Results 111 to 120 of about 58,471 (202)

Spatio‐Temporal Processes of Diffusion‐Controlled Communication in Hierarchical Multi‐Compartments

Angewandte Chemie, EarlyView.
This study highlights the molecular communication of neighboring biomimetic populations in pH‐responsive hierarchically and non‐covalently organized multi‐compartments (HMC) through the assembly of micro‐ and nanocompartments. HMC unify key roles for cyclic spatio‐temporal diffusion processes and spatio‐temporal enzyme(‐like) reactions.
Xin Qiao, Haixu Chen, Andreas Schurig, Xiaoliang Wang, Yinyong Sun, Matthias Tobler, Susanne Boye, Kathrin Castiglione, Dietmar Appelhans, Xin Huang   +9 more
wiley   +2 more sources

Engineering cofacial porphyrin dimers using lacunary polyoxotungstates. [PDF]

Chem Sci
Yamaguchi M, Yonesato K, Shioya K, Li C, Murata K, Ishii K, Yamaguchi K, Suzuki K.   +7 more
europepmc   +1 more source

meso‐Free Porphyrinoids

Asian Journal of Organic Chemistry, EarlyView.
meso‐Free porphyrinoids are recognized as a versatile platform for further functionalization and oligomerization. The synthesis and characteristic features of such meso‐free porphyrinoids are reviewed. Abstract meso‐Unsubstituted (meso‐free) porphyrins have been an effective platform for creating versatile peripherally functionalized porphyrins and ...
Takayuki Tanaka, Osamu Iwanaga, Atsuhiro Osuka   +2 more
wiley   +1 more source

Hydrogen‐Bond‐Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach

Angewandte Chemie, EarlyView.
Hydrogen‐bonding‐directed supramolecular semiconductor thin films are realized by a thermal precursor approach. The precursor film is formed via solution processes and thermally converted to the target semiconductor film. This versatile strategy enables the fabrication of supramolecularly controlled thin films composed of insoluble molecules like π ...
So Ueno, Mitsuaki Yamauchi, Nobutaka Shioya, Hiroshi Matsuda, Takeshi Hasegawa, Keitaro Yamamoto, Yoshiyuki Mizuhata, Hiroko Yamada   +7 more
wiley   +2 more sources

Formulation and Characterization of Carbopol-Based Porphyrin Gels for Targeted Dermato-Oncological Therapy: Physicochemical and Pharmacotechnical Insights. [PDF]

Int J Mol Sci
Ozon EA, Anastasescu M, Musuc AM, Burloiu AM, Socoteanu RP, Atkinson I, Mitran RA, Culita DC, Lupuliasa D, Mihai DP, Gird CE, Boscencu R.   +11 more
europepmc   +1 more source

Solvent‐Directed Handedness in a Chirally Twisted Tetrakisporphyrin Macrocycle

Asian Journal of Organic Chemistry, EarlyView.
A chirally twisted tetrakisporphyrin macrocycle was synthesized by incorporating a chiral dioxolane into a tetrakisporphyrin macrocycle. The solvent type influenced the preferred handedness of the twisted conformation. Circular dichroism measurements and computational analyses determined the handedness of the conformers in solvents toluene and ...
Kouta Tanabe, Naoyuki Hisano, Takeharu Haino   +2 more
wiley   +1 more source

Photodynamic Inactivation Mediated by Endogenous Porphyrins of <i>Corynebacterium diphtheriae</i> in Planktonic and Biofilm Forms. [PDF]

ACS Omega
Alves GB, Calderari MRDCM, Fonseca END, Sant'anna LO, Santos LSD, Mattos-Guaraldi AL.   +5 more
europepmc   +1 more source

Tuning Antiaromaticity Through Meso‐Substituent Orientation in Core‐Modified Isophlorins

Asian Journal of Organic Chemistry, EarlyView.
The antiaromaticity of dithiadioxaisophlorins is controlled by the steric bulkiness of meso‐substituents through their tilt angle relative to the macrocycle. Bulkier substituents maintain larger angles, preserving stronger antiaromaticity, while smaller groups facilitate π‐conjugation with the macrocycle, diminishing antiaromaticity.
Maika Isoda, Haruna Sugimura, Yusuke Honda, Ken‐ichi Yamashita   +3 more
wiley   +1 more source

Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine

Angewandte Chemie, EarlyView.
19E‐geissoschizine is a key precursor in the biosynthesis of monoterpene indole alkaloids such as strychnine, ibogaine, and vinblastine. Using enzymatic assays and gene silencing, three CYPs were identified from C. roseus that oxidize this compound to four alkaloid scaffolds: strychnos, sarpagan, akuammiline, and mavacurane. Mutational analysis reveals
Mohamed O. Kamileen, Benke Hong, Klaus Gase, Maritta Kunert, Lorenzo Caputi, Benjamin R. Lichman, Sarah E. O'Connor   +6 more
wiley   +2 more sources

Sporadic Porphyria Cutanea Tarda, Cutaneous Sarcoidosis, and Compound Heterozygosity of HFE Mutations Cys282Tyr and His63Asp-A Case Report. [PDF]

EJHaem
Kim JL, Crawford R, Lano IM, Merkeley H.
europepmc   +1 more source