [PDF]
Tan HC+4 more
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A Microsomal Iron-Porphyrin Activator of Rat Liver Tryptophan Pyrrolase
Philip Feigelson, Olga Greengard
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Visible light‐driven photochemistry has advanced significantly, offering diverse methodologies in synthetic organic chemistry. Photocatalysis using red and near‐infrared (NIR) light is particularly notable due to its lower energy, reduced phototoxicity, minimized side reactions, and deeper penetration into reaction media.
Tong Zhang, Suman Pradhan, Shoubhik Das
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Porphyrin-based electrospun nanomaterials for life science applications. [PDF]
Mendes AC+4 more
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The cobalt complexes [(Hbbpya)CoII]2⁺, and [(Mebbpya)CoII]2⁺ show contrasting CO₂ reduction behaviors. [(Hbbpya)CoII]2⁺ selectively forms CO via a fast, two‐electron pathway aided by a ‐NH proton relay, while [(Mebbpya)CoII]2⁺ favours hydrogen evolution due to a slower, competitive one‐electron mechanism.
Ayan Bera+13 more
wiley +1 more source
Novel Azole-Modified Porphyrins for Mitochondria-Targeted Photodynamic Therapy. [PDF]
Rangasamy S+12 more
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A Monolithium Monohydrogen Porphyrin
A monohydrogen metalloporphyrin was synthesized by reacting lithium vapor with a thin film of tetraphenylporphyrin under UHV conditions. The resulting LiHTPP complex is thermally stable and isolable by vacuum sublimation. Spectroscopic and theoretical analyses reveal insights into its nonplanar structure, energetics, and mechanism of formation and ...
Maik Schöniger+3 more
wiley +1 more source