Results 51 to 60 of about 76,963 (249)

Synthesis and properties of cationic derivaties of meso-tetra(4-pyridyl)porphyrin

open access: yesТонкие химические технологии, 2009
Synthesis of amphyphilic cationic meso-pyridilsubstituted porphyrins bearing long chain alkyl groups is described. An improved methods of preparation of tetra- and mono-alkylsubstituted meso-pyridil porphyrins are proposed.
N. V. Novikov   +5 more
doaj  

Conformational control of nonplanar free base porphyrins: towards bifunctional catalysts of tunable basicity.

open access: yesChemical Communications, 2017
For the first time, free base and N-methylated porphyrins have been utilized as bifunctional organocatalysts in Michael additions and it was found that distortion of the macrocycle is a vital prerequisite for their catalytic activity.
Marie Roucan   +4 more
semanticscholar   +1 more source

Lead Halide Perovskite Photoelectrocatalysis

open access: yesAdvanced Materials, EarlyView.
Lead halide perovskite semiconductors have emerged as highly promising materials for solar fuel and chemical synthesis. This perspective discusses advances made in the rational photoelectrode design to improve solar‐to‐chemical conversion, product scope, and scalability.
Virgil Andrei
wiley   +1 more source

Photophysical and Antibacterial Properties of Porphyrins Encapsulated inside Acetylated Lignin Nanoparticles

open access: yesAntibiotics, 2021
Lignin has recently attracted the attention of the scientific community, as a suitable raw material for biomedical applications. In this work, acetylated lignin was used to encapsulate five different porphyrins, aiming to preserve their photophysical ...
Nidia Maldonado-Carmona   +6 more
doaj   +1 more source

Double‐Transition‐Metal MXenes: Multimetallic 2D Platforms for Next‐Generation Biomedicine

open access: yesAdvanced Materials, EarlyView.
The present work explores recent progress in double‐transition‐metal MXenes and focuses on their potential as multifunctional biomedical nanoplatforms whose tunable optical, electronic, mechanical, and surface properties enable imaging, theranostics, antimicrobial activity, biosensing, tissue engineering, and drug delivery.
Parsa Namakiaraghi   +2 more
wiley   +1 more source

Modifications of Porphyrins and Hydroporphyrins for Their Solubilization in Aqueous Media

open access: yesMolecules, 2017
The increasing popularity of porphyrins and hydroporphyrins for use in a variety of biomedical (photodynamic therapy, fluorescence tagging and imaging, photoacoustic imaging) and technical (chemosensing, catalysis, light harvesting) applications is also ...
Michael P Luciano, C. Brückner
semanticscholar   +1 more source

Machine Learning Accelerated Computational Design of Bio‐Inspired Catalysts in the Nitrogen Reduction Reaction

open access: yesAdvanced Materials, EarlyView.
We introduce a computational workflow that combines quantum chemical calculations and machine learning techniques to predict the catalytic performance of a wide range of catalysts in the nitrogen reduction reaction (NRR). The analysis of the trained models provides insights into the complex structure–activity relationship in experimental catalytic ...
Leonardo Di Ciano   +5 more
wiley   +1 more source

Synthesis and properties amphiphilic meso-arylsubstituted porphyrins

open access: yesТонкие химические технологии, 2007
Synthesis of amphiphilic meso-arylsubstituted porphyrins with hydrophobic long chain groups and with terminal carboxylic and hydroxylic groups via dipyrrolylmethanes and with the use of monopyrrolic condensation is described.
I. N. Fedulova   +5 more
doaj  

Entropy analysis of nickel(II) porphyrins network via curve fitting techniques

open access: yesScientific Reports, 2023
Nickel(II) porphyrins typically adopt a square planar coordination geometry, with the nickel atom located at the center of the porphyrin ring and the coordinating atoms arranged in a square plane.
Muhammad Talha Farooq   +2 more
doaj   +1 more source

Magnetic‐Field Modulation of Charge Transport in Non‐Fullerene Semiconductors for Enhanced Hydrogen Evolution

open access: yesAdvanced Materials Interfaces, EarlyView.
ABSTRACT This study demonstrates that weak magnetic fields (16–40 mT) increase the efficiency of the hydrogen evolution reaction (HER) in electrocatalysts based on non‐fullerene acceptor (NFA) derivatives IT‐4Cl and Y6. Electrochemical measurements reveal that the application of the magnetic field reduces the onset potential and increases the current ...
João Paulo Araujo Souza   +7 more
wiley   +1 more source

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