Results 61 to 70 of about 64,218 (310)
Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
5-(4-X-Phenyl)-10,15,20-tris(substituted phenyl) porphyrins (4-6) were synthesized from meso-(substituted phenyl) dipyrromethanes (1-3), which in turn were prepared in yields of 75-92 %.
Edgardo N. Durantini
doaj +1 more source
Synthesis, Photophysical Properties, and Toxicity of o-Xylene-Bridged Porphyrin Dimers
In this work, a number of new porphyrin dimers coupled with spacers based on α,α’-dibromo-o-xylene were synthesized and characterized by 1H, 13C NMR, 1H-1H COSY NMR, UV-vis-spectroscopy, and MALDI-TOF mass spectrometry.
Kseniya A. Zhdanova +6 more
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Photofrin II as an efficient radiosensitizing agent in an experimental tumor [PDF]
Background and Objective: The use of ionizing irradiation as radiation therapy (RT) for tumor treatment represents a well-established method. The use of photodynamic therapy (PDT), especially with Photofrin II, for tumor treatment is also known. Chemical
Corti, L. +6 more
core +1 more source
Electroactive Metal–Organic Frameworks for Electrocatalysis
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska +7 more
wiley +1 more source
Cretaceous-Tertiary boundary layer at Stevns Klint (Denmark): copper and copper(II) porphyrins [PDF]
High concentrations (up to 4000 ppm) of copper(II) porphyrins have been detected in the kerogen of the Cretaceous/Tertiary (KT) boundary informal type sediment, the Fish Clay, at Stevns Klint, Denmark. These pigments have also been found in the Danish KT
PAVLE I. PREMOVIC +4 more
doaj +2 more sources
Simulation of Heme using DFT+U: a step toward accurate spin-state energetics [PDF]
We investigate the DFT+U approach as a viable solution to describe the low-lying states of ligated and unligated iron heme complexes. Besides their central role in organometallic chemistry, these compounds represent a paradigmatic case where LDA, GGA ...
Cococcioni, Matteo +3 more
core +2 more sources
Band Alignment in In‐Oxo Metal Porphyrin SURMOF Heterojunctions
Porphyrin core metalation in indium‑oxo SURMOFs enables systematic tuning of band edge positions without altering the crystal structure. First‑principles calculations reveal type‑I and type‑II heterostructures as well as multi‑junction energy cascades, establishing a modular strategy for exciton funneling and charge separation in optoelectronic ...
Puja Singhvi, Nina Vankova, Thomas Heine
wiley +1 more source
In recent years, scientific advancements have constantly increased at a significant rate in the field of biomedical science. Keeping this in view, the application of porphyrins and metalloporphyrins in the field of biomedical science is gaining ...
Muhammad Imran +4 more
doaj +1 more source
A previously unreported coordination motif stabilising single Fe atoms by indigo chelation and pyridyl coordination on Au(111) has been revealed. By using planar tritopic pyridyl linkers (TPyB), extended 2D porous networks of indigo3(TPyB)2Fe6 form. These networks can be crystalline or vitreous and offer an environment where individual coordination ...
Hongxiang Xu +9 more
wiley +1 more source
Synthesis and properties of cationic derivaties of meso-tetra(4-pyridyl)porphyrin
Synthesis of amphyphilic cationic meso-pyridilsubstituted porphyrins bearing long chain alkyl groups is described. An improved methods of preparation of tetra- and mono-alkylsubstituted meso-pyridil porphyrins are proposed.
N. V. Novikov +5 more
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