Results 81 to 90 of about 44,750 (259)

Kinetic‐Directed Thermodynamic Repair Enables the Synthesis of High‐Strain 2D Sub‐Stoichiometric COFs

Advanced Science, EarlyView.
2D covalent organic frameworks are promising photocatalysts. Yet, precise synthesis of sub‐stoichiometric COFs remains challenging due to poor kinetic control. We propose a general strategy: tuning polymerization degree of kinetic intermediates via time or solvent polarity directs their thermodynamic repair into highly crystallization. Using [4+3]‐type
Xiang Pei, Kaifu Yu, Pan He, Hongqing Wu, Bo Jiang, Kewen Shu, Yang Li, Ya Tang, Lijian Ma   +8 more
wiley   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

Angewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera, Francesco Basoccu, Andrea Porcheddu   +2 more
wiley   +2 more sources

The porphyrin metabolism in liver cirrhosis

Терапевтический архив, 2013
AIM: To comparatively study porphyrin metabolic disturbances in liver cirrhosis (LC) of varying etiology and to estimate the diagnostic and prognostic value of the detected disorders/MATERIAL AND METHODS: Seventy-one patients were examined; among them 34,
A B Krivosheev, M A Kondratova, T A Krivosheeva, L Ia Kupriianova, L A Khvan   +4 more
doaj  

Self‐Sustaining Lactate Depletion Nanoplatform Remodels Tumor Microenvironment and Augments Synergistic Photodynamic/Photothermal/Chemodynamic/Starvation Therapy for Eradication of Colon Cancer

Advanced Science, EarlyView.
The HILA nanoplatform integrates HMnO2, LOX, and ICG to orchestrate multimodal therapy (starvation, chemodynamic, photodynamic, and photothermal) for achieving efficient colon cancer eradication. The established HMnO2‐LOX catalytic cycle continuously consumes lactate, acidifys microenvironment, relieves hypoxia, and generats reactive oxygen species ...
Yu‐E. Wang, Shibo Zhao, Wenying Wu, Zhiwei Duan, Yuan Li, Xiangyu Zeng, Liang Hong, Yan Chen, Ling Tao, Kewu Zeng, Chaoda Xiao, Xiangchun Shen   +11 more
wiley   +1 more source

Wet Transfer of In Situ Grown Azo‐Containing Two‐Dimensional Conjugated Covalent Organic Framework Films for Photoswitchable Electronic Devices

Angewandte Chemie, EarlyView.
Wet transfer of an atomically flat azo‐functionalized 2D covalent organic framework film onto monolayer MoS2 enables clean van der Waals heterostructure devices with reversible photoswitching and multilevel nonvolatile memory. ABSTRACT Two‐dimensional π‐conjugated covalent organic frameworks (2D π‐COFs) combine in‐plane π‐delocalization with periodic ...
Kexin Wang, Bin Han, Fan Qiu, Yeonsu Jeong, Yusheng Chen, Yubin Fu, Christos Gatsios, Marco Vittorio Nardi, Melanie Timpel, Yang Hou, Shun‐Qi Xu, Paolo Samorì   +11 more
wiley   +2 more sources

Conformational switching of ethano-bridged Cu,H2-bis-porphyrin induced by aromatic amines

Beilstein Journal of Nanotechnology, 2015
Cu,H2-bis-porphyrin (Cu,H2-Por2), in which copper porphyrin and free-base porphyrin are linked together by an ethano-bridge, was dissolved in chloroform and spread at the air/liquid subphase interface of a Langmuir trough.
Simona Bettini, Emanuela Maglie, Rosanna Pagano, Victor Borovkov, Yoshihisa Inoue, Ludovico Valli, Gabriele Giancane   +6 more
doaj   +1 more source

Ion‐Gating Reservoir Computing for Preprocessing‐Free Speech Recognition from Throat Vibrations

Advanced Electronic Materials, EarlyView.
This work presents a throat‐mounted mechanoelectric sensor integrated with an ion‐gel/graphene reservoir device for on‐device speech recognition. The system converts raw biomechanical vibrations into rich nonlinear current dynamics, enabling efficient classification through a simple linear readout. The approach highlights a compact and tunable physical‐
Daiki Nishioka, Akito Tateyama, Hina Kitano, Takashi Nakanishi, Kazuya Terabe, Takashi Tsuchiya   +5 more
wiley   +1 more source

Antiaromaticity‐Driven Enhancement of Single‐Molecule Electrical Conductance by s‐Indacene Molecular Bridges

Angewandte Chemie, EarlyView.
Within the same molecular length scale, antiaromatic s‐indacene exhibits a marked increase in conductance compared to its aromatic benzodithiophene counterpart. Notably, the inherently small HOMO–LUMO gap of antiaromatic systems maintains a certain level of conductance even in the presence of cross‐conjugation.
Ching‐Piao Chu, Yuki Hanamura, Tatsuhiko Ohto, Seiya Maeda, Ryo Yamada, Siao‐Lei Yu, Yen‐Ju Cheng, Hirokazu Tada, Yoshito Tobe   +8 more
wiley   +2 more sources

Porphyrin Functionalized Graphene for Sensitive Electrochemical Detection of Uric Acid

International Journal of Electrochemical Science, 2016
In this study, by employing nanobiocomposite from porphyrin modified graphene oxide, we make a stable and sensitive amperometric UA amperometric biosensor.
Yun Yang, Ruirui Sun, Mingxiang Li, Boya Geng, Jingyi Deng, Mingyi Tang   +5 more
doaj   +1 more source

Donor–Acceptor Covalent Organic Framework Enables Ambipolar Charge Storage in Aluminum‐Ion Energy Storage

Advanced Energy Materials, EarlyView.
A donor–acceptor covalent organic framework is designed as an ambipolar cathode for aluminum‐ion energy storage. The crystalline, microporous architecture enables intrinsic charge transport without conductive additives. Multi‐electron redox activity at donor and acceptor sites supports high capacity, excellent stability, and efficient reversible ...
Cataldo Valentini, Verónica Montes‐García, Wojciech Kukułka, Saira Sarwar, Michał Bielejewski, Mateusz Wlazło, Rossella Greco, Viktorija Pankratova, Ignacio Pérez‐Juste, Dawid Pakulski, Paolo Samorì, Artur Ciesielski   +11 more
wiley   +1 more source