Results 51 to 60 of about 64,218 (310)

Topologically protected excitons in porphyrin thin films [PDF]

, 2014
The control of exciton transport in organic materials is of fundamental importance for the development of efficient light-harvesting systems. This transport is easily deteriorated by traps in the disordered energy landscape.
Aspuru-Guzik, Alán, Saikin, Semion S., Yao, Norman Y., Yuen-Zhou, Joel   +3 more
core   +2 more sources

Enhancing Optoelectronic Properties in Phthalocyanine‐Based SURMOFs: Synthesis of ABAB Linkers by Avoiding Statistical Condensation with Tailored Building Blocks

Advanced Functional Materials, EarlyView.
A novel phthalocyanine (PC)‐based metal–organic framework (MOFs) is synthesized using ditopic PC linkers obtained through regioselective statistical condensation. The resulting MOF exhibits significant improvements in electronic absorption, thereby enhancing the material's performance in light harvesting and energy conversion.
Lukas S. Langer, Mareen Stahlberger, Xiaojing Liu, Yi Luo, Niklas E. Häußermann, Puja Singhvi, Yidong Liu, Olaf Fuhr, Martin Nieger, Lars Heinke, Thomas Heine, Christof Wöll, Stefan Bräse   +12 more
wiley   +1 more source

The biosynthesis of porphyrins

Ergebnisse der Physiologie Biologischen Chemie und Experimentellen Pharmakologie, 1948
This article is intended as a summary of some of the work which has been done, over the past ten years, on the biosynthesis of porphyrins. The treatment accorded to this subject should not be considered to be that of an exhaustive review article. It will consider only those papers which, in the author’s opinion, are most pertinent to the particular ...
openaire   +3 more sources

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

Advanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies, Marcos Eduardo G. Carmo, Gonçalves J. Marrenjo, Stephan Reuther, Patrick Ganswindt, Antonio Otavio T. Patrocinio, Thomas Bein, Osmando F. Lopes, Jenny Schneider   +8 more
wiley   +1 more source

Method and apparatus for eliminating luminol interference material [PDF]

, 1979
A method and apparatus for removing porphyrins from a fluid sample which are unrelated to the number of bacteria present in the sample and prior to combining the sample with luminol reagent to produce a light reaction is disclosed.
Jeffers, E. L., Thomas, R. R.
core   +1 more source

High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole [PDF]

, 2000
The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III ...
Bendix, Jesper, Golubkov, Galina, Gray, Harry B., Gross, Zeev   +3 more
core   +1 more source

Flexibility and Dynamicity Enhances and Controls Supramolecular Self‐Assembly of Zinc(II) Metallogels

Advanced Functional Materials, EarlyView.
Zinc(II) coordination complexes with tunable aryloxy‐imine ligands exhibit controllable supramolecular self‐assembly into hierarchical fibrous structures. Coordination‐driven stacking, not π–π interactions, enables gelation, dynamic assembly/disassembly, and enhanced nanomechanical properties.
Merlin R. Stühler, Hesam Makki, Dorothee Silbernagl, Mathias Dimde, Kai Ludwig, Bengt E. Tegner, Christopher Greve, Konstantin Rausch, Eva M. Herzig, Anna Köhler, Alex J. Plajer   +10 more
wiley   +1 more source

Cellular Uptake and Phototoxicity Optimization of Arene Ruthenium Porphyrin Derivatives

Inorganics
In this study, dinuclear and tetranuclear arene ruthenium porphyrins were synthesized and assessed for their potential as photosensitizers (PSs) in photodynamic therapy (PDT) using the Colo205 colon cancer cell line as a model system.
Zeinab Janbeih, Manuel Gallardo-Villagrán, Bruno Therrien, Mona Diab-Assaf, Bertrand Liagre, Ludmil Benov   +5 more
doaj   +1 more source

Interlocked Porphyrin Switches [PDF]

Chemistry – A European Journal, 2013
AbstractWe describe the synthesis of a series of interlocked structures from porphyrin–glycoluril cage compounds and bis(olefin)‐terminated viologens by an olefin‐metathesis protocol. The length of the chain connecting the olefin substituents with the viologen has a marked effect on the products of the ring‐closure reaction.
Coumans, R.G.E., Coumans, R.G.E., Elemans, J.A.A.W., Rowan, A.E., Rowan, A.E., Nolte, R.J.M.   +5 more
openaire   +6 more sources

Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)

Advanced Functional Materials, EarlyView.
Luminescent MOF‐76 materials based on Eu(III) and mixed Eu(III)/Y(III) show rapid and reversible changes in emission intensity in response to O2 with very short response times. The effect is based on triplet quenching of the linker ligands that act as photosensitizers. Average emission lifetimes of a few milliseconds turn out to be mostly unaffected by
Zhenyu Zhao, Christian Weinberger, Jakob Steube, Matthias Bauer, Martin Brehm, Michael Tiemann   +5 more
wiley   +1 more source